High-resolution seismic imaging of gas accumulations and seepage in the sediments of the Ria de Aveiro barrier lagoon (Portugal)

Methane is a powerful greenhouse gas and an important energy source. The global significance and impact in coastal zones of methane gas accumulation and seepage in sediments from coastal lagoon environments are still largely unknown. This paper presents results from four high-resolution seismic surveys carried out in the Ria de Aveiro barrier lagoon (Portugal) in 1999, 2002 and 2003. These comprise three chirp surveys (RIAV99, RIAV02, RIAV02A) and one boomer survey (RIAV03). Evidence of extensive gas accumulation and seepage in tidal channel sediments from the Ria de Aveiro barrier lagoon is presented here for the first time. This evidence includes: acoustic turbidity, enhanced reflections, acoustic blanking, domes, and acoustic plumes in the water column (flares). The stratigraphy and structural framework control the distribution and extent of gas accumulations and seepage in the study area. In these shallow systems, however, tidal altitude variations have a significant impact on gas detection using acoustic methods, by changing the raw amplitude of the enhanced seismic reflections, acoustic turbidity, and acoustic blanking in gas-prone areas. Direct evidence of gas escape from drill holes in the surrounding area has shown that the gas present in the Ria de Aveiro consists of biogenic methane. Most of the gas in the study area was probably generated mainly in Holocene lagoon sediments. Evidence of faults affecting the Mesozoic limestones and clays underlying some of the shallow gas occurrences, and the presence of high-amplitude reflections in these deeper units raise the possibility that some of this gas could have been generated in deeper sedimentary layers, and then migrated upward through the fractured Mesozoic strata.     

Physical forcing of onshore transport of crab megalopae in the northern Portuguese upwelling system

Wind-driven circulation is a mechanism that may be involved in the shoreward transport of invertebrate larvae. This study investigated the temporal variability of the supply of crab megalopae to an estuary located in the northwest coast of Portugal, which is affected by seasonal upwelling, and related variations in supply to several upwelling indices. Megalopae of the European common shore crab Carcinus maenas (L.). were collected daily, using artificial settlement substrates, during a 3-month period, from March 15 to June 15, 2000. Two settlement episodes were detected, which were consistent with the variation in abundance and size of juvenile crabs. Variations in subtidal sea level and sea surface temperature anomaly were correlated with the strength of along-shore wind stress and consistent with upwelling theory. Contingency analyses showed positive significant associations between increasing intensity of southerly winds and megalopal supply, for time lags of 0–6 d, indicating that shoreward transport occurred during relaxation or reversal of upwelling favourable winds. Associations between megalopal supply and tidal range or the duration of nocturnal flood were not detected. Compared to other studies of the supply of crab megalopae to coastal habitats that used a similar methodology, very low numbers of megalopae were collected during this study. The paucity of C. maenas megalopae in the Ria de Aveiro is in agreement with the low densities of this larval stage in the plankton, and indicates that maintenance of the population is achieved despite a low supply of megalopae.     

Suitability of GNSS for analysis of soil subsidence in Recife in a highly urbanized coastal area

Natural Hazards - Recife Metropolitan Region, in the northeast of Brazil, is formed by a coastal plain bounded by hills and by the Atlantic Ocean. Recife Metropolitan Region has about 4 million...     

Tectonic Control of the Triassic Santa Maria Supersequence of the Paraná Basin, Southernmost Brazil, and its Correlation to the Waterberg Basin, Namibia

The Middle and Late Triassic Santa Maria Basin, exposed in southernmost Brazil, and Waterberg Basin, in Namibia, are herein interpreted as part of en échelon small basins in southern West Gondwana. The main structures are the Waterberg-Omaruru Fault which can be connected to a NW-strike anastomosed fault zone in Brazil. Based on field structural and stratigraphic analysis two populations of NW-strike fractures, named A-type and B-type, are recognized. A-type fractures (Az = 280°-290°) occur in the Sanga do Cabral Supersequence, underlying units of Santa Maria Basin, as extension of the Waterberg-Omaruru Fault during the Early Triassic. B-type fractures (Az = 295°-345°) are observed in all studied stratigraphic units, from the Triassic Sanga do Cabral Supersequence to the Early Cretaceous Botucatu/Serra Geral formations. Based on the structural analysis we propose that NNE-SSW extension reactivated structures of the Damara Belt, Namibia, with a propagation towards Rio Grande do Sul State forming an anastomosing normal fault system and related-rift basin by Early-Middle Triassic time. The A-type fractures were preferentially active by this phase and the B-type ones are interpreted as secondary link segments within the anastomosing system. During the Gondwana break-up and South Atlantic opening (rift to proto-oceanic phase, Aptian) the B-type fractures were reactivated as normal faults by N50°E-S50°W extension.     

The influence of tidal action on porewater nitrate concentration and dynamics in intertidal sediments of the Sado estuary

The change in porewater nitrate (NO₂ ^? + NO₃ ^?) concentrations during exposure of intertidal sediment was studied at a fixed location in the Sado estuary, southwest Portugal, in November 1994. In order to follow nitrate concentration and dynamics from pre-ebb to post flood, during the day, high vertical resolution profiles (0.2 cm) were studied. As a complement, in February 1995, potential nitrification rates in the sediment were measured by laboratory incubations, with high vertical resolution (0.2 cm) up to 3 cm depth. Oxygen penetration was measured with polarographic mini-electrodes. The sediment’s texture as well as the organic matter composition in carbon and nitrogen were studied in deeper (30 cm) cores. In February 1993,²¹⁰Pb activity depth profiles were measured in a core sampled at the beginning of exposure, in order to evaluate the possibility of nonlocal particle exchange. C:N ratios and²¹⁰Pb activity profiles show evidence of nonlocal exchange of solid phase particles between the surface and deeper sediment, most likely due to macrofaunal activity. As a consequence, fresh organic matter is brought from the surface to 7–9 cm depth, causing enhancement of nutrient concentrations. Results of this study suggest nitrate dynamics in intertidal sediments of the Sado estuary are strongly influenced by tidal action. Periodic submersion and exposure allow for the diversification of pathways of oxygen supply to the sediment. Tidal stress at the sediment-water interface during the arrival (flooding) and departure (exposure) of the tidal front at the site has an important bearing on the effective depth of the nitrification zone. A denitrification rate of 2.16 μmol N dm^?5 h^?1 was measured directly from the nitrate inventory in the 1.5–6 cm depth layer. The schematic model of N cycling in these sediments suggests that 20% of the N pool is denitrified during exposure, and that this process is limited by O₂ availability for nitrification.     

The Stellar Content of Active Galaxies

We present the results of a long-slit spectroscopic study of 38 active and four normal galaxies. Stellar absorption features, continuum colours and their radial variations are analysed in an effort to characterize the stellar population in these galaxies and detect the presence of a featureless continuum underlying the starlight spectral component. Spatial variations of the equivalent widths of conspicuous absorption lines and continuum colours are detected in most galaxies. Star-forming rings, in particular, leave clear fingerprints in the equivalent widths and colour profiles. We find that the stellar populations in the inner regions of active galaxies present a variety of characteristics, and cannot be represented by a single starlight template. Dilution of the stellar lines by an underlying featureless continuum is detected in most broad-lined objects, but little or no dilution is found for most of the 20 type 2 Seyferts in the sample. Colour gradients are also ubiquitous. In particular, all but one of the observed Seyfert 2s are redder at the nucleus than in its immediate vicinity. Possible consequences of these findings are briefly outlined.     

Single Particle Characterisation of the Aerosol in the Marine Boundary Layer and Free Troposphere over Tenerife, NE Atlantic, during ACE-2

In the framework of the 2nd Aerosol Characterization Experiment (ACE-2), in June and July 1997, size segregated samples were collected for single particle analysis on the island of Tenerife, in both the marine boundary layer (MBL) and the free troposphere (FT), to study the characteristics of the North Atlantic aerosol. A systematic assessment was made of the aerosol under background conditions and when the environment was perturbed by European emissions and/or Saharan dust. The aerosol particles were analysed by automated and manual SEM-EDX, followed by cluster analysis to identify the different particle types and their abundance. Basing on back trajectory calculations, particle numbers and volume concentrations, different periods can be identified regarding the origin of the sampled air masses. In the FT, the air masses were classified as clean Atlantic, Saharan dust from Africa or pollution from Europe. In the MBL, air masses were classified as clean, polluted or perturbed by emissions from Europe. For both the FT and MBL samples, the main changes in chemical composition were observed between the fine and coarse mode aerosol. The FT fine mode aerosol is dominated by S-poor aluminosilicates (62%) in the event of the dust samples or sulphates, carbonaceous particles (20%) and S-rich aluminosilicates (46%) in the polluted samples. For the larger fractions, a strong decreasing trend was observed for the sulphates (less than 20%) and carbonaceous particles (10%) in the polluted samples. The MBL fine mode was completely dominated by S-rich particles (polluted 55% and perturbed 59%), and to a lesser extent, carbonaceous and aged sea salt particles. In the coarse mode, the polluted air mass is dominated by sea salt particles (62%). Contrary to the fine fraction, the polluted air mass in the coarse fraction contained 5.3% of S-rich particles. The combined interpretation of the data from the analysis of size-fractioned particles and the calculated backward trajectories for air masses coming from Europe, Africa and the Atlantic, results in better insights on aerosol chemistry, especially for the comparison of the particle composition in the FT and the MBL.     

Impact of a Saturation-Dependent Dissipation Source Function on Operational Hindcasts of Wind-Waves in the Australian Region

The impact of a modified parametric form of the dissipation source function S ds on the skill of an operational spectral wind-wave model is investigated. Numerical experiments are made with a version of the WAM model presently used operationally by the Australian Bureau of Meteorology to produce sea-state forecasts within the Australian region. Performances of wave hindcasts obtained using several alternative forms of this newly proposed dissipation source function are compared to those produced with forms of S ds commonly used operationally. A new ad hoc technique to compare modelled and observed wave spectra is introduced to assess the quality of calculated one-dimensional frequency spectra.

Our results indicate that wave model performance in terms of integral spectral parameters, such as the significant wave height H s , may benefit from improved parameterisations of the dissipation source term S ds . On the other hand, we also found that model performance was relatively poor in terms of predictions of the one-dimensional frequency spectrum, regardless of the chosen form of S ds . These results suggest that further refinements of the dissipation source term are strongly dependent on improved parametrisations of the nonlinear interactions source term S nl .     

Improved imaging of a karst aquifer using focused source electromagnetic and differentially normalized method: a qualitative analysis

Geophysical investigations using conventional techniques applied to groundwater exploration can often present strong limitations involving high financial costs, complex acquisition logistics and high ambiguity in results. Dispersion of the electric current flow, induced polarization) effects, cultural noises and shallow lateral heterogeneities represent the main problems faced by geoelectric methods in these types of surveys. Moreover, elements such as intrusions and mineralization at different depths may be responsible for signal attenuation as well as high resistivity in unsaturated zones and complex three-dimensional formations or clayey zones cause variations in the electric current. The focused source electromagnetic and differentially normalized method approaches can help to solve some these issues. Aiming at a higher signal-to-noise ratio, the focused source electromagnetic method and approaches of the differentially normalized method, first applied to petroleum exploration, are tested on a groundwater target, in a karst environment sectioned by a diabase dyke. We performed the processing and analysis on real IP resistivity profiling data acquired with two-way dipole-dipole array, guided by magnetic data acquired on the same profile, mapping a diabase dyke. The inversion of focused source electromagnetic method/differentially normalized method was not performed, instead that we converted the induced polarization–resistivity data to a differential signal to qualitatively prove the presence of aquifer. Joint interpretation of focused source electromagnetic method curves and inverted two-dimensional induced polarization–resistivity sections allowed for precise delineation of a conductive zone associated with the karst aquifer, le magnetics allowed for the definition of a neighbour dyke. The techniques have great potential in the aid of groundwater exploration, contributing substantially to the reduction of interpretation ambiguity. Focused source electromagnetic method/differentially normalized method/ approaches show that a simple linear combination of the conventional geoelectric data is able to remove the geological noise and provide the vertical focusing of the electric current.