Oceanographic controls on the carbon isotopic compositions of sinking particles from the Cariaco Basin

This study examined the relationship between carbon isotopic composition of sinking organic matter (OM) and the biological, physical and chemical properties of the surface ocean in the Cariaco Basin. The ¹³C/¹²C ratio of OM (δ¹³C_org) in sinking particles was determined on sediment trap samples from four depths collected from 1996 to 1999 as part of the CArbon Retention In A Colored Ocean time series. Water column properties, including temperature, productivity, chlorophyll and concentration of dissolved CO₂, were concurrently measured on monthly cruises. The δ¹³C_org varied from a high of –17.7‰ to a low of –22.6‰ during the study period. The variation of the δ¹³C_org throughout seasonal cycles was directly proportional to the strength of upwelling and was negatively correlated with temperature (r²=0.64). During the 1996–1997 upwelling event, the strongest during the study period, the δ¹³C_org increased by 4.4‰ whereas during the 1998–1999 upwelling event, the weakest during the study period, the δ¹³C_org only increased by 3.3‰. Contrary to most previous studies, we observed a negative relationship (r²=0.53) between [CO_2 aq] and the estimated isotopic fractionation factor (ε_p). However, there was no correlation between ε_p and the calculated growth rates indicating that there was non-diffusive uptake of carbon into phytoplankton cells. It thus appears that [CO_2 aq] does not control the δ¹³C_org in the water column of the study site. The best explanation for the isotopic enrichment observed is a carbon concentrating mechanism (CCM) in phytoplankton. The existence of a CCM in phytoplankton has major implications for the interpretation of the δ¹³C_org in the Cariaco Basin.     

Juvenile contribution of the Neoproterozoic Rio Negro Magmatic Arc (Ribeira Belt,Brazil): Implications for Western Gondwana amalgamation

The ca. 790–600 Ma Rio Negro Complex (RNC) of the Ribeira belt (Brazil) consists of a plutonic portion of a magmatic arc built by the E-vergent subduction of the ESE border of the São Francisco paleoplate during the amalgamation of Western Gondwana.The plutonic series comprises low- to medium-K granitoids (ca. 790–620 Ma) and high-K granitoids and shoshonite rocks (ca. 610–605). The age span of 185 m.y. is suggestive of a long history of arc-related magmatism, continuously or not in time. The Nd isotopic signatures of the RNC consist of εNd(t) ratios from ? 3 to + 5 for the medium-K series shoshonite series and from ? 14 to ? 3 for the younger high-K group. This time-dependent trend of Nd isotopes is indicative of progressive maturity of the arc over time. The same evolution is indicated by Sr data, as the medium-K rocks have ⁸⁷Sr/⁸⁶Sr initial ratios < 0.705 while the high-K rocks yield values between 0.705 and 0.710. The predominance of intermediate rocks over mafic ones suggests an initial intra-oceanic to transitional stage, possibly developed in a distal portion of a passive margin, such as the Japanese arc, evolving to a more developed, differentiated felsic rock associations.The role of transform fault zones, such as the Luanda shear zone, is emphasized in order to explain the consumption of a wide oceanic plate in the inner portion of Western Gondwana.     

Early succession of the macroinvertebrate community in a shallow lake: Response to changes in the habitat condition

In the present study the initial succession of the aquatic macroinvertebrate communities of a newly created shallow lake in a wetland area was monitored during 15 months. Three different types of macroinvertebrate samples (multihabitat, associated to the Phragmites australis stands and associated to the sediment) were collected monthly from May 2004 to July 2005. Additional samples were collected in the reed stand in 2007, when the reed belt had become much taller and thicker. Colonization of the lake was fast, and the colonization sequence was mainly related to the dispersal abilities of the taxa. Habitat-specific changes in the assemblage's structure and composition were registered. The communities associated to the sediment showed a decrease in overall biomass, density and species richness along time. The density of the gastropod Physella acuta and the chironomid species Dicrotendipes pallidicornis, Polypedilum nubifer and Tanytarsus horni decreased significantly, after Chara stands declined; while the chironomid Chironomus riparius became dominant. The epiphytic macroinvertebrate communities associated with the reed stands followed a seasonal pattern, with a warm-period community dominated by the chironomid species Ablabesmyia monilis and Psectrocladius sordidellus-group, and a cold-period community dominated by the chironomid species Cricotopus ornatus and D. pallidicornis.     

Complex geophysical wake flows

Idealized studies of island wakes often use a cylinder-like island to generate the wake, whereas most realistic studies use a close representation of the oceanic bathymetry immersed in a complex representation of the “ambient” geophysical flows. Here, a system of multiple islands was placed into numerical and experimental channels, in order to focus on the complexity of the archipelago wake, including (a) the influence of small neighboring islands and (b) the role of the island-shelf. The numerical geostrophic and stratified channel was built using a three-dimensional primitive equation model, considering a realistic representation of the Madeira archipelago bathymetry, with prescribed initial and boundary conditions. Results from the simulations show that the neighboring islands alter the near-field wake. Small eddies generated by the neighboring islands lead to destabilization of the shear layers of the larger island. Laboratory experiments carried out in the Coriolis rotating tank corroborated this near-field disruptive mechanism. The neighboring island perturbation effect was present whatever the direction of the incoming flow, but under different regimes. North–south wakes produced geostrophic eddies (≥ R _d), whereas west–east wakes produced (exclusively) ageostrophic submesoscale eddies (< < R _d) which traveled offshore with wave-like motion. The archipelago shelf contributed to the asymmetric vertical migration of oceanic vorticity. Cyclonic vorticity dominated the surface dynamics, whereas anticyclonic circulation prevailed at the bottom part of the linearly stratified upper layer. This study identifies several likely wake scenarios induced by the Madeira archipelago, and may serve as guide for future multiscale numerical studies and in situ campaigns.     

Chemical characteristics of groundwater around two massive sulphide deposits in an area of previous mining contamination, Iberian Pyrite Belt, Spain

A detailed chemical study of groundwater was carried out to elucidate the processes controlling the oxidation and dissolution of sulphide minerals at two massive sulphide deposits in the Iberian Pyrite Belt (IPB), i.e. the mined La Zarza deposit and the unmined Masa Valverde deposit. It was found that major-element compositions varied according to the hydrological regime, La Zarza being in a relatively high area with groundwater recharge (and disturbance due to the human factor) and Masa Valverde being in a relatively low area with groundwater discharge. The variations mainly concern pH, Eh, SO₄ and Na concentrations. Metal concentrations were determined (a) by ICP-MS after filtration, and (b) in some cases by voltammetric measurement of Cu, Pb, Zn, Cd and Mn using the Voltammetric In situ Profiling (VIP) System, which allows detection of only the mobile fractions of trace elements (i.e., free metal ions and small labile complexes a few nanometers in size). If one compares the results obtained by each of the two methods, it would appear that the groundwater shows significant enhancement of metal solubility through complexing with organic matter and/or adsorption onto colloids and/or small particles. In areas of sulphide oxidation, however, this solubility enhancement decreases according to Cu>Zn>Cd>Pb. Under very low redox conditions, the attained metal concentrations can be several orders of magnitude (up to 10⁸–10⁹ for Cu and 10²–10³ for Pb) larger than those expected from equilibrium with respect to sulphide minerals as calculated with the EQ3NR geochemical code; Zn concentrations, however, are close to equilibrium with respect to sphalerite. The implication of these results is discussed with respect both to mineral exploration and to environmental issues.     

Rockfall detachment susceptibility map in El Hierro Island, Canary Islands, Spain

A semi-quantitative heuristic methodology is developed to map a rockfall detachment susceptibility zonation of El Hierro Island (Canary Archipelago). The rationalized procedure, which we called non-weighted bounded indicators, is based on overlapping thematic maps of conditioning factors to mass movement, which are appropriately and individually rescaled and then composed by addition to obtain a susceptibility numerical index through a GIS. As the consistency of the geomorphological analysis depends on the expert subjective criteria and the appropriate interpretation of the landscape, the use of this methodology reduces subjectivity and quantifies the degree of susceptibility. The main factors affecting the mass movement phenomena (rockfalls events), also recognized in the field and, therefore, considered in the presented GIS arrangement, are slope, profile curvature, lithology, vegetation cover and dykes density. To calculate the slope threshold or minimum angle characteristic of rockfall source areas, mixed Gaussian slope frequency decomposition is used. The curvature index reveals stepwise areas. Qualitative geomechanical characteristics are linked to a quantitative index according to a volcanic lithological-complexes classification. Both destabilization (root-wedging) and stabilization effects are considered into the vegetation cover index. The dyke density index incorporates the bearing rock capacity decrease produced in the halo around a dyke network intrusion. Slope, curvature and vegetation indexes thresholds have been fitted following field observations. A rockfall detachment susceptibility map is obtained and classified based on the histogram maxima. The rockfall inventory, based on rockfall events reported within the island, was used for the model validation. A 12?% of the whole island shows medium to very high susceptibility.     

A description of chloride cell and kidney tubule alterations in the flatfish Solea senegalensis exposed to moderately contaminated sediments from the Sado estuary (Portugal)

The effects of sediment-bound contaminants on kidney and gill chloride cells were surveyed in juvenile Solea senegalensis exposed to fresh sediments collected from three distinct sites of the Sado Estuary (Portugal) in a 28-day laboratorial assay. Sediments were analyzed for metallic contaminants, polycyclic aromatic hydrocarbons and organochlorines as well as for total organic matter, redox potential and fine fraction. The potential for causing adverse biological effects of each surveyed sediment was assessed by comparison of contaminant levels to available guidelines for coastal sediments, namely the Threshold Effects Level (TEL) and the Probable Effects Level (PEL). The Sediment Quality Guideline Quotient indices (SQGQ) were calculated to compare the overall contamination levels of the three stations. A qualitative approach was employed to analyze the histo/cytopathological traits in gill chloride cells and body kidney of fish exposed to each tested sediment for 0, 14 and 28 days. The results showed that sediment contamination can be considered low to moderate and that the least contaminated sediment (from a reference site, with the lowest SQGQ) caused lesser changes in the surveyed organs. However, the most contaminated sediment (by both metallic and organic xenobiotics, with highest SQGQ) was neither responsible for the highest mortality nor for the most pronounced lesions. Exposure to the sediment presenting an intermediate SQGQ, essentially contaminated by organic compounds, caused the highest mortality (48%) and the most severe damage to kidneys, up to full renal necrosis. Chloride cell alterations were similar in fish exposed to the two most contaminated sediments and consisted of a pronounced cellular hypertrophy, likely involving fluid retention and loss of mitochondria. It can be concluded that sediment contamination considered to be low or moderate may be responsible for severe injury to cells and parenchyma involved in the maintenance of osmotic balance, contributing for the high mortality levels observed. The results suggest that sediment-bound organic contaminants such as PAHs (polycyclic aromatic hydrocarbons) and PCBs (polychlorinated biphenyls) may be very toxic to the analyzed organs, especially the kidney, even when present in low-risk concentrations.     

Uncovering unnoticed small-scale tsunamis: field survey in Lombok,Indonesia, following the 2018 earthquakes

Natural Hazards - In 2018, Lombok island, Indonesia, was hit by a series of destructive earthquakes that caused thousands of casualties and widespread material damage. In response to those events,...     

STANOVA: a smoothed-ANOVA-based model for spatio-temporal disease mapping

Spatio-temporal disease mapping can be viewed as a multivariate disease mapping problem with a given order of the geographic patterns to be studied. As a consequence, some of the techniques in multivariate literature could also be used to build spatio-temporal models. In this paper we propose using the smoothed ANOVA multivariate model for spatio-temporal problems. Under our approach the time trend for each geographic unit is modeled parametrically, projecting it on a preset orthogonal basis of functions (the contrasts in the smoothed ANOVA nomenclature), while the coefficients of these projections are considered to be spatially dependent random effects. Despite the parametric temporal nature of our proposal, we show with both simulated and real datasets that it may be as flexible as other spatio-temporal smoothing models proposed in the literature and may model spatio-temporal data with several sources of variability.