Fluids in the lithosphere, 2. Experimental constraints on CO2 transport in dunite and quartzite at elevated P-T conditions with implications for mantle and crustal decarbonation processes

In a series of experiments at 0.5–1.3 GPa and 1050–1200°C we have monitored the transport, via crack propagation, of CO₂ into well-annealed olivine and quartz aggregates. The objectives were to determine (1) the extent and rate of fluid penetration; (2) the effect of varying both P-T conditions and microstructure; and (3) the fluid penetration pathways. Experiments on CO₂ penetration into dunite annealed in the absence of MgO indicate rapid and pervasive fluid transport on a grain-dimension scale, but a limited penetration distance ( 1 mm). Additional experiments on dunite annealed in the presence of MgO (either dispersed or present at both ends), however, resulted in CO₂ penetration that was both pervasive on the scale of individual grains and almost always completely through the 5 mm long samples. The abundance of fine (10 μm) grains in the MgO-free dunite, in contrast to the much larger grain sizes of the samples annealed with MgO present, suggests the difference in fluid penetration behavior may arise because the strength variation in dunite scales with the grain size. Effects arising from changes in olivine point defect chemistry, however, are an additional possibility. The response of synthetic quartzite to CO₂ overpressure is distinct from that of dunite: Quartzite experiences rapid and complete penetration of CO₂, via a macroscopically visible system of transgranular fractures, over the range of P-T conditions investigated.The small amount of porosity ( 2–3%) present in most rock samples fabricated for this study, lacks three-dimensional connectivity, thus precluding any enhanced fluid penetration via porous flow. Pores could possibly enhance fluid penetration as the result of a small reduction in resistance to fracture, but the probable abundance of strength-controlling flaws in natural rocks is likely to produce similar behavior.The results of our experiments on olivine and olivine + MgO suggest that the transport of pressurized CO₂ in very olivine-rich mantle environments will be pervasive on the scale of individual grains and its extent may be dependent on rock microstructure and/or crystal chemical effects. Such pervasive fluid transport, perhaps associated with magma decarbonation, may have interesting implications for both magma transport and local LREE enrichment of adjacent mantle wall-rock. The ease with which quartzite is penetrated by CO₂ at the conditions of our experiments underscores the possible role of decarbonation reactions in crustal permeability-enhancement processes.     

Spatial variability in soil moisture as predicted from airborne thematic mapper (ATM) data

In the first part of this project, the extent to which moisture content of alluvial soils could be predicted from imagery derived from an airborne thematic mapper (ATM) was investigated. From sampling done on the same day as the flight, it was found that digital numbers derived from the thermal channel (waveband 11) were strongly correlated with gravimetric moisture content. From sampling three fields of contrasting land cover, the relationship between waveband 11 values and moisture content was found to be independent of land cover type. Spatial variation in waveband 11 values and thus moisture content were related to palaeochannel patterns on the alluvial land. This was investigated by deriving variograms for long transects from each of the three investigated fields. The range and sills of the variograms are shown to express the nature and pattern of palaeochannels. By the application of such geostatistical techniques, high resolution imagery can thus be used to quantify palaeochannel characteristics on alluvial land.     

A direct measurement of the distribution in depth of 26Al in the Estacado meteorite

The two-dimensional distribution of ²⁶Al across a slice of the Estacado meteorite was measured using non-destructive γ-γ coincidence counting. The maximum activity was found to be 60 ± 2 dpm kg^?1 and the variation across the slice rather small. The intensity and distribution are in moderate agreement with existing theoretical models if the pre-atmospheric shape of the meteorite had been a sphere of radius 0.35 ± 0.05 m, but it was more likely to have been slightly non-spherical.     

Zircon saturation revisited: temperature and composition effects in a variety of crustal magma types

Hydrothermal experiments in the temperature range 750–1020°C have defined the saturation behavior of zircon in crustal anatectic melts as a function of both temperature and composition. The results provide a model of zircon solubility given by: In D_Zr^zircon/melt= ?3.80?[0.85(M?1)]+12900/T where D_Zr^zircon/melt is the concentration ratio of Zr in the stoichiometric zircon to that in the melt, T is the absolute temperature, and M is the cation ratio (Na + K + 2Ca)/(Al · Si). This solubility model is based principally upon experiments at 860°, 930°, and 1020°C, but has also been confirmed at temperatures up to 1500°C for M = 1.3. The lowest temperature experiments (750° and 800°C) yielded relatively imprecise, low solubilities, but the measured values (with assigned errors) are nevertheless in agreement with the predictions of the model.For M = 1.3 (a normal peraluminous granite), these results predict zircon solubilities ranging from ～ 100 ppm dissolved Zr at 750°C to 1330 ppm at 1020°C. Thus, in view of the substantial range of bulk Zr concentrations observed in crustal granitoids (～ 50–350 ppm), it is clear that anatectic magmas can show contrasting behavior toward zircon in the source rock. Those melts containing insufficient Zr for saturation in zircon during melting can have achieved that condition only by consuming all zircon in the source. On the other hand, melts with higher Zr contents (appropriate to saturation in zircon) must be regarded as incapable of dissolving additional zircon, whether it be located in the residual rocks or as crystals entrained in the departing melt fraction. This latter possibility is particularly interesting, inasmuch as the inability of a melt to consume zircon means that critical geochemical “indicators” contained in the undissolved zircon (e.g. heavy rare earths, Hf, U, Th, and radiogenic Pb) can equilibrate with the contacting melt only by solid-state diffusion, which may be slow relative to the time scale of the melting event.     

Efficient updating of kriging estimates and variances

This short note presents a method for efficiently updating ordinary kriging estimates and variances when one or more additional samples are incorporated into the kriging system. First, the foundation linear algebra result is presented. Then the update equations are derived. Finally, an illustrative application of updating is briefly discussed.     

Rapid neutron capture in supernova explosions

The implications of recent studies of the dynamics of the cores of highly evolved massive stars are considered with regard to the general problems of nucleosynthesis. The typical conditions estimated for these models are shown to be very promising for the process of element synthesis by neutron capture on a fast time scale (ther-process ofBurbidge et al., 1957).     

Detection of subsidence conditions by photogeology

A variety of air-photo interpretation criteria need to be used for detecting areas of potential subsidence. An initial step is to search for past failures showing on air photographs, to establish the cause and to interpret the boundaries of the environment that might be affected. Causes detectable include karstic terrain, areas liable to piping, or containing concealed peat, old shafts, and stratiform or vein workings. Airborne imaging conditions can be selected to improve the possibility of detection in some situations.

The technique can indicate situations where risks are high, but cannot be used to map with certainty voids liable to collapse.     

Landform development on moraines of the Klutlan Glacier,Yukon Territory,Canada

The landform evolution of the Klutlan moraines is described and explained primarily with respect to processes that cause voids in which debris is deposited. Morainal deposits of different ages provide examples of landforms at different stages of development, so that continuous ideal evolutionary sequences can be inferred. Specific features are classified as those on material of the same depositional age that develop mostly in a vertical direction with numerous topographic reversals, and those cross-cutting materials of different depositional age that develop primarily in a horizontal direction. The evolution of slopes is often terminated by their destruction as the underlying ice melts, but former slopes on morainal debris are traceable to ice-ridge slopes on the original glacier surface. The general process of evolution is one of downwasting by surficial icemelt, in which a grand topographic reversal takes place as the original ice mass with a gently convex surface melts to leave a basin floored by a concave mantle of morainal debris. The primary glacial process of melting differs from the primary karst process of solution, but many minor glacial processes and major glacial forms are similar to minor karst processes and major karst forms.     

Blaubleibender covellite and its relationship to normal covellite

Both natural and synthetic samples of blaubleibender (blue-remaining) covellite have been studied by reflected light microscopy, electron probe microanalysis and electron microscopy and diffraction. The natural sample of composition Cu_1.20S has a 19a × 19a superstructure based on the hexagonal coveilite subcell (side a). The synthetic sample of composition Cu_1.10S has a 27 a × 2 7a superstructure. In both cases the phases are homogeneous. The evidence suggests that the recognition of two distinct types of blaubleibender covellite may be an oversimplification, and that a series of metastable superstructures based on the covellite structure may exist.Work done while on leave at the Department of Mineralogy and Petrology, Cambridge