Integrated biomarker assessment of the effects exerted by treated produced water from an onshore natural gas processing plant in the North Sea on the mussel Mytilus edulis

The biological impact of a treated produced water (PW) was investigated under controlled laboratory conditions in the blue mussel, Mytilus edulis. Mussel health status was assessed using an integrated biomarker approach in combination with chemical analysis of both water (with SPMDs), and mussel tissues. Acyl-CoA oxidase activity, neutral lipid accumulation, catalase activity, micronuclei formation, lysosomal membrane stability in digestive cells and haemocytes, cell-type composition in digestive gland epithelium, and the integrity of the digestive gland tissue were measured after 5 week exposure to 0%, 0.01%, 0.1%, 0.5% and 1% PW. The suite of biomarkers employed were sensitive to treated PW exposure with significant sublethal responses found at 0.01-0.5% PW, even though individual chemical compounds of PW were at extremely low concentrations in both water and mussel tissues. The study highlights the benefits of an integrated biomarker approach for determining the potential effects of exposure to complex mixtures at low concentrations. Biomarkers were integrated in the Integrative Biological Response (IBR/n) index.     

Thallium in meteorites

Abstract— Thallium has been quantified in 50 iron meteorites and 6 chondrites using a combination of solvent extraction and graphite furnace atomic absorption spectrometry. The accuracy of the data was checked by analysis of two iron meteorites by laser-excited ICP mass spectrometry. The Tl abundance values for irons appear to be the first recorded and show that the Tl content allows for taxonomic separation of several groups on Tl vs. Ni abundance plots. The Tl content of irons is inversely correlated with abundances of platinum group metals such as Ir, Pt, and Rh and, in this respect, behaves like Pd and As that favour sulphur-rich phases in meteorites. Analysis of carbonaceous chondrites showed a 30-fold enrichment of Tl compared with ordinary chondrites.     

The Iguaraçu H5 chondrite: a fall from Paraná State,Brazil

Abstract— The Iguaraçu meteorite, a single stone of 1200 g, fell in Paraná State, Brazil in October 1977. It is classified as an H5 ordinary chondrite with olivine of composition Fa 18.7.     

Effect of vegetation cover and sediment type on 3D subsurface structure and shear strength in saltmarshes

The vulnerability of saltmarshes to lateral erosion at their margin depends on the local biogeomorphological properties of the substrate. In particular, the 3D architecture of pore and root systems is expected to influence shear strength, with repercussions for the wider-scale stability of saltmarshes. We apply X-ray computed microtomography (μCT) to visualize and quantify subsurface structures in two UK saltmarshes at Tillingham Farm, Essex (silt/clay rich substrate) and Warton Sands (sand-rich substrate), with four types of ground cover: bare ground, Spartina spp, Salicornia spp and Puccinellia spp. We extracted μCT structural parameters that characterize pore and root morphologies at each station, and compared them with field measurements of shear strength using a principal component analysis and correlation tests. The 3D volumes show that species-dependent variations in root structures, plant colonization events and bioturbation activity control the morphology of macropores, while sediment cohesivity determines the structural stability and persistence of these pore structures over time, even after the vegetation has died. Areas of high porosity and high mean pore thickness were correlated to lower values of shear strength, especially at Tillingham Farm, where well-connected vertical systems of macropores were associated with current or previous colonization by Spartina spp. However, while well-connected systems of macropores may lower the local deformation threshold of the sediment, they also encourage drainage, promote vegetation growth and reduce the marsh vulnerability to hydrodynamic forces. The highest values of shear strength at both sites were found under Puccinellia spp, and were associated with a high density of mesh-like root structures that bind the sediment and resist deformation. Future studies of marsh stability should ideally consider time series of vegetation cover, especially in silt/clay-dominated saltmarshes, in order to consider the potential effect of preserved buried networks of macropores on water circulation, marsh functioning and cliff-face erosion.     

Sediment production and yield from an alluvial gully in northern Queensland,Australia

Sediment production, transport and yield were quantified over various timescales in response to rainfall and runoff within an alluvial gully (7 · 8 ha), which erodes into dispersible sodic soils of a small floodplain catchment (33 ha) along the Mitchell River, northern Australia. Historical air photographs and recent global positioning system (GPS) surveys and LiDAR data documented linear increases in gully area and volume, indicating that sediment supply has been relatively consistent over the historic period. Daily time lapse photography of scarp retreat rates and internal erosion processes also demonstrated that erosion from rainfall and runoff consistently supplied fine washload (< 63 µm) sediment in addition to coarse lags of sand bed material. Empirical measurements of suspended sediment concentrations (10 000 to >100 000 mg/L) and sediment yields (89 to 363 t/ha/yr) were high for both Australian and world data. Total sediment yield estimated from empirical washload and theoretical bed material load was dominated by fine washload (< 63 µm). A lack of hysteresis in suspended sediment rating curves, scarp retreat and sediment yield correlated to rainfall input, and an equilibrium channel outlet slope supported the hypothesis that partially or fully transport‐limited conditions predominated along the alluvial gully outlet channel. This is in contrast to sediment supply‐limited conditions on uneroded floodplains above gully head scarps. While empirical data presented here can support future modelling efforts to predict suspended sediment concentration and yield under the transport limiting situations, additional field data will also be needed to better quantify sediment erosion and transport rates and processes in alluvial gullies at a variety of spatial and temporal scales. Copyright © 2013 John Wiley & Sons, Ltd.     

Environmental scanning electron microscopy (ESEM) and nanoindentation investigation of the crack tip process zone in marble

This study explores the interaction between crack initiation and nanomechanical properties in the crack-tip fracture process zone of Carrara marble. Specimens with preexisting cracks were loaded in a uniaxial testing machine until the process zone appeared at the tips of the preexisting cracks. ESEM analysis reveals an increase in microcrack density in the process zone with increased loading of the specimen. Nanoindentation testing comprised of lines and grids of single nanoindentations located both near and far from the process zone shows a decrease in both indentation modulus and indentation hardness near grain boundaries in intact material, and with closeness to the process zone. Ultimately, the study confirms that the crack-tip process zone manifests itself as an area of reduced indentation hardness and indentation modulus in marble.     

Refractory Metal Nuggets – Formation of the first condensates in the Solar Nebula

As gas flowed from the solar accretion disk or Solar Nebula onto the proto-Sun, magnetic pressure gradients in the solar magnetosphere and the inner Solar Nebula provided an environment where some of this infalling flow was diverted to produce a low pressure, high temperature, gaseous, “infall” atmosphere around the inner Solar Nebula. The pressure in this inner disk atmosphere was mainly dependant on the accretion flow rate onto the star. High flow rates implied relatively high pressures, which decreased over time as the accretion rate decreased.In the first hundred thousand years after the formation of the Solar Nebula, accretional flow gas pressures were high enough to create submicron-sized Refractory Metal Nuggets (RMNs) – the precursors to Calcium Aluminum Inclusions (CAIs). Optimal temperatures and pressures for RMN formation may have occurred between 20,000 and 100,000 years after the formation of the Solar Nebula. It is possible that conditions were conducive to RMN/CAI formation over an 80,000 year timescale. The “infall” atmosphere and the condensation of refractory particles within this atmosphere may be observable around the inner disks of other protostellar systems.The interaction of forces from magnetic fields with the radiation pressure from the proto-Sun and the inner solar accretion disk potentially produced an optical-magnetic trap above and below the inner Solar Nebula, which provided a relatively stable environment in which the RMNs/proto-CAIs could form and grow. These RMN formation sites only existed during accretion events from the proto-solar disk onto the proto-Sun. As such, the formation and growth time of a particular RMN was dependent on the timescale of its nascent accretion event.Observational evidence suggests that RMNs were the nucleation particles for CAIs. As a consequence, the observed bimodal distribution of ²⁶Al in CAIs, where some CAIs have ²⁶Al while others do not, is probably due to the injection ²⁶Al during the short CAI formation period, where ²⁶Al was not present when the first CAIs were formed.