Hydrocarbon distribution in coals and in dispersed organic matter of different maceral compositions and maturities

More than 60 samples from 5 coal seams and adjacent siltstones and sandstones were selected from a well through Westphalian B sediments from Northern Germany in order to study bitumen generation and migration. The cores were drilled between 1200 und 1530 metres depth. In this interval, vitrinite reflectance (Rr) is increasing from 0.70 to 0.92%. Results reveal high hydrocarbon generation potentials for all coal samples, but not for adjacent clastic rocks, although maceral compositions of both are quite similar. Yields and compositions of thermal extracts from the coals depend on maceral compositions and rank. However, the bulk of the already generated bitumen has not been removed during natural coalification and is not easily releasable by thermovaporisation. A mass balance based on elemental composition of dull coals indicates that in the rather narrow rank interval (0.70–0.92% Rr) a total mass loss of 20% may have occurred by migration. This is evidenced by a loss of about 20% of the original hydrogen, the rest being stored in the coals.

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Zusammenfassung Um die Entstehung und Migration von Bitumen zu untersuchen wurden in Norddeutschland mehr als 60 Proben aus 5 Kohleflözen und benachbarten Silt- und Sandsteinen aus einer Bohrung durch Westphal B-Sedimente bearbeitet. Die Entnahmetiefe der Bohrkerne liegt zwischen 1200 und 1530 Metern. Innerhalb dieses Intervales steigt die Vitrinit-Reflexion (Rr) von 0,70 auf 0,92%. Für alle Proben aus den Flözen ergeben sich hohe Kohlenwasserstoff-Bildungspotentiale, nicht aber für die benachbarten klastischen Gesteine, obwohl die Mazeral-Zusammensetzungen in beiden ähnlich sind. Die Ausbeute und Zusammensetzung thermaler Extrakte aus den Flözen hängen von Mazeral-Zusammensetzung und Reife ab. Allerdings wurden weder während der Inkohlung größere Mengen des Bitumens abtransportiert, noch ist dieses durch Thermovaporisation leicht freisetzbar. Eine Massenbalanzierung auf der Basis der Elementzusammensetzung ergibt für das relativ schmale Interval von C,70-0,92% Rr ein Massenverlust von 20% durch Migration. Diese Angabe basiert auf einer 20%igen Reduzierung der ursprünglichen Wasserstoffmenge, wobei die restlichen 80% in der Kohle gespeichert bleiben.

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Résumé Dans un forage pratiqué à travers le Westphalien B du nord de l'Allemagne, on a sélectionné plus de 60 échantillons provenant de 5 couches de charbon ainsi que des siltites et grès adjacents, dans le but d'étudier la formation et la migration du bitume. Les carottes proviennent de profondeurs situées entre 1200 et 1530 m. Dans cet intervalle, le pouvoir réflecteur de la vitrinite (Rr) passe de 0,70 à 0,92%. L'étude révèle des potentiels élevés en hydrocarbure pour tous les échantillons de charbon, mais pas pour les roches détritiques voisines, bien que les compositions «macérales» soient analogues dans les deux cas. L'importance et la composition des extrait athermiques des charbons dépendent de la composition «macérale» et du degré d'évolution. Toutefois, la plus grande partie du bitume engendré est restée sur place au cours de la houillification naturelle et elle est difficile à extraire avex la methode de thermovaporisation. Une balance des masses d'éléments indique pour cet intervalle relativement étroit (0,7–0,92% Rr) une perte totale de masse de 20% due à la migration. Ce résultat correspond à une perte d'environ 20% de l'hydrogène originel, les 80% restants étant demeurés dans le charbon.

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A Note on Robust Estimates

It is well known that the mean can be an unsatisfactory estimator of a true value if data are a poor approximation to a normal distribution or are too few in number for a normal distribution to be adequately delineated. Unfortunately, this knowledge is not always implemented in the evaluation of analytical data. The median may be used occasionally because it is recognised to be less affected by discrepent data. However, there are other 'robust' estimators which can be better than the simple median. This note complements a previous paper by the writer (1).     

The Organization of Production in High Technology Industries: An Empirical Assessment*

Recent attention given to the concept of vertical integration and disintegration of production processes has identified the existence of a continuum, with small, flexibly specialized producers at one end and large, mass production units at the other end. Firms along the continuum constantly strive for the optimum combination of economies of scale and scope. This paper attempts to identify the organizational characteristics of high technology firms in one industrial complex of the U.S. Manufacturing Belt. A principal components analysis is performed on a number of theoretically relevant variables for a sample of high technology establishments in Northeast Ohio. The results indicate that the region contains a variety of organizational forms ranging from isolated workshops to large, vertically integrated assembly plants. These findings conform to expectations derived from recent conceptualizations in the literature. Additional empirical research will further enhance understanding of the processes that shape the organization of production in territorial complexes.     

Resonant tidal disruption in galactic nuclei

It has recently been shown by Rauch 38 Tremaine that the rate of angular momentum relaxation in nearly Keplerian star clusters is greatly increased by a process termed 'resonant relaxation'; it was also argued, via a series of scaling arguments, that tidal disruption of stars in galactic nuclei containing massive black holes could be noticeably enhanced by this process. We describe here the results of numerical simulations of resonant tidal disruption which quantitatively test the predictions made by Rauch 38 Tremaine. The simulation method is based on an N -body routine incorporating cloning of stars near the loss cone and a semirelativistic symplectic integration scheme. Normalized disruption rates for resonant and non-resonant nuclei are derived at orbital energies both above and below the critical energy, and the corresponding angular momentum distribution functions are found. The black hole mass above which resonant tidal disruption is quenched by relativistic precession is determined. We also briefly describe the discovery of chaos in the Wisdom–Holman symplectic integrator applied to highly eccentric orbits and propose a modified integration scheme that remains robust under these conditions. We find that resonant disruption rates exceed their non-resonant counterparts by an amount consistent with the predictions; in particular, we estimate the net tidal disruption rate for a fully resonant cluster to be about twice that of its non-resonant counterpart. No significant enhancement in rates is observed outside the critical radius. Relativistic quenching of the effect is found to occur for hole masses M  >  M _Q  = (8 ± 3) × 10⁷  M . The numerical results combined with the observed properties of galactic nuclei indicate that for most galaxies the resonant enhancement to tidal disruption rates will be very small.