PLASMA CHEMISTRY OF METEORITES—I. CLEANSING AND REDUCTION OF THE ODESSA IRON METEORITE

Three small samples of the Odessa, Texas iron meteorite, two surrounded by sandy soil, were introduced into a hydrogen plasma. The soil was effectively cleansed from the iron surfaces, being substantially destroyed with only a fine dust remaining. The appearance of the iron meteorite samples indicated that the terrestrial oxidation was reversed, probably to magnetite, Fe₃O₄, and metallic iron.     

CLASSIFICATION:OLDTIMERS AND NEWCOMERS

Classification and regression techniques are among the most used tools by chemometricians.Withclassification,the two classic methods are discriminant analysis and SIMCA.In this paper we discuss theconnection between these two methods and introduce two new ones of the same family:DASCO(discriminantanalysis with shrunken covariances)and RDA(regularized discriminant analysis).We demonstrate on bothsimulated and real data sets that their performance is superior to the old favorites.This is especially truein small-sample/high-dimension settings typical in chemistry.     

Insolation, Moisture Balance and Climate Change on the South American Altiplano Since the Last Glacial Maximum

Sediment cores from Lake Titicaca contain proxy records of past lake level and hydrologic change on the South American Altiplano. Large downcore shifts in the isotopic composition of organic carbon, C/N, wt.%C_org, %CaCO₃, and % biogenicsilica illustrate the dynamic changes in lake level that occurred during the past 20,000 years. The first cores taken from water depths greater than 50 meters in the northern subbasin of the lake are used to develop and extend the paleolake-level record back to the Last Glacial Maximum (LGM). Quantitative estimates of lake level are developed using transfer functions based on the ¹³C of modern lacustrine organic sources and the ¹³C of modern sedimented organic matter from core-tops. Lake level was slightly higher than modern during much of the post-LGM (20,000–13,500 yr BP) and lake water was freshunder the associated outflow conditions. The Pleistocene/Holocene transition (13,500–7,500 yr BP) was a period of gradual regression, punctuated by minor trangressions. Following a brief highstand at about 7250 yr BP, lake level dropped rapidly to 85 m below the modern level, reaching maximum lowstand conditions by 6250 yr BP. Lake level increased rapidly between 5000yr BP and 4000 yr BP, and less rapidly between 4000 yr BP and 1500 yr BP.Lake level remained relatively high throughout the latest Holocene with only minor fluctuations (<12 meters). Orbitally induced changes in solar insolation, coupled with long-term changes in El Niño-Southern Oscillation variability, are the most likely driving forces behind millennial-scale shifts in lake level that reflect regional-scale changes in the moisture balance of the Atlantic-Amazon-Altiplano hydrologic system.     

Sediment community metabolism associated with continental shelf hypoxia, Northern Gulf of Mexico

Net fluxes of respiratory metabolites (O₂, dissolved inorganic carbon (DIC), NH₄ ⁺, NO₃ ^?, and NO₂ ^?) across the sediment-water interface were measured using in-situ benthic incubation chambers in the area of intermittent seasonal hypoxia associated with the Mississippi River plume. Sulfate reduction was measured in sediments incubated with trace levels of³⁵S-labeled sulfate. Heterotrophic remineralization, measured as nutrient regeneration, sediment community oxygen consumption (SOC), sulfate reduction, or DIC production, varied positively as a function of temperature. SOC was inversely related to oxygen concentration of the bottom water. The DIC fluxes were more than 2 times higher than SOC alone, under hypoxic conditions, suggesting that oxygen uptake alone cannot be used to estimate total community remineralization under conditions of low oxygen concentration in the water column. A carbon budget is constructed that compares sources, stocks, transformations, and sinks of carbon in the top meter of sediment. A comparison of remineralization processes within the sediments implicates sulfate reduction as most important, followed by aerobic respiration and denitrification. Bacteria accounted for more than 90% of the total community biomass, compared to the metazoan invertebrates, due presumably to hypoxic stress.     

Variable Energy Explosives for Soft Ground Blasting

A range of bulk explosives, the NOVALITE range hay been specifically developed for soft ground blasting. These explosives can be used in both wet and dry blasting conditions, range in density from 0.3-1.2 g/cc and range in VoD from 2-4.5 km/s. This range of explosives hay the potential to be tailored to ground type and is predicted to be suitable for a variety of applications which include: blasting in soft to medium overburden, coal blasting, wall control, and low vibration blasting. Trials have been conducted in several applications with encouraging results. Several cast/throw blasts have been conducted with these products partially replacing either ANFO or Heavy ANFO. The results from the blast have been equivalent in cast (per cent) and at reduced cost per unit volume. These products have also been used in presplit blasting and have again achieved equivalent or better results when compared to conventional presplit blasting at a lower cost per unit volume. This product has also been used in a vibration sensitive area replacing traditional explosive products, and generating excellent fragmentation and digging whilst maintaining vibration limits. This new range of products, NOVALITE, has shown great potential in many applications either reducing cost per unit volume, improving wall quality or improving productivity in environmentally sensitive areas.     

The relationship of total dissolved solids measurements to bulk electrical conductivity in an aquifer contaminated with hydrocarbon

A recent conceptual model links higher bulk conductivities at hydrocarbon impacted sites to higher total dissolved solids (TDS) resulting from enhanced mineral weathering due to acids produced during biodegradation. In this study, we evaluated the above model by investigating the vertical distribution of bulk conductivity, TDS, and specific conductance in groundwater. The results showed higher TDS at contaminated locations consistent with the above model. Further, steep vertical gradients in bulk conductivity and TDS suggest vertical and spatial heterogeneity at the site. We observed that at fluid conductivities <40 mS/m, bulk conductivity was inversely related to fluid conductivity, but at fluid conductivities >40 mS/m, bulk conductivity increased with increasing fluid conductivity. However, at fluid conductivities >80 mS/m, bulk conductivities increased without a corresponding increase in fluid conductivity, resulting in a poor correlation between bulk conductivity and fluid conductivity for the contaminated samples. This suggests that electrolytic conductivity was not completely responsible for the observed variability in bulk conductivity. We suggest two possible reasons for the inverse relationship at low fluid conductivity and poor positive correlation at high fluid conductivity: (1) geochemical heterogeneity due to biological processes not captured at a scale comparable to the bulk conductivity measurement and (2) variability in the surface conductivity, consistent with a simple petrophysical model that suggests higher surface conductivity for contaminated sediments. We conclude that biodegradation processes can impact both electrolytic and surface conduction properties of contaminated sediments and these two factors can account for the higher bulk conductivities observed in sediments impacted by hydrocarbon.     

Ion Probe Study of Silicate Inclusions from Colomera (ⅡE) Iron Meteorite: the Rare Earth Element Perspective

Coupled with a petrographical study, I carried out an ion probe study of rare earth element microdistributions in mineral phases of silicate inclusions from the Colomera ⅡE iron meteorite. Most mineral grains have homogeneous REEs, but show considerable inter-grain variations by a factor of 2 to 100. The whole rock REE abundances for Colomera, estimated by combining REE data with modal abundances, are relatively LREE-enriched with REEs of -10'CI, which suggest that Colomera silicates were highly differentiated and might represent a low degree partial melt (-10%) of a chondritic source. REE geochemistry of Colomera silicate inclusions points to an origin that involves differentiation, dynamic mixing, remelting, reduction, recrystallization, and subsequent rapid cooling near the surface of a planetary body.     

Stable isotopic fingerprint of a hyporheic–hypolentic boundary in a reservoir

Stable isotopes of H₂O are used to define the hyporheic–hypolentic boundary in Ledbetter Creek as it discharges to Kentucky Lake, a constructed reservoir in western Kentucky, USA. High-resolution (centimeter-scale) sample collection and analysis were utilized to determine one-dimensional variations in δ²H and δ¹⁸O of H₂O and chloride (Cl⁻) across the boundary. During reservoir low stand in winter, the hyporheic–hypolentic zone contains water from Ledbetter Creek and groundwater separated by an interface at ~10 cm below the channel bottom. Following reservoir-stage increase in spring and summer, water from Kentucky Lake infiltrates into the hyporheic–hypolentic zone to a depth of at least 18 cm below the channel bottom. Reservoir-stage decline in autumn causes source-water mixing, largely obscuring the hyporheic–hypolentic boundary. Stable isotopes provide an effective complement to conventional tracers for delineation of water masses within the hyporheic–hypolentic zone.

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Resumen Se han utilizado isótopos estables del agua para definir el límite hiporreico-hipoléntico en Ledbetter Creek, que constituye una zona de descarga del lago Kentucky, una presa construida al Oeste de Kentucky, USA. Se ha llevado a cabo una recogida de muestras de alta resolución (a escala centimétrica) y se utilizaron los resultados para determinar las variaciones unidimensionales en δ²H y δ¹⁸O del H₂O y los cloruros (Cl⁻) alrededor del límite. Durante la época de niveles bajos en invierno, la zona hiporreica-hipolentica tiene agua procedente de Ledbetter Creek y de agua subterránea separada por una interfase de ~10 cm debajo del límite del canal. Siguiendo el incremento de los niveles en la presa en primavera y verano, el agua del Lago Kentucky se infiltra en la zona hiporreica-hipoléntica hasta una profundidad de, al menos, 18 cm bajo el límite hiporreico-hipoléntico. Los isótopos estables aportan un complemento efectivo a los trazadores convencionales para la delimitación de masas de agua dentro de la zona hiporreica-hipoléntica.

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Résumé L’utilisation des isotopes stables de la molécule d’eau a permis de définir l’interface hyporhéique-hypolentique dans la Ledbetter Creek, au point de déversement dans le réservoir artificiel que constitue le Kentucky Lake (Ouest du Kentucky, Etats-Unis). Une campagne de prélèvements à haute résolution (échelle centimétrique) a contribué à déterminer les variations unidimensionnelles des valeurs de δ2H et de δ18O de la molécule d’eau et de la concentration en chlorures (Cl⁻) de part et d’autre de l’interface. En hiver, lorsque le niveau du réservoir est minimal, la zone hyporhéique-hypolentique contient de l’eau de la Ledbetter Creek et de l’eau souterraine, séparées par un interface situé environ 10 cm sous le fond du chenal. Suite aux recharges printanières et estivales, l’eau du Kentucky Lake envahit la zone hyporhéique-hypolentique sur plus de 18 cm sous le fond du chenal. En automne, la baisse de niveau dans le réservoir occasionne un mélange des eaux, rendant diffus l’interface hyporhéique-hypolentique. Les isotopes stables constituent ainsi un complément efficace aux traceurs conventionnels pour la délimitation des masses d’eau dans la zone hyporhéique-hypolentique.

     

Geostatistical integration of near-surface geophysical data

Accurate statics calculation and near‐surface related noise removal require a detailed knowledge of the near‐surface velocity field. Conventional seismic surveys currently are not designed to provide this information, and 3D high‐resolution reflection/refraction acquisition is not feasible for large survey areas. Satellite images and vibrator plate attributes are dense low‐cost data, which can be used in spatially extrapolating velocities from sparse uphole data by geostatistics. We tested this approach in two different areas of Saudi Arabia and found that the optimal recipe depends on the local geology.