Maturation related changes in the distribution of ester bound fatty acids and alcohols in a coal series from the New Zealand Coal Band covering diagenetic to catagenetic coalification levels

A rank series of lignites and coals of low to moderate maturation levels (vitrinite reflectance (R₀): 0.27–0.8%) from the New Zealand Coal Band were investigated using alkaline ester cleavage experiments to reveal compositional changes of ester bound components (fatty acids and alcohols) during increasing maturation. Ester bound alcohols are found to be present in highest amounts in the very immature lignite samples (R₀: 0.27–0.29%), but show a rapid decrease during early diagenesis. Ester bound fatty acids also show an initial exponential decrease during diagenesis, but reveal an intermittent increase during early catagenesis before decreasing again during main catagenesis. This intermittent increase was related to the short chain fatty acids. To obtain a maturity related signal and to eliminate facies related scattering in the amounts of fatty acids in the coal samples, the carbon preference index of fatty acids (CPI_FA) parameter is introduced here. For the long chain fatty acids (C₂₀–C₃₂) originating from terrigenous plant debris, the CPI_FA decreases with increasing maturity, showing a strong maturation related signal. During diagenesis, the same trend can be observed for the short chain fatty acids, but the intermittent increase in the amounts of short chain fatty acids is also accompanied by high CPI_FA values. This indicates less altered organic biomass at this advanced maturation level and is in contrast to the mature CPI_FA signal of the long chain fatty acids of the same samples. One possible reason for this discrepancy could be extremely different amounts of short and long chain fatty acids in the original source organic matter of these samples. However, another intriguing explanation could be the incorporation of immature bacterial biomass from deep microbial communities containing C₁₆ and C₁₈ fatty acids as main cell membrane components. Deep microbial life might be stimulated at this interval by the increasing release of thermally generated potential substrates from the organic matrix during early catagenesis. In contrast to the fatty acids, the high amounts of alcohols in the immature lignite samples are also visible in the alkene distribution from the open system pyrolysis experiments of the organic matrix before and after saponification.     

Fifty years of organisational change in container shipping: regional shift and the role of family firms

Spectacular growth has marked the industry initiated by Malcolm McLean with the sailing of the Ideal-X in 1956. While the growth of container shipping has been typically seen in terms of technological advances, increasing vessel capacity, traffic growth, financial performance and competitiveness, it has been shaped also by organisational transformations. This paper provides an overview of the major companies that make up the container shipping industry, tracing the rapid adoption of containerisation by American carriers to its diffusion to Europe and then Asia. While several carriers belong to business conglomerates, the most dynamic in recent years have been those that are those that possess a family structure. About 12 of the present top 20 carriers are largely family controlled, including 4 out of the top 5. Unlike other capital intensive industries, where the power has shifted towards corporate governance, the container shipping industry retains a strong individualistic entrepreneurial character. At a time when North American ownership in container shipping is no more, the spirit of innovation began 50 years ago by an American visionary is still evident in the entrepreneurial dynamism of many of the industry leaders.     

Crossing Boundaries in a Collaborative Modeling Workspace

There is substantial literature on the importance of bridging across disciplinary and science–management boundaries. One of the ways commonly suggested to cross boundaries is for participants from both sides of the boundary to jointly produce information (i.e., knowledge co-production). But simply providing tools or bringing people together in the same room is not sufficient. Here we present a case study documenting the mechanisms by which managers and scientists collaborated to incorporate climate change projections into Colorado’s State Wildlife Action Plan. A critical component of the project was the use of a collaborative modeling and visualization workspace: the U.S. Geological Survey’s Resource for Advanced Modeling (RAM). Using video analysis and pre/post surveys from this case study, we examine how the RAM facilitated cognitive and social processes that co-produced a more salient and credible end product. This case provides practical suggestions to scientists and practitioners who want to implement actionable science.     

The diurnal variation of atomic hydrogen

This note critically examines the relative importance of several effects which influence the diurnal variation of atomic hydrogen abundance near the critical level.It is pointed out that the neglect of exospheric hydrogen in a recent theoretical treatment causes an overestimation of the diurnal variation at high exospheric temperatures, and an underestimation at low exospheric temperatures. The fluxes due to lateral flow are large compared to other fluxes only to the extent that the actual diurnal variation is very different from the diurnal variation corresponding to zero net lateral flow, which does not seem to be the case in the real atmosphere. Two effects which are probably important are charge exchange reactions with thermal oxygen ions, resulting in a diurnal exchange with the plasmasphere; and charge exchange reactions with high velocity protons, resulting in enhanced escape and diurnal variation.     

Equity vs. Efficiency: Public Capital Investment in Ohio, 1988–1992

Recent research on the role of public capital in the economy focuses primarily on assessing its economic, and sometimes spatial economic, impacts. Access to more detailed and disaggregate data than typically used in these analyses allows us to take a fresh perspective on the often conflicting goals of interregional equity and aggregate efficiency. Using the state of Ohio as a case study, and classic definitions of equity and efficiency, we assess the correspondence between distributions of infrastructure investment and the social/economic distress they are intended to alleviate. Traditional map and statistical analysis combined with a graphical device we call the variegated distribution plot reveals that, in both rates and levels, investment is highest in areas of greatest distress. Both patterns are consistent with equity-driven investment distributions.     

Depthimeter-Precise Vessel Depth for Bathymetry

This article describes the design, operation, and field testing of the depthimeter. The depthimeter merges heave and acoustically derived vessel depth to form estimates of instantaneous vessel depth and instantaneous sea surface height, both relative to mean sea level. Results from sea trials held in December 1997 demonstrate successful operation of the system.     

The Rhenohercynian passive margin of SW England: Development,inversion and extensional reactivation

The SW England Rhenohercynian passive margin initiated with rift-related non-marine sedimentation and bimodal magmatism (Late Lockhovian). Continued lithospheric extension resulted in the exhumation of mantle peridotites and limited seafloor spreading (Emsian-Eifelian). Variscan convergence commenced during the Late Eifelian and was coeval with rifting further north. Collision was marked by the Early Carboniferous emergence of deep marine sedimentary/volcanic rocks from the distal continental margin, oceanic lithosphere, pre-rift basement and upper plate gneisses (correlated with the Mid-German Crystalline High of the Saxothuringian Zone). Progressive inversion of the passive margin was strongly influenced by rift basin geometry. Convergence ceased in the Late Carboniferous and was replaced by an extensional regime that reactivated basin controlling/thrust faults and reorientated earlier fabrics (Start-Perranporth Zone). The resultant exhumation of the lower plate was accompanied by emplacement of the Early Permian SW England granites and was contemporaneous with upper plate sedimentary basin formation above the reactivated Rhenohercynian suture. The Rhenohercynian passive margin probably developed in a marginal basin north of the Rheic Ocean or, possibly, a successor basin following its closure. The Lizard ophiolite is unlikely to represent Rheic Ocean floor or associated forearc (SSZ) crust. The Rheic and Rhenohercynian sutures may be coincident or the Rheic suture may be located further south in the Léon Domain.     

Reconstructing recent sedimentation in two urbanised coastal lagoons (NSW,Australia) using radioisotopes and geochemistry

In this study, we combined grain size and geochemical analyses with radioisotope analysis of lead-210 (²¹⁰Pb), caesium-137 (¹³⁷Cs) and radiocarbon (¹⁴C) ages to reconstruct the sedimentation history of two urbanised coastal lagoons in south-east Australia. Towradgi and Fairy Lagoons were both found to exhibit slow initial sedimentation of less than 1 mm year⁻¹ prior to anthropogenic influences. Land clearing in the catchments increased runoff and erosion in the creeks feeding into the estuaries, and has resulted in progradation of fluvial material into the estuarine systems with a marked increase in sedimentation to between 2 and 7 mm year⁻¹. The upper 20–50 cm of the sediment column in both lagoons contained elevated concentrations of heavy metals such as Pb, Cu, Ni and Zn. This pollution trend was found to be consistent with the history of industrialisation and urbanisation in the region, which expanded rapidly post World War 2. The total metal concentrations were consistent with other urbanised/industrialised estuaries around the world. Despite the fairly disturbed nature of these coastal lagoons, the use of ²¹⁰Pb, ¹³⁷Cs and ¹⁴C dating in combination with bulk geochemical analyses allowed detailed reconstruction of sedimentation history.