Hydrologic separation and their contributions to N loss in an agricultural catchment in hilly red soil region

The impacts of hydrological processes on N loss is of great value to understand the N transport at catchment scale,which is far from clear. Rainfall, soil water, groundwater and stream water and their N concentrations were monitored from March 2017 to February 2018 in Sunjia agricultural catchment of the red soil critical zone. Objectives of this study were:(1) to determine the dynamics of N concentration of different waters and their N loads;(2) to assess their contributions to N load of streamflow in the paddy and upland mixed agricultural catchment. Our results showed that the N concentrations of soil water(4.8 mg L~(-1)) and groundwater(6.0 mg L~(-1)) were the highest, approximately 2 to 5 times higher than those of stream water(2.7 mg L~(-1)), rain water(1.7 mg L~(-1)) and irrigation water(1.2 mg L~(-1)). The N net loss of the catchment(38.2 kg ha~(-1) yr~(-1))accounted for 15% of the total fertilizer N input. Rainy season(April–June) was a high-risk period of N loss, contributing to more than one third of the total annual loss amount. Using end-member mixing analysis model(EMMA), we found groundwater(whose discharge accounted for 25% of the catchment streamflow) was an important source for the N loss in the agricultural catchment. Even in this catchment with coexisting upland and paddy field ecosystems, identified end-members could be used to predict the N load well(R~20.87, p0.001). These results can deepen our understanding of the relationship between hydrological process and N transport in the red soil critical zone and are also helpful to improve the water and fertilizer management in subtropical agricultural catchment.     

近海地下石油储备库海水入侵风险研究

地下石油储备库于近海处建立,可降低石油运输成本,同时有较强的军事意义。但是临近海岸线,海水易入侵库区,导致库区内金属结构腐蚀,使储备库的使用年限降低。以某近海地下石油储备库工程为背景,构建了综合断层、节理密集带、导水通道等15种地质结构的精细化三维水文地质模型,研究了库区自然状态下和运行期的地下水渗流场及溶质运移场,模拟海水入侵风险。研究表明：（1）自然状态下地下石油储备库无海水入侵。（2）运行期只在洞库顶部以上25 m处设置四周超出洞室50 m、水幕孔间距为10 m、孔径0.11 m的水平水幕时,不能有效防治海水入侵。（3）洞库运行9 a时,3#洞室东南侧Cl−物质的量浓度超过7 mol/m3,海水开始入侵洞室群;运行22~23 a时,海水入侵速率最快;运行41 a 时,3#洞室东南侧Cl−物质的量浓度超过143 mol/m3,海水入侵达到对钢筋的强腐蚀程度;运行50 a时,除1#洞室外其余所有洞室均受到海水入侵,3#、4#洞室有部分区域达到强腐蚀程度,海水入侵最严重。建议增设垂直水幕等设施,以增强对海水入侵的防治。研究成果可为近海地区地下石油储备库抑制海水入侵提供借鉴。     

Evaporation from seasonally frozen bare and vegetated ground at various groundwater table depths in the Ordos Basin,Northwest China

In cold climates, the process of freezing–thawing significantly affects the ground surface heat balance and water balance. To better understand the mechanism of evaporation from seasonally frozen soils, we performed field experiments at different water table depths on vegetated and bare ground in a semiarid region in China. Soil moisture and temperature, air temperature, precipitation, and water table depths were measured over a 5‐month period (November 1, 2016, to March 14, 2017). The evaporation, which was calculated by a mass balance method, was high in the periods of thawing and low in the periods of freezing. Increased water table depth in the freezing period led to high soil moisture in the upper soil layer, whereas lower initial groundwater levels during freezing–thawing decreased the cumulative evaporation. The extent of evaporation from the bare ground was the same in summer as in winter. These results indicate that a noteworthy amount of evaporation from the bare ground is present during freezing–thawing. Finally, the roots of Salix psammophila could increase the soil temperature. This study presents an insight into the joint effects of soil moisture, temperature, ground vegetation, and water table depths on the evaporation from seasonally frozen soils. Furthermore, it also has important implications for water management in seasonally frozen areas.     

河南栾川南泥湖和上房沟花岗岩体黑云母成分特征及其成岩成矿意义

河南栾川南泥湖和上房沟花岗岩体与钼多金属成矿作用密切相关。本文用电子探针测试方法,分析了南泥湖岩体和上房沟岩体中黑云母的成分特征。结果表明,2个岩体中黑云母均具有高硅、富镁、低铝和贫铁的特征,属镁质黑云母。2个岩体的结晶温度分别为730~830℃和750~860℃,氧逸度(logfO2)分别为-8.5~-7.0和-8.0~-6.5,结晶压力和深度分别为72~120MPa、54~127MPa和2.62~4.37km、1.97~4.63km,有利于南泥湖-三道庄和上房沟超大型钼矿床的形成,地球化学特征显示2个岩体均属壳幔混源的Ⅰ型花岗岩,属深源中浅成花岗岩。     

Physicochemical Conditions of the Formation of Beryl and Aquamarin in Mufushan Granopegmatite Deposit,Hunan Province,China

The formation of the Mufushan granopegmatite was closely related to the Late Yenshanian multiphase and multistage magmatic activities,More than one generation of beryl and aquamarine occur in different types of pegmatite in the granites.The presence of melt and melt-fluid inclusions strongly indicates a melt-solution character of the pegmatitic magma.Forming temperatures of the different generations of beryl in a Na^ -K^ ,Ca^2 -CO3^2--Cl^--SO4^2- solution ranges from 990℃to 200℃.Aquamarine was formed at 720-180℃.The contents of alkali metals(Na^ K^ )in th ore-formming solution of aquamarine are lower than those in the beryl,but the contents of alkali earths(Ca) and salinity are higher,The granite was generated by remelting of the basement formation(meta-sedimentary rocks of the Lengjiaxi Group)which also served as the source of ore-forming material.Beryllium in the pegmatite was transported mainly in the form of Na[Be(CO3)2],with part of it being complexed with Cl^- and SO4^2-.During the generation and evolution of the pegmatite,equilibrium might have been reached in the solid-melt-fluid or solid-fluid system.The intergranular solutions may have reacted with the early crystallized minerals,resulting in potash-feldsparization,albitization and muscovitization during which the ore-forming elements were mobilized and transported in favour of ore deposition.     

海洋生态环境监测传感器的应用与发展

受人类活动的影响,海洋污染日益严重。我国海岸带、河口和海湾生态系统均受到了不同程度的破坏。海洋生态环境监测传感器的应用可实现实时海洋环境的监测和快速预警,对于预防海洋灾害、调节海洋经济发展与环境之间的矛盾有重要意义。文中归纳了海洋生态环境类传感器所应用的分析检测技术,总结了目前所研发的各类海洋生态环境传感器,预测了传感器的发展趋势,并对我国未来传感器的研究工作提出了建议。     

基于不等式约束的三维电阻率探测混合反演方法

三维电阻率探测的线性反演和非线性反演中均存在着多解性的固有难题.电阻率线性反演方法的效率较高,但反演结果对初始模型的依赖性较强,易陷入局部极小;而非线性反演方法不依赖初始模型,但搜索效率极低,尚未见到关于三维电阻率非线性反演的文献.针对上述问题,融合线性与非线性反演方法的互补优势,提出了最小二乘法（线性方法）与改进遗传算法（非线性方法）相结合的混合反演方法的概念和思想.首先,提出了将介质电阻率变化范围作为不等式约束引入反演方程的思路,以实现压制多解性、提高可靠性的目标.提出了宽松不等式约束和基于钻孔推断的局部严格不等式约束的获取及定义方法.在此基础上,分别提出了基于不等式约束的最小二乘线性反演方法和遗传算法非线性反演方法.其次,对于遗传算法在变异搜索方向控制、初始群体产生等方面进行了改进,优化了其搜索方向和初始群体多样性.然后,提出了混合反演方法及其实现方案,利用改进遗传算法进行第一阶段反演,发挥其对初始模型的依赖程度低的优势,搜索到最优解附近的空间,输出当前最优个体;利用最小二乘法进行第二阶段反演,将遗传算法得到的当前最优个体作为初始模型,在最优解附近空间执行高效率的局部线性搜索,最终实现地电结构的三维成像.最后,开展了合成数据与实际工程算例验证,与传统最小二乘方法进行了对比,发现混合反演方法在压制多解性、摆脱初始模型依赖和提高反演效果方面有较好效果.

     

山东济宁高硫煤与低硫煤煤层剖面地球化学特征研究

运用电感耦合等离子质谱（ICP-MS）、X射线荧光光谱（XRF）、离子选择电极（ISE）、显微镜光度计和煤化学等方法,对山东济宁矿区的高硫煤（太原组16号煤层）与低硫煤（山西组3上煤层）剖面的煤岩、煤质和煤地球化学特征进行研究。高硫煤中微量元素在垂向上呈现显著的变化规律：（1）Sr含量从煤层底板到顶板呈增高趋势,而Ba含量则相反;因而Sr/Ba比值从下向上呈逐渐变大趋势（0.04～47.7）;（2）Th/U比值从下向上也呈逐渐变大趋势（0.2～37.1）;（3）As含量在煤层顶板石灰岩（26.1μg/g）、透镜状黄铁矿夹层（14.7～19.3μg/g）中较高;（4）V、Cr、Co、Ni、Cu、Pb、Zn等元素在煤层底部和顶部分层中含量较高,而在煤层中部分层中含量较低;（5）Nb、Ta、Zr、Hf、Ga等元素从煤层的底部到顶部呈逐渐降低趋势;（6）煤中稀土元素总量（REE）,除透镜状黄铁矿夹层（第2、4、11分层）外,其它分层（第1、3、5、6、7、8、9、10分层）显示从上往下逐渐增高之规律性。低硫煤中微量元素的分布和垂向变化与高硫煤明显不同：As含量在14个煤分层中都较低（1.03～3.37μg/g）,Sr/Ba比值从下向上变化不大（0.4～2.2）,各个煤分层中稀土元素总量（REE）呈现随灰份含量增高而增高的变化趋势,低硫煤与高硫煤的稀土元素分布模式差别很大。上述研究结果表明济宁矿区高硫煤与低硫煤在地球化学特征上的差别,反映了上石炭统太原组与下二叠统山西组沉积环境和聚煤条件的差别,具有指相意义;太原组16号煤层中富集的硫及有害微量元素,对环境具有潜在危害。     

新疆库车盆地钾盐科探1井含盐系地球化学特征及找钾指示

在盐湖沉积演化过程中,钾盐矿物在盐类沉积的中晚期阶段才开始析出。因此,研究含盐系盐类的沉积地球化学特征,不仅可以从侧面获取岩盐的沉积物源和成盐古卤水蒸发浓缩程度等地球化学信息,而且更能揭示古盐湖钾盐富集趋势。文章通过对库车盆地钾盐科探1井钻取的岩芯样品进行高精度采样测试,得出岩盐中Mg×103/Cl、K×103/Cl、Li×103/Cl与K+、Mg2+、Li+、Ca2+、Cl-含量的垂向变化规律。并与库车盆地其他钻孔中的岩盐含钾性进行对比,同时,依据钻井剖面岩性特征,与潜江凹陷和大汶口凹陷含盐系剖面进行对比,论述研究区成盐的地球化学特征,对其钾盐成矿前景进行分析和评价。     

河北省崇礼幅1∶50 000矿产地质图数据库

根据《固体矿产地质调查技术要求(1∶50 000)》(DD 2019-02)和行业其他规范要求,完成河北省崇礼幅1∶50 000专项地质填图379.93 km²、矿点检查11处,采集水系沉积物样品1622件、重力测量物理点1623个,测试锆石U-Pb年龄样3组、流体包裹体样80余件,系统编制了河北省崇礼幅1∶50 000矿产地质图,并建立了数据库。突出了对燕山期岩浆岩和相关脉岩、碱性杂岩体和谷嘴子岩组、矿化蚀变等相关成矿信息的表达,厘定了崇礼幅中太古代、新太古代的变质深成侵入体,划分了海西期、印支期、燕山期的岩浆岩建造类型,划分了张家口组火山岩的7个建造类型、谷嘴子岩组变质岩的3个建造类型,系统总结了该区金矿的成矿地质体、成矿构造及成矿结构面、成矿作用特征标志。该数据库为该区金矿的找矿工作提供了基础数据支撑,对金矿目标层地质信息和构造建造信息的提取提供了便利条件,对今后矿产勘查部署具有一定的参考价值。