First data on U-Pb SHRIMP-II isotopic dating based on zircons of ash sediments from Cenozoic depressions in Southwest of Primorie

U-Pb (SHRIMP-II) isotopic dating has been conducted for zircons of the ash sediments of the Ust’-Suifun Suite, which was the final stage of Late Cenozoic explosive volcanism in Southwest Primorskii krai. These pyroclastic units are widespread within sediments that fill in Cenozoic depressions including large coalfields. The concordant dates (23.7–24.6 Ma) are in line with the results of the K-Ar determinations for volcanic tephra (23.6–27.1 Ma) and correspond to the beginning of the active phase of spreading and taphrogenesis in the neighboring Trench of the Sea of Japan. These processes started as early as the Eocene and are reflected in the continental vicinity with the formation of riftogenic depressions and the occurrence of a peculiar gas volcanism.     

Peculiarities of Dynamic Slip Nucleation in a Thin Granular Layer

Izvestiya, Physics of the Solid Earth - Abstract—Granular media determine the dynamics of many natural systems including faults in the Earth’s crust. The paper addresses the laboratory...     

Campanian stage of granite formation in the south of the Sredinnyi Range in Kamchatka: New U-Pb SHRIMP Data

This article gives an account of the results of the U-Pb-SHRIMP study of zircons derived from gneissoid and equigranular granitoids of the Malka Uplift of the Sredynnyi Range in Kamchatka. It was established that intrusion and crystallization of granitoids occurred in the time interval from 76.2 ± 1.5 to 83.1 ± 2.0 Ma. The texture of zircon crystals suggests their magmatic origin. The obtained data reliably confirm that granite formation and emplacement of the recently formed continental crust in Kamchatka took place in the Late Cretaceous (Campanian).     

Relevance of Pentane- and Hexane-Utilizing Bacterial Indicators for Finding Hydrocarbon Microseepage: A Study from Jamnagar Sub-basin, Saurashtra, Gujarat, India

Mesozoic sediments are source rocks for nearly half the world’s hydrocarbon reserves. Hence, there is great interest in the oil industry to know the trap and sub-trappean sediment thickness and their extent in the trap covered regions of Jamnagar study area. The microbial prospecting method is applied in the Jamnagar sub-basin, Gujarat for evaluating the prospects for hydrocarbon exploration by investigating the anomalous abundance of n-pentane- and n-hexane-oxidizing bacteria of this area. A total of 150 near-surface soil samples were collected in Jamnagar sub-basin, Gujarat for the evaluation of hydrocarbon resource potential of the basin. In this study, bacterial counts for n-pentane-utilizing bacteria range between 1.09 × 10² and 9.89 × 10⁵ cfu/g and n-hexane-utilizing bacteria range between 1.09 × 10² and 9.29 × 10⁵ cfu/g. The adsorbed hydrocarbon gases consisting of ethane plus hydrocarbons (ΣC₂₊) of 1–977 ppb and n-pentane (nC₅) of 1–23 ppb. The integrated geomicrobial and adsorbed soil gas studies showed the anomalous hydrocarbon zones nearby Khandera, Haripur, and Laloi areas which could probably aid to assess the true potential of the basin. Integrated geophysical studies have shown that Jamnagar sub-basin of Saurashtra has significant sediment thickness below the Deccan Traps and can be considered for future hydrocarbon exploration.     

Space-time interaction amongst clusters of mining induced seismicity

Elementary cluster analysis of induced seismicity in a South African gold mine has shown that there is a clear interaction amongst the clusters; and that the level of the interaction is a function of the distance. The clusering algorithm used is an adaptation of the single-link cluster analysis which considers both three-dimensional space and time. A high level of interaction between the clusters is demonstrated from the cross-correlation analysis of seismic activity rates and radiated energy. A distinct decrease in the value of correlation coefficients was detectable as distance increased. This was somewhat surprising, considering the simplicity of the technique used. Since no attempt is made to study the physical mechanisms of interaction, these results are very preliminary, but interesting from an observational point of view.     

The use of acidimetric titration as a novel approach to study particulate trace metal speciation and mobility: Application to sediments of the Scheldt estuary

The study of trace metal speciation has benefited from a great deal of interest leading to the development and the diversification of sequential extraction schemes (SES), which triggered the need for harmonization by the standard, measurements and testing programme (SM & T). However, some uncertainties still persist in the application of the harmonized 3-step protocol, because of the difficulty in conceptualizing a technique that can be applied to environmental samples irrespective of their nature. The alternative method proposed in this study is based on the solubility of the sample components progressively dissolved during the course of an acidimetric titration by 1 mol L⁻¹ HCl. The major HCl-reactive mineralogical components are identified using mass balance calculation of H⁺ consumed by their dissolution together with the amount of major elements released into solution. The speciation of minor and trace elements is investigated by comparing their titrations to those of the major elements. This approach is much simpler than SES because it uses simple non-selective H⁺ at room temperature instead of a complex experimental design of so-called specific reagents. The different mineral components of the solid are no longer operationally defined and the problem of selectivity is irrelevant to the titration approach. The method was applied to several sediment samples from the Scheldt estuary and the particulate phase was further examined by Scanning Electron Microprobe and X-ray Diffraction techniques. The nearly complete consumption of H⁺ in the suspension is balanced by the total dissolution of carbonates and Fe-oxyhydroxides. In contrast to the speciation inferred from the Tessier SES, the acidimetric titration has demonstrated that the carbonate phase does not significantly contain trace metals with the exceptions of 40% of the Mn and 30% of the Co. In contrast, the Fe-oxyhydroxides seem to play a major role and account for 70% of Pb and 20% of Cr, in addition to 60% of P and additional amounts of 20% Co and 40% Mn. 70% of the Cu also occur in the oxyhydroxide phase, more likely coprecipitated with gibbsite. 90% of the Cd and 85% of Zn can be attributed to the Acid Volatile Sulfide (AVS) phase as evidenced from S titration. The acidimetric titration method not only provides information on the speciation of trace metals but also allows the quantification of their reactivity and mobility, if one considers that the titration roughly mimics pH changes that may occur as a result of chemical disequilibrium in the environment. The results demonstrate the potential of the acidimetric titration as an alternative to SES protocols in geochemical and environmental regulation studies. This method is applicable to a wide variety of environmental materials with little or minor adjustments.