On the advection of turdidity in the saint lawrence middle estuary

The suspension transport away from the extensive turbidity zone of the St. Lawrence estuary is largely determined by the channel topography. The suspended sediments are advected downstream by a 40 km long turbid plume which takes its source in a turbidity maximum at the head of the estuary and flows downstream partly confined by the South Channel. During the ebbing phase of tidal cycles, the turbid waters of the plume are forced downstream through narrow converging sections of the channel, and slowed down through more opened diverging regions, particularly down-stream of the St. Roch Traverse. These, large fluctuations in stratification modulate the vertical transport of suspended material from the bottom to the surface layer. Midway down the estuary, dispersion of the plume occurs along a frontal zone which seasonally migrates 30 km or more in response to changes in fresh water discharge. The plume is reinforced and the turbidity gradient is intensified by local injections of inshore waters from Ste. Anne Bay, a subtidal platform highly enriched in suspended material by intertidal exchanges with large mudllats. Lateral erosion of the plume and cross-channel transport of suspended matter from the South into the North Channel is made possible by large horizontal shears developing in the central part of the middle estuary during the early flood. These are created by a one-hour tidal phase difference between the North and the South Channel.     

Fractionation of carbon and hydrogen isotopes by methane-oxidizing bacteria

Carbon isotopic analysis of methane has become a popular technique in the exploration for oil and gas because it can be used to differentiate between thermogenic and microbial gas and can sometimes be used for gas-source rock correlations. Methane-oxidizing bacteria, however, can significantly change the carbon isotopic composition of methane; the origin of gas that has been partially oxidized by these bacteria could therefore be misinterpreted.We cultured methane-oxidizing bacteria at two different temperatures and monitored the carbon and hydrogen isotopic compositions of the residual methane. The residual methane was enriched in both ¹³C and D. For both isotopic species, the enrichment at equivalent levels of conversion was greater at 26°C than at 11.5°C. The change in δD relative to the change in δ¹³C was independent of temperature within the range studied. One culture exhibited a change in the fractionation pattern for carbon (but not for hydrogen) midway through the experiment, suggesting that bacterial oxidation of methane may occur via more than one pathway.The change in the δD value for the residual methane was from 8 to 14 times greater than the change in the δ¹³C value, indicating that combined carbon and hydrogen isotopic analysis may be an effective way of identifying methane which has been subjected to partial oxidation by bacteria.     

High-pressure synthesis and properties of magnesiocarpholite,MgAl2[Si2O6] (OH)4

Magnesiocarpholite has been synthesized on its own composition between 15 and 25 kb water pressure and 415°–600° C. Best conditions are 25 kb-550° C, starting from a mixture of oxides and synthetic cordierite. Within the MgO-Al₂O₃-SiO₂-H₂O system, possible substitutions appear to be very limited in magnesiocarpholite. Cell-parameters are a=13.706(3), b= 20.075(3), c=5.107(l) Å, space group Ccca. The larger cell, as compared with the most magnesian natural carpholites, is tentatively ascribed to structural disorder. Preliminary stability data confirm the low-temperature character of this mineral which is shown to be a high-pressure equivalent of sudoite+quartz.     

Influence of frozen conditions on the oxygen diffusion coefficient in unsaturated porous materials

The efficiency of soil covers used as oxygen barriers to control the generation of acid drainage from sulfidic mine wastes can be evaluated in terms of the diffusive oxygen flux reaching the underlying wastes. Oxygen diffusion has been extensively investigated over the last few decades for unsaturated porous materials that are not frozen. However, little attention has been paid to materials that are fully or partially frozen, and thus, the diffusion of oxygen through soil covers during the winter freezing period has been generally neglected. This paper presents a laboratory method developed to evaluate the effective diffusion coefficient of oxygen (D_e) in frozen, inert materials. The method is a modified version of the conventional double-chamber cell in which the temperature and unfrozen volumetric water content of the sample are measured in addition to the more commonly monitored change in oxygen concentration. Several tests were conducted on non-reactive materials: that is, a sand at multiple degrees of saturation (S_r?=?20, 30, 39, and 42%), a silt (S_r?=?47%), and a mixture of the two (S_r?=?90%). Experimental data were interpreted using the POLLUTE code. Values of D_e for frozen materials were slightly lower than those obtained at ambient laboratory temperatures. In addition to the development of an empirical method for determining D_e, a preliminary model based on the model proposed by Aachib et al. (Water Air Soil Pollut 156:163–193, 2004) was created for the prediction of D_e in frozen materials by defining the involved parameters as temperature-dependent. The results indicate that predicated values of D_e are slightly higher than experimental values, suggesting that there remains room for improvement in the model.

     

High-pressure,low-temperature metamorphism in Alpujarride Units of southeastern Betics (Spain)Métamorphisme de haute pression et basse température dans les unités Alpujarrides du Sud-Est de la cordillère Bétique (Espagne)

We present the first occurrences of high-pressure, low-temperature ferro-magnesiocarpholite-bearing mineral assemblages associated to quartz segregations in the Alpujarride units of southeastern Betics (Sierra de Almagro, Sierra de los Pinos and Sierra Cabrera). Thermobarometric results show that the carpholite-bearing rocks underwent the same P–T conditions in the three outcrops, i.e. 8–10 kbar, 350–400 °C. Metamorphic and structural data allow us to conclude that these rocks belong to the same Alpujarride unit. In the Sierra de Almagro, tectonic units with carpholite-bearing rocks overlie low-pressure, low-temperature Alpujarride units, then forming a stack with an inverted tectono-metamorphic sequence, as observed in the central and western part of the Alpujarride complex. The preservation of carpholite-bearing assemblages in these rocks implies that no significant temperature increase occurred during the exhumation history. To cite this article: G. Booth-Rea et al., C. R. Geoscience 334 (2002) 857–865.     

Image analysis and circular statistics for shape-fabric analysis: applications to lithified ignimbrites

 Computer-assisted image analysis can be successfully used to derive quantitative textural data on pyroclastic rock samples. This method provides a large number of different measurements such as grain size, particle shape and 2D orientation of particle main axes (directional- or shape-fabric) automatically and in a relatively short time. Orientation data reduction requires specific statistical tests, mainly devoted to defining the kind of particle distribution pattern, the possible occurrence of preferred particle orientation, the confidence interval of the mean direction and the degree of randomness with respect to pre-assigned theoretical frequency distributions. Data obtained from image analysis of seven lithified ignimbrite samples from the Vulsini Volcanic District (Central Italy) are used to test different statistics and to provide insight about directional fabrics. First, the possible occurrence of a significant deviation from a theoretical circular uniform distribution was evaluated by using the Rayleigh and Tukey χ ² tests. Then, the Kuiper test was performed to evaluate whether or not the observation fits with a unimodal, Von Mises-like theoretical frequency distribution. Finally, the confidence interval of mean direction was calculated. With the exception of one sample (FPD10), which showed a well-developed bimodality, all the analysed samples display significant anisotropic and unimodal distributions. The minimum number of measurements necessary to obtain reasonable variabilities of the calculated statistics and mean directions was evaluated by repeating random collections of the measured particles at increments of 100 particles for each sample. Although the observed variabilities depend largely on the pattern of distribution and an absolute minimum number cannot be stated, approximately 1500–2000 measurements are required in order to get meaningful mean directions for the analysed samples. Received: 9 April 1996 / Accepted: 26 December 1996     

The Limit Problems for the Equation of Oscillations of a Satellite

We consider the ordinary differential equation of the second order, which describes oscillations of a satellite with respect to its mass center moving along an elliptic orbit with eccentricity e. The equation has two parameters: e and μ. It is regular for 0 ≤ e < 1 and singular when e = 1. For 1 we obtain three limit problems. Their bounded solution to the first limit problem form a two-dimensional (2D) continuous invariant set with a periodic structure. Solutions to the second limit problem form 2D and 3D manifolds. The μ-depending families of odd bounded solutions are singled out. One of the families is twisted into a self-similar spiral. To obtain the limit families of the periodic solutions to the original problem match together the odd bounded solutions to the first and the second limit problem. The point of conjunction is described by the third (the basic) limit problem. The limit families are very close to prelimit ones computed in earlier studies. This revised version was published online in July 2006 with corrections to the Cover Date.     

Near bottom variations of turbidity in the St Lawrence estuary

Observations of the turbidity and velocity fields in the near-bottom waters of the St Lawrence estuary were obtained with a package which includes a self-recording attenuance meter and a currentmeter. The latter also measures salinity and temperature. Time series varying in length between 26 h and 26 days, and with repetition rates between one and 15 min are discussed for 3 typical open-channel and nearshore stations. A high-frequency sampling mode provides a means to observe the passage of a frontal disturbance over the bottom during the semi-diurnal cycle. With lower frequency records having lengths of one week to one month, contributions to the turbidity fluctuations due to the spring-neap oscillations, seasonal changes in run-off, and the sudden rise in solid discharge of local tributaries following storms, can be resolved. From turbidity polar diagrams, local onshore sources of particulate suspended matter can be identified. Among other advantages, it is possible from such records to time precisely the occurrence of turbidity peaks in relation to the ebb and flow velocities, to assess the importance of resuspension, and to specify exactly the time rate of change of the turbidity. On the whole, self-recording equipments provide a wealth of information unavailable from more traditional hydrocast sampling techniques.     

Foldbelts with early salt withdrawal and diapirism: Physical model and examples from the northern Gulf of Mexico and the Flinders Ranges, Australia

A physical experiment shows that shortening applied to existing diapirs and minibasins produces anomalous structural styles that are unlike those of more typical foldbelts. Strong minibasins remain largely undeformed while weak diapirs localize contractional strain. Short diapirs form the cores to folds and thrusted folds, whereas tall diapirs are squeezed and often welded, commonly leading to the extrusion of allochthonous material. Key features of the model are observed in real examples. In the northern Gulf of Mexico passive margin, minibasins were originally separated by a polygonal pattern of deep salt ridges, with diapirs located at ridge intersections. Gravity spreading resulted in squeezed diapirs (and associated allochthonous salt) connected by variably oriented contractional, extensional, and strike-slip structures. In the Flinders Ranges convergent-margin foldbelt of South Australia, preexisting diapirs were squeezed, welded, and thrusted, with anticlines plunging away in multiple directions, so that minibasins are surrounded by highly variable structures. A different geometry is observed in La Popa Basin, Mexico, where squeezing of a linear salt wall produced a vertical weld with diapirs at the terminations, rather than the culmination. In all areas, foldbelt geometries are strongly influenced by the preestablished salt-minibasin architecture.