Dissolution kinetics of fosteritic olivine at 90-150 °C including effects of the presence of CO2

The steady state dissolution rate of San Carlos olivine [Mg_1.82Fe_0.18 SiO₄] in dilute aqueous solutions was measured at 90, 120, and 150 °C and pH ranging from 2 to 12.5. Dissolution experiments were performed in a stirred flow-through reactor, under either a nitrogen or carbon dioxide atmosphere at pressures between 15 and 180 bar. Low pH values were achieved either by adding HCl to the solution or by pressurising the reactor with CO₂, whereas high pH values were achieved by adding LiOH. Dissolution was stoichiometric for almost all experiments except for a brief start-up period. At all three temperatures, the dissolution rate decreases with increasing pH at acidic to neutral conditions with a slope of close to 0.5; by regressing all data for 2 ? pH ? 8.5 and 90 °C ? T ? 150 °C together, the following correlation for the dissolution rate in CO₂-free solutions is obtained:

     

New Calculation of the Electrical Microfield Distribution in Plasma

Recently new calculations for the probability field distribution in plasma generating a new expression for the Debye screening fields was carried out by Martin and Perez (1996). This field is a very accurate solution of the Poisson equation for a point test charge in a plasma described by a uniform charge density at Boltzmann thermal equilibrium. The method that we here present is based mainly on the introduction of this adequate field considering the dependence of the potential with the magnitude of the test charge in the calculus of the distribution. First we find the spectral function F(k) carrying out the Fourier transform of the field which is numerically calculated for each representative value of the variable in k space and then fitting these data in order to get F(k). Thus, after the usual numerical integration on the wave number space d³k, the field strength distribution is achieved. This approximation recovers the Holtsmark distribution in the limit of high temperature, and/or, small densities as also these where 0. As in previous works (Ecker, 1972; Spatschek, 1990) the most probable value of the field decreases as the temperature is reduced, and/or, the density increased.     

Abundance Gradients in the Outer Galactic Disk

Radial abundance gradients of the element ratios O/H, Ne/H, S/H, and Ar/H are determined for a sample of disk planetary nebulae, emphasizing the behaviour of the gradients at large galactocentric distances. This revised version was published online in July 2006 with corrections to the Cover Date.     

Subduction Influence on Oxygen Fugacity and Trace and Volatile Elements in Basalts Across the Cascade Volcanic Arc

Fluids or melts derived from a subducting plate are often citedas a mechanism for the oxidation of arc magmas. What remainsunclear is the link between the fluid, oxygen fugacity, andother major and trace components, as well as the spatial distributionof the impact of those fluids. To test the potential effectsof addition of a subduction-derived fluid or melt to the sub-arcmantle, olivine-hosted melt inclusions from primitive basalticlavas sampled from across the central Oregon Cascades (43°–45°N)have been analyzed for major, trace and volatile elements andfO₂. Oxygen fugacity was determined in melt inclusions fromsulfur speciation determined by electron microprobe and fromolivine–chromite oxygen geobarometry. The overall rangein fO₂ based on sulfur speciation measurements is from <–0·25log units to + 1·9 log units (FMQ, where FMQ is fayalite–magnetite–quartzbuffer). Oxygen fugacity is positively correlated with fluid-mobiletrace element and light rare earth element contents in basaltsgenerated by relatively low-degree partial melting. Establishinga further correlation between fO₂ and fluid-mobile trace elementabundances with position along the arc requires the basaltsto be subdivided into shoshonitic, calc-alkaline, low-K tholeiiteand enriched intraplate basalt groups. Melt inclusions fromenriched intraplate and shoshonitic lavas show increasing fO₂and trace element abundances closer to the trench, whereas calc-alkalinemelt inclusions exhibit no significant across-arc variations.Low-K tholeiitic melt inclusions record an increase in incompatibletrace elements closer to the trench; however, there is no correlatedincrease in fO₂. The correlation observed in enriched intraplateand shoshonitic melt inclusions is interpreted to reflect aprogressively greater proportion of a fluid-rich, oxidized subductioncomponent in magmas generated nearer the subduction zone. Significantly,calc-alkaline melt inclusions with high ratios of large ionlithophile elements to high field strength elements, characteristicof ‘typical’ arc magmas, have oxidation states indistinguishablefrom low-K tholeiite and enriched intraplate basalt melt inclusions.The lack of across-arc geochemical variation in calc-alkalinemelt inclusions may suggest that these basalts are not necessarilythe most appropriate magmas for examining recent addition ofa subduction component to the sub-arc mantle. Flux and batchmelt model results produce a wide range of predicted amountsof melting and subduction component added to the mantle source;however, general trends characterized by increased melting andproportion of the subduction component from enriched intraplate,to low-K tholeiite, to calc-alkaline are robust. The model resultsdo not require enriched intraplate, low-K tholeiite and calc-alkalinemagmas to be produced from the same more fertile mantle source.However, enriched intraplate magmas, in contrast to calc-alkalineand low-K tholeiite magmas, cannot be generated from a depletedmantle source. Flux or batch melting of either the more fertileor depleted mantle sources used to generate the low-K tholeiite,calc-alkaline, and enriched intraplate magmas cannot reproduceshoshonitic compositions, which require a significantly depletedmantle source strongly metasomatized by a subduction component.The potential mantle source for shoshonitic basalts has a predictedfO₂ (after oxidation) from + 0·3 to + 2·4 logunits (FMQ) whereas the mantle source for low-K tholeiite, calc-alkaline,and enriched intraplate magmas may range from –1·1to + 0·7 log units (FMQ). KEY WORDS: basalt; Cascades; melt inclusions; oxidation state; volatiles     

Distribution and accumulation rate of ore elements in Holocene and Late Glacial Sediments of the Deryugin Basin,Sea of Okhotsk

Results of the study of contents and accumulation rates of Fe, Mn, and a number of trace elements in Upper Quaternary sediments of the Deryugin Basin are presented. Maps of the average contents and accumulation rates of excess Fe, Mn, Zn, Ba, Ni, Pb, Cu, and Mo in sediments of the first oxygen isotope stage (OIS) have been plotted. Anomalous contents and accumulation rates are confined to peripheral zones of the Deryugin sedimentary basin and large fracture zones. Different mechanisms of the influence of fluid-dynamic processes on the rate of hydrogenic and biogenic accumulation of ore elements are assumed.Translated from Litologiya i Poleznye Iskopaemye, No. 2, 2005, pp. 115–132.Original Russian Text Copyright © 2005 by Astakhov, Gorbarenko, Bakhareva, Gretskaya, Sattarova.     

Simulation of extensive air showers at ultra-high energy using the CORSIKA Monte Carlo code

Extensive simulations have been carried out with CORSIKA version 5.62 to investigate the general properties of giant cosmic air shower in the energy range 1–100 EeV. The comparison between protons, heavy nuclei and γ initiated showers exhibits unexpected and interesting features. The apparent muon electron ratio at great distances (1.5 km from axis) tends to be comparable at ultra-high energy in both photon-induced cascades and hadronic cascades (compensation between the enhancement versus energy of photo-production cross-section and of the decrease of both pair production cross-section and the bremsstrahlung cross-section, with Landau–Pomeranchuk–Migdal effect); for proton and nuclei primaries, a correlation with lateral electron profile suggests a new energy estimator, in complement to electrons size or density at 600 m, suitable for the determination of the total primary energy spectrum. Another tendency is the local contrast in the abundance of positive and negative muons (with a possible ellipticity in the lateral muon distribution) induced by the geomagnetic field, especially visible for some azimuthal and zenith angles. These distortions are more intense for heavy primaries; they can be exploited on the most favorable horizontal axis or areas, for the discrimination between nuclei and protons.