Absolute measurements and computed values for Martian irradiance between 10.5 and 12.5 μm

The combination of seasonal and orbital changes in Martian insolation result in complex latitude dependent surface temperature variations that effect the total radiance of the planet as seen from the earth. These surface temperature variations have been calculated, based upon a computer simulation of the thermal environment of the planet. The temperature variations are then integrated to yield the total radiance of the planet as seen from the earth as a function of time. The absolute radiance of Mars was measured on April 4, 1971, with a balloon-borne radiometer system operating in the wavelength range between 10.5 and 12.5 μm. The average brightness temperature of the Mars disk determined from these measurements was 254°K with a 1 σ error of 4°K.     

Climate change and control of the southeastern Bering Sea pelagic ecosystem

We propose a new hypothesis, the Oscillating Control Hypothesis (OCH), which predicts that pelagic ecosystem function in the southeastern Bering Sea will alternate between primarily bottom-up control in cold regimes and primarily top-down control in warm regimes. The timing of spring primary production is determined predominately by the timing of ice retreat. Late ice retreat (late March or later) leads to an early, ice-associated bloom in cold water (e.g., 1995, 1997, 1999), whereas no ice, or early ice retreat before mid-March, leads to an open-water bloom in May or June in warm water (e.g., 1996, 1998, 2000). Zooplankton populations are not closely coupled to the spring bloom, but are sensitive to water temperature. In years when the spring bloom occurs in cold water, low temperatures limit the production of zooplankton, the survival of larval/juvenile fish, and their recruitment into the populations of species of large piscivorous fish, such as walleye pollock (Theragra chalcogramma), Pacific cod (Gadus macrocephalus) and arrowtooth flounder (Atheresthes stomias). When continued over decadal scales, this will lead to bottom-up limitation and a decreased biomass of piscivorous fish. Alternatively, in periods when the bloom occurs in warm water, zooplankton populations should grow rapidly, providing plentiful prey for larval and juvenile fish. Abundant zooplankton will support strong recruitment of fish and will lead to abundant predatory fish that control forage fish, including, in the case of pollock, their own juveniles. Piscivorous marine birds and pinnipeds may achieve higher production of young and survival in cold regimes, when there is less competition from large piscivorous fish for cold-water forage fish such as capelin (Mallotus villosus). Piscivorous seabirds and pinnipeds also may be expected to have high productivity in periods of transition from cold regimes to warm regimes, when young of large predatory species of fish are numerous enough to provide forage. The OCH predicts that the ability of large predatory fish populations to sustain fishing pressure will vary between warm and cold regimes.The OCH points to the importance of the timing of ice retreat and water temperatures during the spring bloom for the productivity of zooplankton, and the degree and direction of coupling between zooplankton and forage fish. Forage fish (e.g., juvenile pollock, capelin, Pacific herring [Clupea pallasii]) are key prey for adult pollock and other apex predators. In the southeastern Bering Sea, important changes in the biota since the mid-1970s include a marked increase in the biomass of large piscivorous fish and a concurrent decline in the biomass of forage fish, including age-1 walleye pollock, particularly over the southern portion of the shelf. Populations of northern fur seals (Callorhinus ursinus) and seabirds such as kittiwakes (Rissa spp.) at the Pribilof Islands have declined, most probably in response to a diminished prey base. The available evidence suggests that these changes are unlikely the result of a decrease in total annual new primary production, though the possibility of reduced post-bloom production during summer remains. An ecosystem approach to management of the Bering Sea and its fisheries is of great importance if all of the ecosystem components valued by society are to thrive. Cognizance of how climate regimes may alter relationships within this ecosystem will facilitate reaching that goal.     

Deconvolving the pre-Himalayan Indian margin-Tales of crustal growth and destruction

The metamorphic core of the Himalaya is composed of Indian cratonic rocks with two distinct crustal affinities that are defined by radiogenic isotopic geochemistry and detrital zircon age spectra. One is derived predominantly from the Paleoproterozoic and Archean rocks of the Indian cratonic interior and is either represented as metamorphosed sedimentary rocks of the Lesser Himalayan Sequence(LHS) or as slices of the distal cratonic margin. The other is the Greater Himalayan Sequence(GHS) whose provenance is less clear and has an enigmatic affinity. Here we present new detrital zircon Hf analyses from LHS and GHS samples spanning over 1000 km along the orogen that respectively show a striking similarity in age spectra and Hf isotope ratios. Within the GHS, the zircon age populations at 2800-2500 Ma,1800 Ma, 1000 Ma and 500 Ma can be ascribed to various Gondwanan source regions; however, a pervasive and dominant Tonianage population(～860-800 Ma) with a variably enriched radiogenic Hf isotope signature(eHf = 10 to-20) has not been identified from Gondwana or peripheral accreted terranes. We suggest this detrital zircon age population was derived from a crustal province that was subsequently removed by tectonic erosion. Substantial geologic evidence exists from previous studies across the Himalaya supporting the Cambro-Ordovician Kurgiakh Orogeny. We propose the tectonic removal of Tonian lithosphere occurred prior to or during this Cambro-Ordovician episode of orogenesis in a similar scenario as is seen in the modern Andean and Indonesian orogenies, wherein tectonic processes have removed significant portions of the continental lithosphere in a relatively short amount of time. This model described herein of the pre-Himalayan northern margin of Greater India highlights the paucity of the geologic record associated with the growth of continental crust. Although the continental crust is the archive of Earth history, it is vital to recognize the ways in which preservation bias and destruction of continental crust informs geologic models.     

The P–V–T equation of state of CaPtO3 post-perovskite

Orthorhombic post-perovskite CaPtO₃ is isostructural with post-perovskite MgSiO₃, a deep-Earth phase stable only above 100 GPa. Energy-dispersive X-ray diffraction data (to 9.4 GPa and 1,024 K) for CaPtO₃ have been combined with published isothermal and isobaric measurements to determine its P–V–T equation of state (EoS). A third-order Birch–Murnaghan EoS was used, with the volumetric thermal expansion coefficient (at atmospheric pressure) represented by α(T) = α₀ + α₁(T). The fitted parameters had values: isothermal incompressibility, $ K_{{T_{0} }} $  = 168.4(3) GPa; $ K_{{T_{0} }}^{\prime } $  = 4.48(3) (both at 298 K); $ \partial K_{{T_{0} }} /\partial T $  = ?0.032(3) GPa K^?1; α₀ = 2.32(2) × 10^?5 K^?1; α₁ = 5.7(4) × 10^?9 K^?2. The volumetric isothermal Anderson–Grüneisen parameter, δ _T , is 7.6(7) at 298 K. $ \partial K_{{T_{0} }} /\partial T $ for CaPtO₃ is similar to that recently reported for CaIrO₃, differing significantly from values found at high pressure for MgSiO₃ post-perovskite (?0.0085(11) to ?0.024 GPa K^?1). We also report axial P–V–T EoS of similar form, the first for any post-perovskite. Fitted to the cubes of the axes, these gave $ \partial K_{{aT_{0} }} /\partial T $  = ?0.038(4) GPa K^?1; $ \partial K_{{bT_{0} }} /\partial T $  = ?0.021(2) GPa K^?1; $ \partial K_{{cT_{0} }} /\partial T $  = ?0.026(5) GPa K^?1, with δ _T  = 8.9(9), 7.4(7) and 4.6(9) for a, b and c, respectively. Although $ K_{{T_{0} }} $ is lowest for the b-axis, its incompressibility is the least temperature dependent.     

Revisiting the orogenic energy balance in the western Taiwan orogen with weak faults

Orogens at convergent margins must meet the energetic requirements necessary to lift rocks against gravity, allow for frictional sliding along basal detachments and accommodate internal deformation processes. The combination of critical taper and kinematic wedge theories predicts the partitioning between these energy sinks as a function of both fault and crustal strengths. Integrating contemporary estimates of both crustal pore fluid pressures and the coefficient of friction on major faults, we find that work associated with internal deformation processes is the dominant energy sink in the western Taiwan orogenic wedge. These processes consume 54% of the total work budget, while the dissipation rates associated with frictional sliding on the basal detachment and lifting rocks against gravity are lower, requiring only 11% and 35% respectively. These results suggest a mechanical dichotomy in orogenic wedges where the faulting dominates the kinematic deformation budget, but internal distributed deformation processes dominate the energy budget.     

Relationships between sediment contamination and toxicity in San Francisco Bay

Sediment contamination and toxicity were monitored at 14 sites in San Francisco Bay between 1991 and 1996. Sediment contamination patterns were different in the major reaches of the Bay, and at each site. Several contaminants were consistently above concentrations previously associated with toxicity at most sites. Bulk sediment bioassays using the amphipod Eohaustorius estuarius and sediment elutriate bioassays using larval bivalves (Mytilus spp., Crassostrea gigas) also indicated different patterns of sediment toxicity in space and time. Sediments were most toxic to the amphipods at Redwood Creek (90% of the tests), and were toxic in at least half the tests conducted at five other sites. Sediment elutriates severely reduced normal bivalve larval development at the San Joaquin and Sacramento Rivers in all samples, but toxicity occurred in less than a third of the tests in the Central and South Bays. Toxicity could not be statistically related to seasonal freshwater flow or rainfall in the Bay, but seasonal variation in contaminant concentrations and toxicity was observed. Amphipod toxicity was inversely and significantly related to the mean effects range-median quotient, suggesting that cumulative concentrations of several contaminants were related to toxicity. Further analysis identified suites of specific contaminants at each site that were variably related to amphipod toxicity at each site. Chlordanes, cadmium, and silver were significantly related to amphipod survival in the North Bay. Seasonal patterns in low, and high molecular weight polycyclic aromatic hydrocarbons (PAHs) were related to toxicity at Alameda, and metals and PAHs were related to toxicity at Castro Cove. Larval bivalve toxicity was associated with metals in bulk sediments, but elutriate chemistry was not measured, and relationships with toxicity could not be examined. Hypotheses about effective concentrations of several individual contaminants and mixtures of contaminants were posed.     

Assessing changes in nutrient status in the Richmond River estuary,Australia, using paleolimnological methods

Eutrophication from nutrient over-enrichment is a serious problem for the coastal zone and the estuarine environment globally. Australian estuaries are generally oligotrophic, but assessing whether they are becoming more eutrophic over time is inhibited by a lack of long-term monitoring data. The Richmond River, Australia, provided an ideal example of an estuary under anthropogenic pressure where the use of paleoecological techniques may potentially be used to reconstruct changes in nutrient status over time. Five cores were extracted from depositional areas in the Richmond River, and subjected to paleo-magnetic profiling and loss-on-ignition testing to ensure the core of greatest integrity was selected for further analytical work. Results from diatom and stable isotope analyses combined with ²¹⁰Pb and AMS ¹⁴C dating show a strong indication that the total phosphorus levels in the Richmond River have fluctuated since 1940. Evidence also suggests that these fluctuations are most likely a function of climate. This study has successfully applied paleolimnological techniques to the estuarine environment to produce information that can be used by environmental managers to aid decision making in relation to nutrient control for the Richmond River. Further work using paleolimnological techniques should be aimed at the extraction of a core containing diatoms that pre-date European settlement and include analyses of specific lipids and fatty acid biomarkers.     

Theory And Measurements For Turbulence Spectra And Variances In The Atmospheric Neutral Surface Layer

Predictions from a new theory for high Reynolds number turbulent boundary layers during near-neutral conditions are shown to agree well with measurements of atmospheric surface-layer variances and spectra. The theory suggests surface-layer turbulence is determined by detached eddies that largely originate in the shearing motion immediately above the surface layer; as they descend into this layer, they are strongly distorted by the local shear and impinge onto the surface. Because the origin of these eddies is non-local, they are similar to those described in previous studies as `inactive' turbulence. However, they are, in fact, dynamically highly active, supplying the major mechanism for the momentum transport, including upward bursting on the time scale of the larger eddies. The vertical velocity results show that the variance and the low frequency parts of spectra increase with height in the surface layer, while in the self similar (k₁ ^-1) range the streamwise low frequency components are approximately constant with height. These large-scale longitudinal eddies extend to a length _s, which is equal to the boundary-layer height near the surface andincreases linearly to a maximum of about three times the boundary-layer height at roughly 15 m and decreases in the upper parts of the surface layer. This lower part of the surface layer, the eddy surface layer, is the region in which the eddies impinging from layers above are strongly distorted. This new result for the atmospheric boundary layer has practical application for calculating fluctuating wind loads on structures and lateral dispersion of pollution from local sources.