Determining Effects of Area Burned and Fire Severity on Carbon Cycling and Emissions in Siberia

The Russian boreal forest contains about 25% of the global terrestrial biomass, and even a higher percentage of the carbon stored in litter and soils. Fire burns large areas annually, much of it in low-severity surface fires – but data on fire area and impacts or extent of varying fire severity are poor. Changes in land use, cover, and disturbance patterns such as those predicted by global climate change models, have the potential to greatly alter current fire regimes in boreal forests and to significantly impact global carbon budgets. The extent and global importance of fires in the boreal zone have often been greatly underestimated. For the 1998 fire season we estimate from remote sensing data that about 13.3 million ha burned in Siberia. This is about 5 times higher than estimates from the Russian Aerial Forest Protection Service (Avialesookhrana) for the same period. We estimate that fires in the Russian boreal forest in 1998 constituted some 14–20% of average annual global carbon emissions from forest fires. Average annual emissions from boreal zone forests may be equivalent to 23–39% of regional fossil fuel emissions in Canada and Russia, respectively. But the lack of accurate data and models introduces large potential errors into these estimates. Improved monitoring and understanding of the landscape extent and severity of fires and effects of fire on carbon storage, air chemistry, vegetation dynamics and structure, and forest health and productivity are essential to provide inputs into global and regional models of carbon cycling and atmospheric chemistry.     

Plio-Pleistocene basanitic and melilititic series of the Bohemian Massif: K-Ar ages,major/trace element and Sr–Nd isotopic data

The Plio-Pleistocene volcanic rocks of the Bohemian Massif comprise a compositional spectrum involving two series: an older basanitic series (6.0–0.8 Ma) and a younger, melilititic series (1.0–0.26 Ma). The former consists of relatively undifferentiated basaltic rocks, slightly silica-undersaturated, with Mg# ranging from 62 to almost primitive mantle-type values of 74. The major and trace element characteristics correspond to those of primitive intra-plate alkaline volcanic rocks from a common sub-lithospheric mantle source (European Asthenospheric Reservoir – EAR) including positive Nb, and negative K and Pb anomalies. ⁸⁷Sr/⁸⁶Sr ratios of 0.7032–0.7034 and ¹⁴³Nd/¹⁴⁴Nd of 0.51285–0.51288 indicate a moderately depleted mantle source as for other mafic rocks of the central European volcanic province with signs of HIMU-like characteristics commonly attributed to recycling of subducted oceanic crust in the upper mantle during the Variscan orogeny. The melilititic series is characterized by higher degrees of silica-undersaturation, and high Mg# of 68–72 values, compatible with primitive-mantle-derived compositions. The high OIB-like Ce/Pb (19–47) and Nb/U (32–53) ratios indicate that assimilation of crustal material was negligible. In both series, concentrations of incompatible elements are mildly elevated and ⁸⁷Sr/⁸⁶Sr ratios (0.7034–0.7036) and ¹⁴³Nd/¹⁴⁴Nd ratios (0.51285–0.51288) overlap. Variations in incompatible element concentrations and isotopic compositions in the basanitic series and melilititic series can be explained by a lower degree of mantle melting for the latter with preferential melting of enriched mantle domains. The Sr and Nd isotopic compositions of both rock series are similar to those of the EAR. Minor differences in geochemical characteristics between the two series may be attributed to: (i) to different settings with respect to crust and lithospheric mantle conditions in (a) Western Bohemia (WB) and (b) Northeastern Bohemia (NEB) and the Northern Moravia and Silesia (NMS) areas, (ii) a modally metasomatized mantle lithosphere in WB in contrast to cryptically metasomatized domains in the NEB and NMS, (iii) different degrees of partial melting with very low degrees in WB but higher degrees in NEB and NMS. The geochemical and isotopic similarity between the Plio-Pleistocene volcanic rocks and those of the late Cretaceous and Cenozoic (79–6 Ma) suggests that their magmas came from compositionally similar mantle sources, that underwent low degrees of melting over an interval of ∼80 Ma. The Oligocene to Miocene basanitic series that accompanied the Plio-Pleistoicene basanitic series in the NMS region indicate that they shared a common mantle source. There is no geochemical evidence for thermal erosion of the lithospheric mantle or significant changes in mantle compositions within the time of a weak thermal perturbation in the asthenospheric mantle. These perturbations were caused by a dispersed mantle plume or passively upwelling asthenosphere in zones of lithospheric thinning.     

Determination of Major and Trace Element Abundances in Selected Canmet Ore Standards by X-ray Fluorescence Spectrometry

Data for the major element oxides and seventeen trace elements (Ba, Co, Cu, Ga, La, Mo, Nb, Ni, Pb, Rb, Sb, Sn, Sr, U, Y, Zn and Zr) have been determined by X-ray fluorescence spectrometry for the CANMET ore standards MA-1, TLG-1, BH-1, CT-1, OKA-1, PR-1, HV-1, MP-2 and TAN-1.     

The Roles of Reconnected Flux and Overlying Fields in CME Speeds

Researchers have reported i) correlations of coronal mass ejection (CME) speeds and the total photospheric magnetic flux swept out by flare ribbons in flare-associated eruptive events, and, separately, ii) correlations of CME speeds and more rapid decay, with height, of magnetic fields in potential-field coronal models above eruption sites. Here, we compare the roles of both ribbon fluxes and the decay rates of overlying fields in a set of 16 eruptive events. We confirm previous results that higher CME speeds are associated with both higher ribbon fluxes and more rapidly decaying overlying fields. We find the association with ribbon fluxes to be weaker than a previous report, but stronger than the dependence on the decay rate of overlying fields. Since the photospheric ribbon flux is thought to approximate the amount of coronal magnetic flux reconnected during the event, the correlation of speeds with ribbon fluxes suggests that reconnection plays some role in accelerating CMEs. One possibility is that reconnected fields that wrap around the rising ejection produce an increased outward hoop force, thereby increasing CME acceleration. The correlation of CME speeds with more rapidly decaying overlying fields might be caused by greater downward magnetic tension in stronger overlying fields, which could act as a source of drag on rising ejections.     

Temporal and spatial variability of sea level and volume flux in the Murderkill Estuary

The instantaneous sea level determined at two sites in the Murderkill Estuary, a tributary of Delaware Bay, results from the superposition of temporal variability operating over different time and spatial scales. Over the relatively short tidal time scales, the semidiurnal tides that represent the dominant tidal constituents in lower Delaware Bay show a modest increase in tidal amplitudes from the bay mouth (Lewes, Delaware), up to Bowers Beach (the mouth of the Murderkill Estuary). However, as the tides propagate into the Murderkill Estuary, the semidiurnal constituents undergo heavy attenuation, resulting in a 48% reduction in tidal amplitude from Bowers to Frederica (approximately the extent of saline intrusion). The diurnal tide, on the other hand, experiences only a 25% reduction in amplitude. The limited tidal asymmetry that is observed may be a result of interaction between flows in the tidal channel and the adjacent salt marsh. At longer time scales, the subtidal sea level experiences no attenuation. The Murderkill Estuary thus behaves like a low pass filter to preferentially damp out high frequency sea level forcing from lower Delaware Bay. The subtidal volume flux in the Murderkill is highly coherent with the time rate of change of sea level, indicating that the Murderkill basically co-oscillates with Delaware Bay in a standing wave fashion over the subtidal time scale. This remote coupling controls more than 90% of the variance in subtidal sea level in the estuary. The surface slopes in the lower bay and the Murderkill Estuary are closely correlated with winds along the orientation of the two waterways, consistent with the effect of local wind on subtidal sea level.     

An unusual occurrence of coesite at the Lonar crater,India

Coesite has been identified within ejected blocks of shocked basalt at Lonar crater, India. This is the first report of coesite from the Lonar crater. Coesite occurs within SiO₂ glass as distinct ~30 μm spherical aggregates of “granular coesite” identifiable both with optical petrography and with micro‐Raman spectroscopy. The coesite+glass occurs only within former silica amygdules, which is also the first report of high‐pressure polymorphs forming from a shocked secondary mineral. Detailed petrography and NMR spectroscopy suggest that the coesite crystallized directly from a localized SiO₂ melt, as the result of complex interactions between the shock wave and these vesicle fillings.     

Use of voltammetric solid-state (micro)electrodes for studying biogeochemical processes: Laboratory measurements to real time measurements with an in situ electrochemical analyzer (ISEA)

Solid-state voltammetric (micro)electrodes have been used in a variety of environments to study biogeochemical processes. Here we show the wealth of information that has been obtained in the study of sediments, microbial mats, cultures and the water column including hydrothermal vents. Voltammetric analyzers have been developed to function with operator guidance and in unattended mode for temporal studies with an in situ electrochemical analyzer (ISEA). The electrodes can detect the presence (or absence) of a host of redox species and trace metals simultaneously. The multi-species capacity of the voltammetric electrode can be used to examine complex heterogeneous environments such as the root zone of salt marsh sediments. The data obtained with these systems clearly show that O₂ and Mn²⁺ profiles in marine sedimentary porewaters and in microbial biofilms on metal surfaces rarely overlap indicating that O₂ is not a direct oxidant for Mn²⁺. This lack of overlap was suggested originally by Joris Gieskes' group. In waters emanating from hydrothermal vents, Fe²⁺, H₂S and soluble molecular FeS clusters (FeS_aq) are detected indicating that the reactants for the pyrite formation reaction are H₂S and soluble molecular FeS clusters. Using the ISEA with electrodes at fixed positions, data collected continuously over three days near a Riftia pachyptila tubeworm field generally show that O₂ and H₂S anti-correlate and that H₂S and temperature generally correlate. Unlike sedimentary environments, the data clearly show that Riftia live in areas where both O₂ and H₂S co-exist so that its endosymbiont bacteria can perform chemosynthesis. However, physical mixing of diffuse flow vent waters with oceanic bottom waters above or to the side of the tubeworm field can dampen these correlations or even reverse them. Voltammetry is a powerful technique because it provides chemical speciation data (e.g.; oxidation state and different elemental compounds/ions) as well as quantitative data. Because (micro)organisms occupy environmental niches due to the system's chemistry, it is necessary to know chemical speciation. Voltammetric methods allow us to study how chemistry drives biology and how biology can affect chemistry for its own benefit.     

Hydrologic variability in black ash wetlands: Implications for vulnerability to emerald ash borer

Black ash (Fraxinus nigra) wetlands are widespread, forested landscape features in the western Great Lakes region. However, the future of these ecosystems is threatened due to impending spread of the invasive emerald ash borer (EAB), which results in tree mortality, decreased transpiration, and potential shifts to wetter, non-forested conditions. The vulnerability to such ecohydrologic shifts likely varies according to local hydrologic regimes controlled by landscape settings, but this site-dependent vulnerability and our ability to predict it is unknown. Here, we assessed vulnerability potential as a function of site hydrology in 15 undisturbed black ash wetlands from their three most common hydrogeomorphic settings in northern Minnesota: lowland, depression, and transition. Further, we used high-resolution (1-cm) surface elevation models to assess spatial variability of water levels at a subset of 10 sites. Although we observed similar ET and groundwater exchange rates among settings, lowland sites were generally drier because of elevated landscape position and greater water level drawdowns (via lower specific yield). We predict that such drier sites will exhibit greater water level increases following EAB-induced ash mortality, compared to wetter sites where open water evaporation and shallow-rooted understory transpiration will offset losses in tree transpiration. Moreover, compared to wetter sites, drier sites exhibited minimal microtopographic variation, limiting the number of elevated microsites for tree establishment and eventual canopy recovery after ash loss. These results suggest that site wetness is a simple and effective predictor of black ash wetland vulnerability to hydrologic regime change. To that end, we assessed the ability of common terrain metrics to predict site wetness, providing a potential tool to target vulnerable areas for active management efforts.     

Approaching four decades of forest watershed research at Upper Penticton Creek,British Columbia: A synthesis

Over the past 35 years, the Upper Penticton Creek (UPC) Watershed Experiment has supported forest hydrology research in south-central British Columbia (BC), Canada. This paper provides a synthesis of research results, highlights the challenges facing UPC and identifies new research directions. Clearcutting approximately 50% of two small, snow-dominated (Dfb Koppen classification) watersheds advanced the timing of snowmelt-generated high flows and decreased late-summer low flows, relative to predictions based on pre-treatment regressions. Changes in high flows did not have a significant effect on stream channels due to low stream power, coarse substrate, and limited riparian disturbance. Changes in summer low flows reduced modelled useable fish habitat by 20%–50%. Evaporation averaged 52% of the annual precipitation in the mature forest, was reduced to 30% in a clearcut, and recovered to 40% and 47% in a 10 and 25 year-old stand, respectively. Groundwater recharge to the bedrock was estimated at 19% of annual precipitation, indicating that, even with the large uncertainty associated with this estimate, deep groundwater should not be ignored in the water balance. Suspended sediment, turbidity, and colour increased post-logging; however, chemical surface water quality did not change. Aquatic community structure changed post-logging; and although this affected the processing of organic matter, the effects on habitat quality were considered minimal. The information gained at UPC has supported provincial policies, management guidelines, forest stewardship plans and watershed risk assessments. The undisturbed control watershed, re-growing treatment watersheds and ongoing long-term hydrometric monitoring continue to provide opportunities for future research addressing issues such as the effects of young forests on streamflow and hydrologic recovery, and the influence of climate change on the hydrologic regime.     

Calcite U–Pb age of the Cretaceous vertebrate‐bearing Bayn Shire Formation in the Eastern Gobi Desert of Mongolia: Usefulness of caliche for age determination

To verify the usefulness of calcite U–Pb measurement for vertebrate‐bearing strata in the Eastern Gobi, Mongolia, we performed laser ablation‐inductively coupled plasma‐mass spectrometry calcite U–Pb and trace element analyses of three caliche (calcrete) of the Bayn Shire Formation. The trace element analysis demonstrates high concentration of U in the calcites. Two meaningful calcite U–Pb ages were obtained; 95.9 ± 6.0 and 89.6 ± 4.0 Ma, which are consistent with published ages from the Bayn Shire Formation. Our results demonstrate that the calcite U–Pb method can be powerful tool for age determination of vertebrate‐bearing strata in the Gobi that do not contain index fossils or beds, but do contain caliches. This would make it possible for a comparison of biostratigraphy between the Gobi and other areas yielding abundant vertebrate fossils in Asia, North America and Europe, based on chronological data.