Maintenance of Near-Surface Stratification in Doubtful Sound, a New Zealand Fjord

The surface waters of Doubtful Sound, a glacially carved fjord in south-western New Zealand, feature a quasi-permanent low-salinity-layer (LSL). The LSL is maintained year round by the extreme precipitation in the catchment (7 m yr⁻¹) and discharge from a hydroelectric power station (450 m³ s⁻¹). The robust, stable LSL has been shown to play a major role in controlling intertidal and subtidal community structure. By contrast, little is known about the dynamics of the LSL itself. The work presented here elucidates the response of the LSL to perturbations in the wind stress and rainfall.Frequency-domain analysis of salinity data collected from an array of moored instruments revealed that the LSL responded to perturbations in both the winds and rainfall. However, the specific roles of the wind stress and rain could not be adequately resolved in these analyses. By contrast, simulations of the response of the LSL using a three-dimensional primitive equation model revealed that strong up-fjord directed wind events set up a storm surge at the head of the fjord. This surge significantly deepens the LSL at the head of the fjord and retards or reverses estuarine circulation. The subsequent relaxation of the surge after the abatement of the wind stress resulted in a redistribution of buoyancy throughout the fjord over a two-day period. It is shown that the development and relaxation of the storm surge is a major process controlling the maintenance of the near-surface stratification.     

Alkalinity production as an indicator of failure in steel slag leach beds treating acid mine drainage

Acid mine drainage is a serious environmental problem throughout mining regions of the US and around the world. In Appalachia, reuse of steel slag from steel production as a source of alkalinity for treatment of acid mine drainage has become a common practice. In these systems, dubbed steel slag leach beds, relatively clean surface water is percolated through a bed of steel slag to add large amounts of alkalinity to the water before mixing it with acidic, metalliferous mine water. These beds do not operate consistently and their failure mechanisms are poorly understood. Using the experience of Raccoon Creek watershed in southern Ohio, the alkalinity distribution of the discharge of six steel slag leach beds is compared. Two of these beds are still functional, one has been abandoned and three are operating poorly. The difference in alkalinity distribution between these beds suggests that a carbonate-dominated alkalinity system is an indicator of a poorly performing steel slag leach bed, while a more even distribution between hydroxide, carbonate and bicarbonate may point to more ideal operating conditions. In eight laboratory column experiments, this evidence was then expanded upon by testing different mixed media substrates (differing mixes of steel slag, wood chips and river gravel) to see which provided the most ideal alkalinity distributions. The columns that had steel slag mixed either with wood chips or wood chips and river gravel outperformed the column with slag only in terms of alkalinity distribution, perhaps due to microbial processes or increased hydraulic conductivity without significant added calcium or carbon that could drive calcium carbonate precipitation within the beds and causing them to fail.     

TRANSFORMATION PATTERNS OF SUBAERIAL MICRO-TIDAL BEACHES

Seven subaerial, low energy beaches in the SE Mediterranean were surveyed biweekly for 13 months. Beach level data were computer-processed and plotted as time-series profile diagrams that differentiated the subaerial beach into three basic subenvironments: backshore, berm, and swash-zone. Heterogeneous seasonal trends in beach sand budget, erosion/accretion patterns, occurrence of ridges and berm-crests, and in pollution by seaborne tar were observed. The profile stations also showed very different degrees of seasonality, although located along similar beaches. Local beachrock protection, when evident, effectively masked seasonality by significantly lowering beach dynamics. Biweekly, seasonal, and annual fluctuations of the beach sand-budget were computed. Average annual net sand flux at the seven beaches was 66 m³/m of beach front, though wide variations occurred. Annual changes in the sand budget along the study area exceeded volumetric changes within the profile, indicating longshore sand transfer. Synchronism of beach behavior prevailed only at the seasonal level. However, intra-seasonal fluctuations for the different profile stations were out of phase, indicating poor synchronism of beach response due to longshore movement of rhythmic topography. Profile changes were thus often unrelated to concomitant wave-climate changes. The overall heterogeneous beach response was in sharp contrast to the identical wave climate, similar bathymetry, and sedimentology of the studied beaches.     

Storm‐dominated shelf‐edge delta successions in a high accommodation setting: The palaeo‐Orinoco Delta (Mayaro Formation), Columbus Basin,South‐East Trinidad

Pliocene age deposits of the palaeo‐Orinoco Delta are evaluated in the Mayaro Formation, which crops out along the western margin of the Columbus Basin in south‐east Trinidad. This sandstone‐dominated interval records the diachronous, basinwards migration of the shelf edge of the palaeo‐Orinoco Delta, as it prograded eastwards during the Pliocene–Pleistocene (ca 3·5 Ma). The basin setting was characterized by exceptionally high rates of growth‐fault controlled sediment supply and accommodation space creation resulting in a gross basin‐fill of around 12 km, with some of the highest subsidence rates in the world (ca 5 to 10 m ka^?1). This analysis demonstrates that the Mayaro Formation was deposited within large and mainly wave‐influenced shelf‐edge deltas. These are manifested as multiple stacks of coarsening upward parasequences at scales ranging from tens to hundreds of metres in thickness, which are dominated by storm‐influenced and wave‐influenced proximal delta‐front sandstones with extensive, amalgamated swaley and hummocky cross‐stratification. These proximal delta‐front successions pass gradationally downwards into 10s to 100 m thick distal delta front to mud‐dominated upper slope deposits characterized by a wide variety of sedimentary processes, including distal river flood and storm‐related currents, slumps and other gravity flows. Isolated and subordinate sandstone bodies occur as gully fills, while extensive soft sediment deformation attests to the high sedimentation rates along a slope within a tectonically active basin. The vertical stratigraphic organization of the facies associations, together with the often cryptic nature of parasequence stacking patterns and sequence stratigraphic surfaces, are the combined product of the rapid rates of accommodation space creation, high rates of sediment supply and glacio‐eustasy in the 40 to 100 Ka Milankovitch frequency range. The stratigraphic framework described herein contrasts strikingly with that described from passive continental margins, but compares favourably to other tectonically active, deltaic settings (for example, the Baram Delta Province of north‐west Borneo).     

The Rose Spit Eddy in Dixon Entrance: Evidence for its existence and underlying dynamics

Abstract

The existence and dynamics of the so‐called “Rose Spit Eddy” in Dixon Entrance, British Columbia, are investigated by (i) analysing published observations of low‐frequency Eulerian and Lagrangian currents in the region; (ii) interpreting tidal residuals produced by the Hecate Model (a non‐rotating hydraulic model of Hecate Strait and Dixon Entrance); and (iii) running a barotropic, non‐linear numerical tidal model over simplified topography to investigate residuals produced over the Rose Spit sill.

Observations have consistently revealed persistent basin‐wide, surface‐intensified cyclonic shears within central and eastern Dixon Entrance. The Hecate hydraulic tidal model also produced a tidal residual cyclonic gyre in central Dixon Entrance, but with velocities considerably larger than those observed. Barotropic numerical simulations of tidal streams flowing over a representation of the Rose Spit sill produced residual flows along the sill in reasonable agreement with observations and theory. A southward‐directed jet flow was produced off Cape Chacon. Elsewhere, tidal rectification was weak. Run without the Coriolis force, organized flow along the sill broke down, although the headland jet off Cape Chacon persisted.

We submit that the observed Rose Spit eddy results from interactions between buoyancy‐driven coastal currents and tidally rectified flows generated over the Rose Spit sill, and near Cape Chacon, and perhaps indirectly, over the western flank of Learmonth Bank (which although west of the Rose Spit eddy, contributes to the cross‐channel flow across the Entrance). These regions of localized tidal stress will each favour recirculation of a portion of the coastal current within the Entrance, helping to form the eddy.

We believe that the Hecate hydraulic model eddy was generated to a significant degree by phase errors introduced at the northern open boundary, where a rocking barrier was used to force currents. A second rocking barrier also produced a large cyclonic gyre, not supported by observations, near the model's southern boundary.     

An improved method for 21-cm foreground removal

21-cm tomography is expected to be difficult in part because of serious foreground contamination. Previous studies have found that line-of-sight approaches are capable of cleaning foregrounds to an acceptable level on large spatial scales, but not on small spatial scales. In this paper, we introduce a Fourier space formalism for describing the line-of-sight methods, and use it to introduce an improved new method for 21-cm foreground cleaning. Heuristically, this method involves fitting foregrounds in Fourier space using weighted polynomial fits, with each pixel weighted according to its information content. We show that the new method reproduces the old one on large angular scales, and gives marked improvements on small scales at essentially no extra computational cost.     

Thermodynamic consistency of Raoult’s Law and Henry’s Law approaches for multiphase organic aerosol partitioning

Partitioning of semivolatile organic compounds between gas, organic aerosol, and aqueous aerosol phases has been described in atmospheric models using Raoult’s Law and/or Henry’s Law, with activity coefficients accounting for nonideal behavior in the aerosol solutions. Raoult’s Law and Henry’s Law are thermodynamically consistent with each other as long as the parameters defining their different reference states are accurately known. Unfortunately, saturation vapor pressures, Henry’s law constants, and activity coefficients for organic aerosol compounds must typically be estimated. As a result, thermodynamic inconsistencies can arise when using Raoult’s and Henry’s Law approaches together due to errors in estimation methods. A test of predicted partitioning parameters for representative semivolatile organics suggests overall errors of at least an order of magnitude. Box model simulations with a simplified partitioning scenario demonstrate that these estimation errors can significantly alter partitioning for many compounds and, more importantly, that thermodynamic inconsistencies will lead to even greater errors than those due solely to uncertain parameters. To avoid these errors, a common reference state should be used to define equilibrium among all phases, improved estimation methods and measurements should continue to be pursued, and alternative reference states that better represent typical organic aerosol mixtures should be explored.