Instrumentation Development for In Situ 40Ar/39Ar Planetary Geochronology

The chronology of the Solar System, particularly the timing of formation of extra‐terrestrial bodies and their features, is an outstanding problem in planetary science. Although various chronological methods for in situ geochronology have been proposed (e.g., Rb‐Sr, K‐Ar), and even applied (K‐Ar), the reliability, accuracy, and applicability of the ⁴⁰Ar/³⁹Ar method makes it by far the most desirable chronometer for dating extra‐terrestrial bodies. The method however relies on the neutron irradiation of samples, and thus a neutron source. Herein, we discuss the challenges and feasibility of deploying a passive neutron source to planetary surfaces for the in situ application of the ⁴⁰Ar/³⁹Ar chronometer. Requirements in generating and shielding neutrons, as well as analysing samples are described, along with an exploration of limitations such as mass, power and cost. Two potential solutions for the in situ extra‐terrestrial deployment of the ⁴⁰Ar/³⁹Ar method are presented. Although this represents a challenging task, developing the technology to apply the ⁴⁰Ar/³⁹Ar method on planetary surfaces would represent a major advance towards constraining the timescale of solar system formation and evolution.     

Rebuttal to the comment by Malhotra and Strom on “Constraints on the source of lunar cataclysm impactors”

?uk et al. (?uk, M. Gladman, B.J., Stewart, S.T. [2010]. Icarus 207 590-594) concluded that the the lunar cataclysm (late heavy bombardment) was recorded in lunar Imbrian era craters, and that their size distribution is different from that of main belt asteroids (which may have been the dominant pre-Imbrian impactors). This result would likely preclude the asteroid belt as the direct source of lunar cataclysm impactors. Malhotra and Strom (Malhotra, R., Strom, R.G. [2011]. Icarus) maintain that the lunar impactor population in the Imbrian era was the same as in Nectarian and pre-Nectarian periods, and this population had a size distribution identical to that of main belt asteroids. In support of this claim, they present an Imbrian size distribution made from two data sets published by Wilhelms et al. (Wilhelms, D.E., Oberbeck, V.R., Aggarwal, H.R. [1978]. Proc. Lunar Sci. Conf. 9, 3735-3762). However, these two data sets cannot be simply combined as they represent areas of different ages and therefore crater densities. Malhotra and Strom (Malhotra, R., Strom, R.G. [2011]. Icarus) differ with the main conclusion of Wilhelms et al. (Wilhelms, D.E., Oberbeck, V.R., Aggarwal, H.R. [1978]. Proc. Lunar Sci. Conf. 9, 3735-3762) that the Nectarian and Imbrian crater size distributions were different. We conclude that the available data indicate that the lunar Imbrian-era impactors had a different size distribution from the older ones, with the Imbrian impactor distribution being significantly richer in small impactors than that of older lunar impactors or current main-belt asteroids.     

Contrasting rainfall generated debris flows from adjacent watersheds at Forest Falls, southern California, USA

Debris flows are widespread and common in many steeply sloping areas of southern California. The San Bernardino Mountains community of Forest Falls is probably subject to the most frequently documented debris flows in southern California. Debris flows at Forest Falls are generated during short-duration high-intensity rains that mobilize surface material. Except for debris flows on two consecutive days in November 1965, all the documented historic debris flows have occurred during high-intensity summer rainfall, locally referred to as ‘monsoon’ or ‘cloudburst’ rains. Velocities of the moving debris range from about 5 km/h to about 90 km/h. Velocity of a moving flow appears to be essentially a function of the water content of the flow. Low velocity debris flows are characterized by steep snouts that, when stopped, have only small amounts of water draining from the flow. In marked contrast are high-velocity debris flows whose deposits more resemble fluvial deposits. In the Forest Falls area two adjacent drainage basins, Snow Creek and Rattlesnake Creek, have considerably different histories of debris flows. Snow Creek basin, with an area about three times as large as Rattlesnake Creek basin, has a well developed debris flow channel with broad levees. Most of the debris flows in Snow Creek have greater water content and attain higher velocities than those of Rattlesnake Creek. Most debris flows are in relative equilibrium with the geometry of the channel morphology. Exceptionally high-velocity flows, however, overshoot the channel walls at particularly tight channel curves. After overshooting the channel, the flows degrade the adjacent levee surface and remove trees and structures in the immediate path, before spreading out with decreasing velocity. As the velocity decreases the clasts in the debris flows pulverize the up-slope side of the trees and often imbed clasts in them. Debris flows in Rattlesnake Creek are relatively slow moving and commonly stop in the channel. After the channel is blocked, subsequent debris flows cut a new channel upstream from the blockage that results in the deposition of new debris-flow deposits on the lower part of the fan. Shifting the location of debris flows on the Rattlesnake Creek fan tends to prevent trees from becoming mature. Dense growths of conifer seedlings sprout in the spring on the late summer debris flow deposits. This repeated process results in stands of even-aged trees whose age records the age of the debris flows.     

Using GIS and large-scale digital data to implement hedonic pricing studies

This paper describes how a standard GIS package can be used to convert large-scale vector digital data (point, line and annotation features) into polygons using standardised and replicable methods. Building area, garden and land use polygons are all derived from such data (Ordnance Survey LandLine.Plus). These entities are then combined with further sources of digital data to derive more refined information such as property types. Finally, complex DEMs are developed for use in visibility studies. The variables calculated are subsequently employed in a property valuation study where many are found to be significant determinants of property price. The main exception is variables relating to viewsheds, although it is argued that this does not invalidate the techniques used in their deviation but highlights the difficulties involved in modelling a large number of variables in a property price analysis.     

Evaluating legacy contaminants and emerging chemicals in marine environments using adverse outcome pathways and biological effects-directed analysis

Natural and synthetic chemicals are essential to our daily lives, food supplies, health care, industries and safe sanitation. At the same time protecting marine ecosystems and seafood resources from the adverse effects of chemical contaminants remains an important issue. Since the 1970s, monitoring of persistent, bioaccumulative and toxic (PBT) chemicals using analytical chemistry has provided important spatial and temporal trend data in three important contexts; relating to human health protection from seafood contamination, addressing threats to marine top predators and finally providing essential evidence to better protect the biodiversity of commercial and non-commercial marine species. A number of regional conventions have led to controls on certain PBT chemicals over several years (termed ‘legacy contaminants’; e.g. cadmium, lindane, polycyclic aromatic hydrocarbons [PAHs] and polychlorinated biphenyls [PCBs]). Analytical chemistry plays a key role in evaluating to what extent such regulatory steps have been effective in leading to reduced emissions of these legacy contaminants into marine environments. In parallel, the application of biomarkers (e.g. DNA adducts, CYP1A-EROD, vitellogenin) and bioassays integrated with analytical chemistry has strengthened the evidence base to support an ecosystem approach to manage marine pollution problems. In recent years, however, the increased sensitivity of analytical chemistry, toxicity alerts and wider environmental awareness has led to a focus on emerging chemical contaminants (defined as chemicals that have been detected in the environment, but which are currently not included in regulatory monitoring programmes and whose fate and biological impacts are poorly understood). It is also known that natural chemicals (e.g. algal biotoxins) may also pose a threat to marine species and seafood quality. Hence complex mixtures of legacy contaminants, emerging chemicals and natural biotoxins in marine ecosystems represent important scientific, economic and health challenges. In order to meet these challenges and pursue cost-effective scientific approaches that can provide evidence necessary to support policy needs (e.g. the European Marine Strategy Framework Directive), it is widely recognised that there is a need to (i) provide marine exposure assessments for priority contaminants using a range of validated models, passive samplers and biomarkers; (ii) integrate chemical monitoring data with biological effects data across spatial and temporal scales (including quality controls); and (iii) strengthen the evidence base to understand the relationship between exposure to complex chemical mixtures, biological and ecological impacts through integrated approaches and molecular data (e.g. genomics, proteomics and metabolomics). Additionally, we support the widely held view that (iv) that rather than increasing the analytical chemistry monitoring of large number of emerging contaminants, it will be important to target analytical chemistry towards key groups of chemicals of concern using effects-directed analysis. It is also important to evaluate to what extent existing biomarkers and bioassays can address various classes of emerging chemicals using the adverse outcome pathway (AOP) approach now being developed by the Organization for Economic Cooperation and Development (OECD) with respect to human toxicology and ecotoxicology.     

Quantifying urban land cover change between 2001 and 2006 in the Gulf of Mexico region

We estimated urbanization rates (2001–2006) in the Gulf of Mexico region using the National Land Cover Database (NLCD) 2001 and 2006 impervious surface products. An improved method was used to update the NLCD impervious surface product in 2006 and associated land cover transition between 2001 and 2006. Our estimation reveals that impervious surface increased 416 km² with a growth rate of 5.8% between 2001 and 2006. Approximately 1110.1 km² of non-urban lands were converted into urban land, resulting in a 3.2% increase in the region. Hay/pasture, woody wetland, and evergreen forest represented the three most common land cover classes that transitioned to urban. Among these land cover transitions, more than 50% of the urbanization occurred within 50 km of the coast. Our analysis shows that the close-to-coast land cover transition trend, especially within 10 km off the coast, potentially imposes substantial long-term impacts on regional landscape and ecological conditions.     

Vegetation Response to Prescribed Fire in Mid-Atlantic Brackish Marshes

Prescribed fire management generally stimulates plant biomass production in coastal marsh systems. This study was conducted to understand the interactive effects of the mechanisms of fire on vegetation production. The effects of canopy removal and ash deposition on biomass production were investigated in two manipulative experiments at the Blackwater National Wildlife Refuge, Dorchester County, MD. On non-burned sites, canopy removal increased biomass production above and belowground (40 and 260?%, respectively), while ash deposition showed no effect on production. On burned sites, post-burn canopy replacement decreased biomass production above and belowground (41 and 40?%, respectively). Production increased more in response to canopy removal at sites dominated by Schoenoplectus americanus than at sites dominated by Spartina patens and Distichlis spicata. Canopy removal was the dominant mechanism through which fire affected biomass production in this study. If increased biomass production is a desirable outcome, prescribed fire programs may benefit by maximizing canopy removal.     

The degradation characteristics of microbial biomass in soil

Soil microbial biomass is a primary source of soil organic carbon (SOC) and therefore plays a fundamental role in carbon and nitrogen cycling. However, little is known about the fate and transformations of microbial biomass in soil. Here we employ HR-MAS NMR spectroscopy to monitor ¹³C and ¹⁵N labeled soil microbial biomass and leachate degradation over time. As expected, there is a rapid loss of carbohydrate structures. However, diffusion edited HR-MAS NMR data reveals that macromolecular carbohydrates are more resistant to degradation and are found in the leachate. Aromatic components survive as dissolved species in the leachate while aliphatic components persist in both the biomass and leachate. Dissolved protein and peptidoglycan accumulate in the leachate and recalcitrant amide nitrogen and lipoprotein persists in both the degraded biomass and leachate. Cross-peaks that appear in ¹H-¹⁵N HR-MAS NMR spectra after degradation suggest that specific peptides are either selectively preserved or used for the synthesis of unknown structures. The overall degradation pathways reported here are similar to that of decomposing plant material degraded under similar conditions suggesting that the difference between recalcitrant carbon from different sources is negligible after decomposition.     

Global photometric properties of Asteroid (4) Vesta observed with Dawn Framing Camera

Dawn spacecraft orbited Vesta for more than one year and collected a huge volume of multispectral, high-resolution data in the visible wavelengths with the Framing Camera. We present a detailed disk-integrated and disk-resolved photometric analysis using the Framing Camera images with the Minnaert model and the Hapke model, and report our results about the global photometric properties of Vesta. The photometric properties of Vesta show weak or no dependence on wavelengths, except for the albedo. At 554 nm, the global average geometric albedo of Vesta is 0.38 ± 0.04, and the Bond albedo range is 0.20 ± 0.02. The bolometric Bond albedo is 0.18 ± 0.01. The phase function of Vesta is similar to those of S-type asteroids. Vesta’s surface shows a single-peaked albedo distribution with a full-width-half-max ∼17% relative to the global average. This width is much smaller than the full range of albedos (from ∼0.55× to >2× global average) in localized bright and dark areas of a few tens of km in sizes, and is probably a consequence of significant regolith mixing on the global scale. Rheasilvia basin is ∼10% brighter than the global average. The phase reddening of Vesta measured from Dawn Framing Camera images is comparable or slightly stronger than that of Eros as measured by the Near Earth Asteroid Rendezvous mission, but weaker than previous measurements based on ground-based observations of Vesta and laboratory measurements of HED meteorites. The photometric behaviors of Vesta are best described by the Hapke model and the Akimov disk-function, when compared with the Minnaert model, Lommel–Seeliger model, and Lommel–Seeliger–Lambertian model. The traditional approach for photometric correction is validated for Vesta for >99% of its surface where reflectance is within ±30% of global average.     

New views of Betelgeuse: multi-wavelength surface imaging and implications for models of hotspot generation

We report contemporaneous multi-wavelength interferometric imaging of the red supergiant star Betelgeuse ( α Orionis), using the Cambridge Optical Aperture Synthesis Telescope (COAST) and the William Herschel Telescope (WHT), at wavelengths of 700, 905 and 1290 nm. We find a strong variation in the apparent symmetry of the stellar brightness distribution as a function of wavelength. At 700 nm the star is highly asymmetric, and can be modelled as the superposition of three bright spots on a strongly limb-darkened disc. However, at 905 nm only a single low-contrast feature is visible and at 1290 nm the star presents a featureless symmetric disc. The change in spot contrast with wavelength is consistent with a model in which the bright spots represent unobscured areas of elevated temperature, owing perhaps to convection, on a stellar disc that itself has a different appearance, i.e. geometrical extent and limb-darkening profile, at different wavelengths. The featureless centre-to-limb brightness profile seen at 1290 nm is consistent with this model and suggests that future interferometric monitoring of the star to quantify the size changes associated with radial velocity variations should be performed at similar wavelengths in the near-infrared.