Relationship among titanium,rare earth elements,U–Pb ages and deformation microstructures in zircon: Implications for Ti-in-zircon thermometry

A zircon grain in an orthopyroxene–garnet–phlogopite–zircon–rutile-bearing xenolith from Udachnaya, Siberia, preserves a pattern of crystallographic misorientation and subgrain microstructure associated with crystal–plastic deformation. The zircon grain records significant variations in titanium (Ti) from 2.6 to 30 ppm that corresponds to a difference in calculated Ti-in-zircon temperatures of over several hundred degrees Celsius. The highest Ti concentration is measured at subgrain centres (30 ppm), and Ti is variably depleted at low-angle boundaries (down to 2.6 ppm). Variations in cathodoluminescence coincide with the deformation microstructure and indicate localised, differential enrichment of rare earth elements (REE) at low-angle boundaries. Variable enrichment of U and Th and systematic increase of Th/U from 1.61 to 3.52 occurs at low-angle boundaries. Individual SHRIMP-derived U–Pb ages from more deformed zones (mean age of 1799 ± 40, n = 22) are systematically younger than subgrain cores (mean age of 1851 ± 65 Ma, n = 7), and indicate that open system behaviour of Ti–Th–U occurred shortly after zircon growth, prior to the accumulation of significant radiogenic Pb. Modelling of trace-element diffusion distances for geologically reasonable thermal histories indicates that the observed variations are ~ 5 orders of magnitude greater than can be accounted for by volume diffusion. The data are best explained by enhanced diffusion of U, Th and Ti along deformation-related fast-diffusion pathways, such as dislocations and low-angle (< 5°) boundaries. These results indicate chemical exchange between zircon and the surrounding matrix and show that Ti-in-zircon thermometry and U–Pb geochronology from deformed zircon may not yield information relating to the conditions and timing of primary crystallisation.     

Predicted signatures of pulsed reconnection in ESR data

Early in 1996, the latest of the European inco-herent-scatter (EISCAT) radars came into operation on the Svalbard islands. The EISCAT Svalbard Radar (ESR) has been built in order to study the ionosphere in the northern polar cap and in particular, the dayside cusp. Conditions in the upper atmosphere in the cusp region are complex, with magnetosheath plasma cascading freely into the atmosphere along open magnetic field lines as a result of magnetic reconnection at the dayside magnetopause. A model has been developed to predict the effects of pulsed reconnection and the subsequent cusp precipitation in the ionosphere. Using this model we have successfully recreated some of the major features seen in photometer and satellite data within the cusp. In this paper, the work is extended to predict the signatures of pulsed reconnection in ESR data when the radar is pointed along the magnetic field. It is expected that enhancements in both electron concentration and electron temperature will be observed. Whether these enhancements are continuous in time or occur as a series of separate events is shown to depend critically on where the open/closed field-line boundary is with respect to the radar. This is shown to be particularly true when reconnection pulses are superposed on a steady background rate.     

An experimental study on non-linear progressive wave-induced dynamic stresses in seabed

In this study, the dynamic stresses within the seabed induced by non-linear progressive waves were explored through a series of hydraulic model tests on a movable bed within a wave flume. By comparing Stokes’ 2nd-order wave theory with the theory of wave-induced dynamic stresses within the seabed as proposed by Yamamoto et al. [1978. On the response of a poro-elastic bed to water waves. Journal of Fluid Mechanics 87 (1), 193–206.] and Hsu and Jeng [1994. Wane-induced soil response in an unsaturated anisotropic seabed of finite thickness. International Journal for Numerical and Analytical Methods in Geomechanics 18, 785–807], the experimental results show that the pressure on the seabed surface, the pore water pressure within the seabed as well as the vertical and the horizontal stresses are all smaller than their theoretical values. If we were to obtain the characteristics of seabed soil, the analytical solution of Hsu and Jeng [1994. Wane-induced soil response in an unsaturated anisotropic seabed of finite thickness. International Journal for Numerical and Analytical Methods in Geomechanics 18, 785–807] might agree to the simulation of the wave-induced effective stresses and shear stress in the sandy seabed. A different phase shift exists among all the three soil stresses. Their influences on the three dynamic stresses within seabed soil are important for seabed stability, and can be used in the verification of numerical models. In the whole, the non-linear progressive waves and the naturally deposited seabed are found to have a strong interaction, and the behavior of the induced dynamic stresses within the seabed is very complicated, and should be investigated integrally.     

A verification framework for interannual-to-decadal predictions experiments

Decadal predictions have a high profile in the climate science community and beyond, yet very little is known about their skill. Nor is there any agreed protocol for estimating their skill. This paper proposes a sound and coordinated framework for verification of decadal hindcast experiments. The framework is illustrated for decadal hindcasts tailored to meet the requirements and specifications of CMIP5 (Coupled Model Intercomparison Project phase 5). The chosen metrics address key questions about the information content in initialized decadal hindcasts. These questions are: (1) Do the initial conditions in the hindcasts lead to more accurate predictions of the climate, compared to un-initialized climate change projections? and (2) Is the prediction model’s ensemble spread an appropriate representation of forecast uncertainty on average? The first question is addressed through deterministic metrics that compare the initialized and uninitialized hindcasts. The second question is addressed through a probabilistic metric applied to the initialized hindcasts and comparing different ways to ascribe forecast uncertainty. Verification is advocated at smoothed regional scales that can illuminate broad areas of predictability, as well as at the grid scale, since many users of the decadal prediction experiments who feed the climate data into applications or decision models will use the data at grid scale, or downscale it to even higher resolution. An overall statement on skill of CMIP5 decadal hindcasts is not the aim of this paper. The results presented are only illustrative of the framework, which would enable such studies. However, broad conclusions that are beginning to emerge from the CMIP5 results include (1) Most predictability at the interannual-to-decadal scale, relative to climatological averages, comes from external forcing, particularly for temperature; (2) though moderate, additional skill is added by the initial conditions over what is imparted by external forcing alone; however, the impact of initialization may result in overall worse predictions in some regions than provided by uninitialized climate change projections; (3) limited hindcast records and the dearth of climate-quality observational data impede our ability to quantify expected skill as well as model biases; and (4) as is common to seasonal-to-interannual model predictions, the spread of the ensemble members is not necessarily a good representation of forecast uncertainty. The authors recommend that this framework be adopted to serve as a starting point to compare prediction quality across prediction systems. The framework can provide a baseline against which future improvements can be quantified. The framework also provides guidance on the use of these model predictions, which differ in fundamental ways from the climate change projections that much of the community has become familiar with, including adjustment of mean and conditional biases, and consideration of how to best approach forecast uncertainty.     

Protection of bridge piers against scouring with tetrahedral frames

Armoring countermeasures, such as riprap stones, are the primary method used to protect bridge piers against scouring; however, these methods have not had definitive success. Recently, flow-altering countermeasures, such as sacrificial piles, have been tested as an alternative to armoring countermeasures. This study investigated the mechanics of an innovative flow-altering countermeasure device, frames in the shape of tetrahedrons that act as a pier-scour countermeasure. Results of measured characteristics for turbulence flow showed that the flow around the tetrahedral frames can be divided into three regions： （1） a deceleration region near the sediment bed; （2） an acceleration region in the middle of water depth region; and （3） a restoration region near the water surface. The velocity magnitudes, turbulent intensities and vorticities decreased in the deceleration region, increased in the acceleration region and reverted to that of the unprotected condition in the restoration region. This pier-scour countermeasure is innovative because of its ability to dissipate energy associated with the downflow and the horseshoes vortex generated around the bridge pier. The scour tests revealed that the frames protected the foundation of bridge piers against scour. The experimental results showed that the percentage reduction of scour depth decreased as the velocity ratio, U/U c , decreased, reaching a value of 50% for the range of parameters tested in this study. Moreover, its efficiency was dependent on the placement density of the frames. The data showed that the frames were more effective when η was larger. However, their influence becomes less significant when η≥ 0.16.     

Monte-Carlo simulation of Mercury's exosphere

Because of its proximity to the Sun and its small size, Mercury has not been able to retain its atmosphere and only a thin exosphere surrounds the planet. The exospheric pressure at the planetary surface is approximately 10⁻¹⁰ mbar, set by the Mariner 10 occultation experiment. The existence of gaseous species H, He, and O has been established by Mariner 10. In addition Na, K, and Ca have been observed by ground based instrumentation. Other elements are expected to be found in Mercury's exosphere since the total pressure of the known species is almost two orders of magnitude less than the exospheric pressure.It is intended to measure these exospheric particle densities in situ with an instrument on board of ESA's BepiColombo Mercury Planetary Orbiter (MPO) spacecraft. Since the expected exospheric densities are very small we developed a Monte-Carlo computer model to investigate if such a measurement is feasible along the MPO spacecraft orbit. We model energy and ejection angle distributions of the particles at the surface, with the emission process determining the actual distribution functions. Our model follows the trajectory of each particle by numerical integration until the particle hits Mercury's surface again or escapes from the calculation domain. Using a large set of these trajectories bulk parameters of the exospheric gas are derived, e.g., particle densities for various atomic and molecular species. Our study suggests that a mass spectrometric measurement is feasible and, at least at MPO's periherm, all species that are released from the surface will be observed.     

The Mars oxidant experiment (MOx) for Mars '96

The MOx instrument was developed to characterize the reactive nature of the martian soil. The objectives of MOx were: (1) to measure the rate of degradation of organics in the martian environment; (2) to determine if the reactions seen by the Viking biology experiments were caused by a soil oxidant and measure the reactivity of the soil and atmosphere: (3) to monitor the degradation, when exposed to the martian environment, of materials of potential use in future missions; and, finally, (4) to develop technologies and approaches that can be part of future soil analysis instrumentation. The basic approach taken in the MOx instrument was to place a variety of materials composed as thin films in contact with the soil and monitor the physical and chemical changes that result. The optical reflectance of the thin films was the primary sensing-mode. Thin films of organic materials, metals, and semiconductors were prepared. Laboratory simulations demonstrated the response of thin films to active oxidants.     

Understanding river dune splitting through flume experiments and analysis of a dune evolution model

Forecasts of water level during river floods require accurate predictions of the evolution of river dune dimensions, because the hydraulic roughness of the main channel is largely determined by the bed morphology. River dune dimensions are controlled by processes like merging and splitting of dunes. Particularly the process of dune splitting is still poorly understood and – as a result – not yet included in operational dune evolution models. In the current paper, the process of dune splitting is investigated by carrying out laboratory experiments and by means of a sensitivity analysis using a numerical dune evolution model. In the numerical model, we introduced superimposed TRIAS ripples (i.e. triangular asymmetric stoss side‐ripples) on the stoss sides of underlying dunes as soon as these stoss sides exceed a certain critical length. Simulations with the model including dune splitting showed that predictions of equilibrium dune characteristics were significantly improved compared to the model without dune splitting. As dune splitting is implemented in a parameterized way, the computational cost remains low which means that dune evolution can be calculated on the timescale of a flood wave. Subsequently, we used this model to study the mechanism of dune splitting. Literature showed that the initiation of a strong flow separation zone behind a superimposed bedform is one of the main mechanisms behind dune splitting. The flume experiments indicated that besides its height also the lee side slope of the superimposed bedform is an important factor to determine the strength of the flow separation zone and therefore is an important aspect in dune splitting. The sensitivity analysis of the dune evolution model showed that a minimum stoss side length was required to develop a strong flow separation zone. Copyright © 2014 John Wiley & Sons, Ltd.     

Statistical analysis of the radon-222 potential of rocks in Virginia,U.S.A.

More than 3,200 indoor radon-222 (²²²Rn) measurements were made seasonally in an area of about 1,000 square kilometers of the Coastal Plain and Piedmont physiographic provinces in Virginia, U.S.A. Results of these measurements indicate that some geological units are associated, on the average, with twice as much indoor²²²Rn as other geological units, and that indoor²²²Rn varies seasonally. The Kruskal-Wallis test was used to test whether indoor²²²Rn concentrations for data gathered over the winter and summer seasons differ significantly by rock unit. The tests concluded that indoor²²²Rn concentrations for different rock units were not equal at the 5-percent significance level. The rocks associated with the highest median indoor²²²Rn concentration are specific rocks in the Mesozoic Culpeper basin, including shale and siltstone units with Jurassic diabase intrusives, and mica schists in the Piedmont physiographic province. The pre-Triassic Peters Creek Schist has the highest ranking in terms of indoor²²²Rn concentration. The rocks associated with the lowest indoor²²²Rn concentrations include coastal plain sediments, the Occoquan Granite, Falls Church Tonalite, Piney Branch Mafic and Ultramafic complex, and unnamed mafic and ultramafic inclusions, respectively. The rocks have been ranked according to observed²²²Rn concentration by transforming the average rank of indoor²²²Rn concentrations to z scores.