Production of bioavailable and refractory dissolved organic matter by coastal heterotrophic microbial populations

Production of dissolved organic matter (DOM) by heterotrophic microbial communities isolated from Loch Creran (Scotland) was studied in time course incubations in which cells were re-suspended in artificial seawater amended with variable proportions of glucose, ammonium and phosphate. The incubation experiments demonstrated that microheterotrophs released part of the substrate as new DOM, with a production efficiency of 11 ± 1% for DOC, 18 ± 2% for DON and 17 ± 2% for DOP. Estimating the impact of this production in Loch Creran, showed that from 3 ± 1% (DOC) to 72 ± 16% (DOP) of DOM could originate from the heterotrophic microbial community. The produced DOM (PDOM) was both bioavailable (BDOM) and refractory (RDOM). Bioavailability as assessed by the difference between the maximum and the end DOM concentration, was generally higher than found in natural systems, with DOP (73 ± 15%, average ± SD) more bioavailable than DON (70 ± 15%), and DON than DOC (34 ± 13%).The stoichiometry of PDOM was linked to both nutrient uptake and BDOM ratios. Absorption and fluorescence of DOM increased significantly during the incubation time, indicating that microheterotrophs were also a source of coloured DOM (CDOM) and that they produce both bioavailable protein-like and refractory humic-like fluorophores.     

The formation of farm mounds on the Island of Sanday,Orkney

A recent archaeological site survey of the island of Sanday on Orkney has identified a distinct concentration of 15 farm mounds. An immediate need is to determine the nature, age, and processes of formation of these very distinctive landform features. This paper reports a geoarchaeological investigation of three mounds at Westbrough, Langskaill, and Skelbrae. For the island as a whole, the mounds vary in diameter from 50 to 205 m, with deposits up to a thickness of 4.3 m. The mounds vary in their morphology, reflecting complex processes of accumulation, often intense disturbance, and in some cases, erosion by the sea. Sections at the three sites are described with analytical data also being given for particle size, percent loss-on-ignition, total phosphate, δ¹³C, and radiocarbon dating. The Westbrough and Skelbrae mounds were formed post-7th century A.D.; more detailed dating was possible for the Langskaill site, which was initiated in the early to mid 13th century. A steady and relatively rapid sedimentation rate (ca. 1.9 cm year⁻¹) took place over the 200 years following the initiation of the mound. The lower part of the Westbrough mound is distinguished by the presence of peat, interpreted as discarded bedding material, but the remainder of the investigated sections are composed dominantly of mineral sediments containing organic matter of terrestrial origin. It is suggested that these materials accumulated from the ash of domestic hearths as well as from the residues of bedding material from the byres (cattle sheds). Turves (vegetation plus some underlying soil) would have been cut, dried, and then used in the byres and such turves would have retained a significant mineral content. The implication is that the inherent fertility of the island made it unnecessary for the farmers to spread the dung over the fields. This may explain why there is the distinct concentration of these mounds on the island of Sanday, an island noted in earlier times for its fertile soils developed on calcareous sands.     

Investigating model performance and parameter sensitivity for runoff simulation across multiple events for a large green roof

Green roofs are a form of green infrastructure aimed at retaining or slowing the movement of precipitation as stormwater runoff to sewer systems. To determine total runoff versus retention from green roofs, researchers and practitioners alike employ hydrologic models that are calibrated to one or more observed events. However, questions still remain regarding how event size may impact parameter sensitivity, how best to constrain initial soil moisture (ISM), and whether limited observations (i.e., a single event) can be used within a calibration-validation framework. We explored these questions by applying the storm water management model to simulate a large green roof located in Syracuse, NY. We found that model performance was very high (e.g., Nash Sutcliffe efficiency index > 0.8 and Kling-Gupta efficiency index > 0.8) for many events. We initially compared model performance across two parameterizations of ISM. For some events, we found similar performance when ISM was varied versus set to zero; for others, varying ISM yielded higher performance as well as greater water balance closure. Within a calibration-validation framework, we found that calibrating to larger events tended to produce moderate to high performance for other non-calibration events. However, very small storms were notoriously difficult to simulate, regardless of calibration event size, as these events are likely fully retained on the roof. Using regional sensitivity analysis, we confirmed that only a subset of model parameters was sensitive across 16 events. Interestingly, many parameters were sensitive regardless of event size, though some parameters were more sensitive when simulating smaller events. This emphasizes that storm size likely influences parameter sensitivity. Overall, we show that while calibrating to a single event can achieve high performance, exploring simulations across multiple events can yield important insight regarding the hydrologic performance of green roofs that can be used to guide the gathering of in situ properties and observations for refining model frameworks.     

西藏高原测站降水与TRMM估测降水一致性评估

利用124个测站2011—2012年6—8月逐小时降水资料,分辨率为0.25°×0.25°的TRMM估测降水和DEM 高程数据,采用相关系数、相对误差和准确性指标,分析了西藏高原TRMM估测降水整体表现能力及海拔高度对降水估测影响。结果表明：TRMM估测降水在西藏高原整体趋势较一致,降水量级偏大,次数偏多;平均无降水准确率远高于平均有降水准确率,漏测率低而空测率高,降水量大的测站TRMM估测能力相对强。西藏高原上大部分测站处于相对低洼（河谷）地带,海拔高度差较小的区域TRMM估测降水与测站降水误差小,较大的区域误差则大。     

GIS技能竞赛辅助“空间分析与建模”教学的探索与实践

本文在简介“空间分析与建模”教学概况的基础上,分析了高校进行“空间分析与建模”教学的教学目标,通过指导学生参加高校GIS技能竞赛,结合竞赛依托平台进行技能与技巧的培训和指导,并将参赛实践引入到“空间分析与建模”的课程教学中,使得教学与竞赛相结合,促进了“空间分析与建模”教学的改革,使该课程教学始终与全国性学生竞赛实践紧...     

Extreme alkali bicarbonate- and carbonate-rich fluid inclusions in granite pegmatite from the Precambrian Rønne granite,Bornholm Island,Denmark

Our study of fluid and melt inclusions in quartz and feldspar from granite pegmatite from the Precambrian Rønne granite, Bornholm Island, Denmark revealed extremely alkali bicarbonate- and carbonate-rich inclusions. The solid phases (daughter crystals) are mainly nahcolite [NaHCO₃], zabuyelite [Li₂CO₃], and in rare cases potash [K₂CO₃] in addition to the volatile phases CO₂ and aqueous carbonate/bicarbonate solution. Rare melt inclusions contain nahcolite, dawsonite [NaAl(CO₃)(OH)₂], and muscovite. In addition to fluid and melt inclusions, there are primary CO₂-rich vapor inclusions, which mostly contain small nahcolite crystals. The identification of potash as a naturally occurring mineral would appear to be the first recorded instance. From the appearance of high concentrations of these carbonates and bicarbonates, we suggest that the mineral-forming media were water- and alkali carbonate-rich silicate melts or highly concentrated fluids. The coexistence of silicate melt inclusions with carbonate-rich fluid and nahcolite-rich vapor inclusions indicates a melt-melt-vapor equilibrium during the crystallization of the pegmatite. These results are supported by the results of hydrothermal diamond anvil cell experiments in the pseudoternary system H₂O–NaHCO₃–SiO₂. Additionally, we show that boundary layer effects were insignificant in the Bornholm pegmatites and are not required for the origin of primary textures in compositionally simple pegmatites at least.     

Ferruginous thermal spring complexes, northwest Tasmania: evidence that far-field stresses acting on a fracture mesh can open and maintain vertical flow in carbonate terrains

Far-field stress changes in the southern Australian plate since 5 Ma have produced significant areas of uplift and seismicity. In northwest Tasmania, there is evidence that this stress reorientation to maximum horizontal NW?CSE stress has influenced meteoric-derived thermal (15?C20°C) discharge patterns of confined karstic aquifers, by placing pre-existing NW-trending faults/fractures into a dilated state or a critically stressed state. Previous studies have shown that spring discharge has operated continuously for at least 65,000 years, and has transported large volumes of solutes to the surface to be deposited as mounds of calcite-goethite-silica up to 7 m high. The thermal spring chemistry at one site, Mella, is consistent with descent to at least 1.2?C1.5 km, although the hinterland within 50 km is less than 500 m elevation. Thermal spring chemistry is consistent with most of the deep water?Crock interaction occurring in low-strontium Smithton Dolomite. While some of this water is discharged at springs, some instead intersects shallow zones of NE-fracture-controlled rock (2?×?4 km in area) with karstic permeability where, although confined and subject to a NE-directed hydraulic gradient, it circulates and cools to ambient temperature, with only minor mixing with other groundwaters.     

Long-term regional hurricane hazard analysis for wind and storm surge

This paper introduces a new method to estimate the long-term regional hurricane wind and storm surge hazard. The output is a relatively small set of hurricane scenarios that together represent the regional hazard. For each scenario, the method produces a hazard-consistent annual occurrence probability, and wind speeds and surge levels throughout the study area. These scenarios can be used for subsequent evacuation or loss estimation modeling. This optimization-based probabilistic scenario (OPS) method involves first simulating tens of thousands of candidate hurricane scenarios with wind speeds and approximate surge depths. A mixed-integer linear optimization is then used to select a subset of scenarios and assign hazard-consistent annual occurrence probabilities to each. Finally, a surge model is used to estimate accurate surge depths for the reduced set of events. The method considers the correlation between winds and surge depths and the spatial correlations of each; it is computationally efficient; and it makes explicit the tradeoff between the number of scenarios selected and the errors introduced by using a reduced set of events. A case study for Eastern North Carolina is presented in which a final set of 97 hurricanes provides unbiased results with errors small enough for many practical uses.