Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

Wrench faults,pull-apart basins,and volcanism in central Oregon: A new tectonic model based on image interpretation

A tectonic study of the Newberry Crater region of central Oregon has been based on the interpretation of Landsat Thematic Mapper imagery. Two major faults, the Brothers-Tumalo and Eugene-Denio Faults, pass NW-SE through the region and step to the right at the eastern margin of the Cascades Range. Dextral wrench faulting on these structures during the Tertiary controlled the formation of the La Pine Basin, a pull-apart structure containing Tertiary and Quaternary sediments and volcanics. Tertiary wrench faulting appears to have been associated with rotations of crustal blocks at a plate margin, but was superseded in the Quaternary by extensional faulting of the Basin and Range province. Newberry Crater and other major bimodal volcanic centres in the NW Cordillera (Crater Lake, Medicine Lake, Mt. St. Helens) seem to have a similar tectonic setting in crustal pull-aparts. A relationship between magma type and fault trend at Newberry and Medicine Lake is suggested.     

Toroidal versus poloidal magnetic fields in Sun-like stars: a rotation threshold

From a set of stellar spectropolarimetric observations, we report the detection of surface magnetic fields in a sample of four solar-type stars, namely HD 73350, HD 76151, HD 146233 (18 Sco) and HD 190771. Assuming that the observed variability of polarimetric signal is controlled by stellar rotation, we establish the rotation periods of our targets, with values ranging from 8.8 d (for HD 190771) to 22.7 d (for HD 146233). Apart from rotation, fundamental parameters of the selected objects are very close to the Sun's, making this sample a practical basis to investigate the specific impact of rotation on magnetic properties of Sun-like stars.
We reconstruct the large-scale magnetic geometry of the targets as a low-order  (ℓ < 10)  spherical harmonic expansion of the surface magnetic field. From the set of magnetic maps, we draw two main conclusions. (i) The magnetic energy of the large-scale field increases with rotation rate. The increase in chromospheric emission with the mean magnetic field is flatter than observed in the Sun. Since the chromospheric flux is also sensitive to magnetic elements smaller than those contributing to the polarimetric signal, this observation suggests that a larger fraction of the surface magnetic energy is stored in large scales as rotation increases. (ii) Whereas the magnetic field is mostly poloidal for low rotation rates, more rapid rotators host a large-scale toroidal component in their surface field. From our observations, we infer that a rotation period lower than ≈12 d is necessary for the toroidal magnetic energy to dominate over the poloidal component.     

Sur quelques concentrations plombo-zinciferes du devonien inferieur du massif schisteux rhenan

Zusammenfassung The Lower Devonian of the Rhine Schist Massif is characterized by a fine detrital sedimentation which reflects a coastal plain environment located between the Old Red Sandstone continent in the N and the marine Bohemian Facies in the SE. Mineralisations are located within these coastal-plain sediments, especially in fractured horizons topped by pelitic and floored by sandy sediments of Sieg Emsian age. The mineralised localities occur in three zones: the districts of Bensberg, Eitorf and Mayen. The Lüderich locality (Bensberg) is the most important having approximately one million tons of Zn and Pb metal. It is localised within a zone having marked sedimentary characteristics since the Siegenian. Mineralisation occurs as penecontemporaneous lenses, fracture fillings etc, formed at abnormal contacts between lithological units having different competance during Siegenian and Lower Emsian deformation. However, locally there is lateral transition between the upper units of the sandy channel series and the lower units of the pelitic swamp facies. Vertical extension of mineralisations is strictly limited to the tectonic contact zone between the Odenspiel Sandstone and the Bensberg pelites. Study of mineralisations at various levels (mapping, morphology, structure, paragenetic and geochemical) leads to the formulation of a genetic model requiring complex fracturation at the contact between contrasting lithologies and preferential drainage through these fractured zones; metals are trapped on the sandstone floor, the pelitic roof trapping the vadose hydrothermal solutions. These basic controls seem to apply throughout the Bensberg, Eitorf and Mayen districts. On a more regional scale the age variations of the gangue sediments reflects a lateral displacement of red/grey facies limits due to coastal evolution. Thus one may demonstrate a type of mineral occurrence whose model may be that of epigenetic reconcentration within fractures affecting syngenetic geochemical anomalies.Zusammenfassung Das Unterdevon des Rheinischen Schiefergebirges wird durch eine feinkörnige detritische Sedimentation gekennzeichnet. Die Verteilung dieser detritischen Sedimente widerspiegelt eine flache Küstenlandschaft zwischen dem Kontinent des Unterrotliegenden im Norden und des Meeres mit der Böhmischen Fazies im Südosten. In diesen Schichten befinden sich gangförmige Vererzungen, die in Bruchzonen auftreten, die ein pelitisches Hangendes und ein sandsteinreiches Liegendes vom Siegen-Ems Alter haben. Die Lagerstätten kommen in drei Bezirken vor: Der Bensberger Bezirk, der Bezirk Eitorf und der Bezirk Mayen. Die Lagerstätte Lüderich (Bensberger Revier) ist die größte (ungefähr eine Million Tonnen Metall Zink+Blei). Sie befindet sich in einer Zone, in der schon in der Siegen-Stufe bemerkenswerte sedimentäre Strukturen auftreten. Die Vererzung tritt als penekonkordante Linsen, Gänge, Stockwerke in tektonischen Kontaktzonen auf. Diese Kontaktzonen befinden sich zwischen 2 verschiedenen sedimentären Einheiten, deren Gesteinseigenschaften sehr verschieden sind. Es handelt sich um Pelite mit Sandstein-Einschaltungen einerseits, die zur unteren Emsstufe gehören sollen und um fluviatile Sandsteine andererseits, die zur oberen Siegenstufe gehören sollen. Lokal ist ein lateraler Übergang durch Faziesänderung von den oberen Sandsteinen in die unteren Pelitschichten jedoch nicht unmöglich. Die Sandsteine vertreten einen fluviatilen Sedimentationsbereich, die Pelite einen sumpfigen Sedimentationsbereich. Die Vererzung (mit einer vertikalen Ausdehnung ungefähr von 300 m) tritt nur im Bereich der Kontaktzone zwischen den Odenspieler Sandsteinen und den Peliten der Unteren Bensberger Schichten auf. Die Resultate der Kartographie, der morphologischen Studie der Erzkörper, der Struktur und der Paragenese führen zu einem genetischen Modell. Dabei spielt die Anwesenheit einer Bruchstruktur an der Grenze zwischen 2 Bereichen mit verschiedenen lithologischen Eigenschaften eine Hauptrolle für die Konzentration der im Hangenden fein verteilten Metalle. Die hydrothermalen Lösungen kommen demnach nicht von der Teufe, sondern aus dem Nebengestein. Im ganzen Bensberger Erzrevier wie in der Gegend von Eitorf und in der Gegend von Mayen finden wir dieselben Leitfäden für die Vererzung in den Lagerstätten und Vorkommen. Beobachtet man die ganze Provinz, dann merkt man, daß die Altersverschiedenheiten in den Nebengesteinen der verschiedenen Lagerstätten eine geographische Wanderung der Faziesgrenze zwischen rot und grau in dieser küstennahen Ebene Widerspiegeln. Die verschiedenen Vorkommen und Lagerstätten treten immer in unmittelbarer Nähe dieser Grenze auf. Die Eigenschaften dieser Lagerstätten weisen auf eine Bildung durch eine epigenetische Umlagerung in eine gangförmige Bruchstruktur hin.     

Proper motion surveys in the infrared

Current and future wide field surveys in infrared passbands present opportunities for ultra low‐mass stellar sample selection via proper motions, as well as or instead of purely photometric techniques. Furthermore, proper motion measurements yield additional clues as to candidate membership of cluster or field (kinematic) populations. In this paper we review some recent results and speculate as to the possibilities afforded by the next generation of wide‐field infrared surveys. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Heavy rare gases from Rabbit Lake (Canada) and the Oklo mine (Gabon): natural spontaneous chain reactions in old uranium deposits

Xenon isotopic studies confirm natural spontaneous chain reactions at the Oklo mine site (Republic of Gabon) with an integrated neutron flux of approximately 4 × 10²⁰n/cm² and a duration between 14,000 and 70,000 years. Similar studies for the Rabbit Lake deposit (Saskatchewan), a slightly younger site with some evidence of continued geologic activity, shows no evidence of self-supporting reactions.     

Land use and climate change on the Yamal Peninsula of north-west Siberia: some ecological and socio-economic implications

Compared to climate, land use change is expected to comprise a more important component of global change in the coming decades. However, climate is anticipated to supass land use as a factor later in the next century, particularly in the Arctic. Discussed here are the implications of land use and climate change on the Yamal peninsula of north-west Siberia, homeland of the Yamal Nenets. Since the discovery of super-giant natural gas fields in the 1960s, extensive exploration has resulted in direct withdrawal of large areas for infrastructure development and associated disturbance regimes have led to cumulative impacts on thousands of additional hectares of land. The land withdrawals have pushed a relatively consistent or increasing number of reindeer onto progressively smaller parcels of pasture. This has led to excessive grazing and trampling of lichens, bryophytes and shrubs and, in many areas, erosion of sandy soils via deflation. The low Arctic tundra lies entirely within the continuous permafrost zone and ice-rich substrates are widespread. One implication of this is that both anthropogenic and zoogenic distubance regimes may easily initiate thermokarst and aeolian rosion, leading to significant further losses of pastures. Even without industrial distubance, a slight change of the climate would result in massive thermokarst erosion. This would have negative consequences equal to or greater than the mechanical distubances described above. The synergistic effects of land use coupled with climate, change therefore have profound implication for the ecosystems of Yamal, as well as the future of the Nenets culture, society and economy.