Isotopic constraints on the Si-biogeochemical cycle of the Antarctic Zone in the Kerguelen area (KEOPS)

Estimation of the silicon (Si) mass balance in the ocean from direct measurements (Si uptake-dissolution rates …) is plagued by the strong temporal and spatial variability of the surface ocean as well as methodological artifacts. Tracers with different sensitivities toward physical and biological processes would be of great complementary use. Silicon isotopic composition is a promising proxy to improve constraints on the Si-biogeochemical cycle, since it integrates over longer timescales in comparison with direct measurements and since the isotopic balance allows to resolve the processes involved, i.e. uptake, dissolution, mixing. Si-isotopic signatures of seawater Si(OH)₄ and biogenic silica (bSiO₂) were investigated in late summer 2005 during the KEOPS experiment, focusing on two contrasting biogeochemical areas in the Antarctic Zone: a natural iron-fertilized area above the Kerguelen Plateau (< 500 m water depth) and the High Nutrient Low Chlorophyll area (HNLC) east of the plateau (> 1000 m water depth). For the HNLC area the Si-isotopic constraint identified Upper Circumpolar Deep Water as being the ultimate Si-source. The latter supplies summer mixed layer with 4.0 ± 0.7 mol Si m^? 2 yr^? 1. This supply must be equivalent to the net annual bSiO₂ production and exceeds the seasonal depletion as estimated from a simple mixed layer mass balance (2.5 ± 0.2 mol Si m^? 2 yr^? 1). This discrepancy reveals that some 1.5 ± 0.7 mol Si m^? 2 yr^? 1 must be supplied to the mixed layer during the stratification period. For the fertilized plateau bloom area, a low apparent mixed layer isotopic fractionation value (?³⁰Si) probably reflects (1) a significant impact of bSiO₂ dissolution, enriching the bSiO₂ pool in heavy isotope; and/or (2) a high Si uptake over supply ratio in mixed layer at the beginning of the bloom, following an initial closed system operating mode, which, however, becomes supplied toward the end of the bloom (low Si uptake over supply ratio) with isotopically light Si(OH)₄ from below when the surface Si(OH)₄ pool is significantly depleted. We estimated a net integrated bSiO₂ production of 10.5 ± 1.4 mol Si m^? 2 yr^? 1 in the AASW above the plateau, which includes a significant contribution of bSiO₂ production below the euphotic layer. However, advection which could be significant for this area has not been taken into account in the latter estimation based on a 1D approach of the plateau system. Finally, combining the KEOPS Si-isotopic data with those from previous studies, we refined the average Si-isotopic fractionation factor to ? 1.2 ± 0.2‰ for the Antarctic Circumpolar Current.     

Cloud filling of ocean colour and sea surface temperature remote sensing products over the Southern North Sea by the Data Interpolating Empirical Orthogonal Functions methodology

Optical remote sensing data is now being used systematically for marine ecosystem applications, such as the forcing of biological models and the operational detection of harmful algae blooms. However, applications are hampered by the incompleteness of imagery and by some quality problems. The Data Interpolating Empirical Orthogonal Functions methodology (DINEOF) allows calculation of missing data in geophysical datasets without requiring a priori knowledge about statistics of the full dataset and has previously been applied to SST reconstructions. This study demonstrates the reconstruction of complete space–time information for 4 years of surface chlorophyll a (CHL), total suspended matter (TSM) and sea surface temperature (SST) over the Southern North Sea (SNS) and English Channel (EC). Optimal reconstructions were obtained when synthesising the original signal into 8 modes for MERIS CHL and into 18 modes for MERIS TSM. Despite the very high proportion of missing data (70%), the variability of original signals explained by the EOF synthesis reached 93.5% for CHL and 97.2% for TSM. For the MODIS TSM dataset, 97.5% of the original variability of the signal was synthesised into 14 modes. The MODIS SST dataset could be synthesised into 13 modes explaining 98% of the input signal variability. Validation of the method is achieved for 3 dates below 2 artificial clouds, by comparing reconstructed data with excluded input information. Complete weekly and monthly averaged climatologies, suitable for use with ecosystem models, were derived from regular daily reconstructions. Error maps associated with every reconstruction were produced according to Beckers et al. (2006). Embedded in this error calculation scheme, a methodology was implemented to produce maps of outliers, allowing identification of unusual or suspicious data points compared to the global dynamics of the dataset. Various algorithm artefacts were associated with high values in the outlier maps (undetected cloud edges, haze areas, contrails, and cloud shadows). With the production of outlier maps, the data reconstruction technique becomes also a very efficient tool for quality control of optical remote sensing data and for change detection within large databases.     

Cold Dust and Very Cold Excess Emission in the Galaxy

We provide insight in the origin of the far-IR to mm emission from galaxies by presenting a decomposition of the Galaxy emission where we separate the contributions from dust in the atomic gas and dust associated with quiescent molecular gas as a function of Galacto-centric distance. This decomposition leaves a puzzling very cold emission excess with a brightness independent of Galactic longitude that might be pointing at interstellar matter in the outer Galaxy not traced by H I nor CO emission. This revised version was published online in September 2006 with corrections to the Cover Date.     

Line-broadening effects in the powder infrared spectrum of apatite

The crystallinity of natural and synthetic apatite samples is often determined from the broadening of ν ₄ PO₄ infrared absorption bands. However, various physical mechanisms contribute to the observed linewidth. In the present study, the factors determining the linewidth in the powder spectrum of synthetic fluorapatite and hydroxyapatite samples are investigated. The temperature dependence of the infrared spectrum (10–270 K) is used to assess the respective contributions of homogeneous broadening, related to the decay of phonons through anharmonic coupling, and heterogeneous broadening related to elastic strain and macroscopic electrostatic effects. This latter contribution is dominant in the investigated samples and depends on the shape of powder particles. It is discussed under the light of the theoretical modeling of the low-frequency dielectric properties of apatite based on first-principles density functional theory calculations. The linewidth of the weak ν ₁ PO₄ absorption band provides a reliable information on microscopic sources of broadening, i.e., apatite crystallinity. In comparison, the other more intense PO₄ bands are more sensitive to long-range electrostatic effects.     

Mapping and spatial analysis of the soybean agricultural frontier in Mato Grosso, Brazil, using remote sensing data

The main pioneer frontier considered by geographers is the Amazonian pioneer frontier. The occupation of the Brazilian territory has been carried out through successive economic cycles. Currently, the expansion of soybean crops in Amazonia is considered as the last economic cycle involving new migrations to still unexplored areas. Mapping this frontier is necessary in order to better understand its drivers and think about efficient land use policies to struggle its progress. In this paper, we propose an innovative methodology for mapping the agricultural frontier in the Amazonian state of Mato Grosso (Brazil) using satellite data acquired during the 2000–2006 period. We assume that the frontier evolves through successive land-use stages such as wildlands, non-croplands, extensive croplands and intensive croplands areas. The transitions between two stages can then be monitored through land-use change analysis. A particular emphasis is given on three land-use transitions named “deforestation”, “economic” and “intensification sub-frontiers”. In order to adapt this model for the use of remote sensing data, we defined (1) a relevant spatial scale corresponding to an agrarian locality, (2) relevant indices to qualify the land-use types and (3) rules applied on land-use types to define the frontier’s location. Our results highlight the dynamic of the agricultural frontier towards northern areas. We identified four main agricultural regions with different levels of agricultural intensification. We finally discuss these results with respect to governmental policies and economics for a better understanding of the frontier’s dynamic.     

Fine‐grained material encased in microtracks of Stardust samples

Dust from comet 81P/Wild 2 was captured at high speed in silica aerogel collectors during the Stardust mission. Studies of deceleration tracks in aerogel showed that a number of cometary particles were poorly cohesive and fragmented during impact. Fragments are now scattered along the walls of impact cavities. Here, we report a transmission electron microscope study of a piece of aerogel extracted from the wall of track 10. We focused on micron‐sized secondary tracks along which fragments of a fine‐grained material are disseminated. Two populations of fragments were identified. The first is made of polycrystalline silicate assemblages (olivine, pyroxene, and spinel) that appear to be chemically related to each other. The second corresponds to silica‐rich glassy clumps characteristic of a mixture of melted cometary material and aerogel. A significant number of fragments have been found with a composition close to chondritic CI for the major elements Fe‐Mg‐S at a submicron scale. These fragments have thus never been chemically differentiated by high‐temperature processes prior to the accretion on the comet, in contrast to terminal particles, which are dominated by larger, denser, and frequently monomineralic components.     

Comparison of model noise in AGCM independent ensemble runs and continuous simulation

Atmospheric General Circulation models (AGCMs) forced by prescribed sea surface temperature (SST) climatological seasonal cycle simulate interannual variabilities that have cyclic characteristics. Such cyclic characteristics generate relationships between one year and the next in the model output. We document these relationships by computing lag-1-year autocorrelation in hundreds of years of CAM3 and ECHAM5 simulations. The autocorrelation is found to be generally less than 0.2, but contain robust structures. In case of zonal averaged zonal wind and air temperature the winter hemisphere is characterized by negative autocorrelation and the summer hemisphere characterized by positive autocorrelation. The presence of autocorrelation means that an average over a 10～25 year AGCM simulation in an effort to reduce the influence of interannual variability on externally-driven climate change might not be very effective. In view of this, we investigate if ensemble runs instead of a continuous simulation is more effective in reducing such influences. The reduction gain by using N 1-year long ensemble runs over N years of continuous run is generally less than 30% and mainly limited to the areas where the autocorrelation is positive. We thus conclude that each year in a continuous simulation can generally be treated as largely independent of the next year in an AGCM run with fixed SST forcing.     

Sustainable development and anthropogenic induced geomorphic hazards in subsiding areas

In many areas of the world, subsidence related to the lowering of the water table is modifying the landscape and provoking costly environmental hazards. We consider the Dead Sea (the Earth's lowest lake) as a model. Its water level was 395 m bMSL in the 1960s. Due to water diversions in the catchment area, as of 2016, the level has dropped to about 430 m bMSL. Here, as in other parts of the Anthropocene world, from China, to Iran, to Turkey, to Canada and the United States, consequences of human interventions are rapidly modifying the environment. Aggressive geomorphic processes leading to accelerated degradations are taking place and affecting landforms and infrastructures. In Tectonic terms, the lake is a pull‐apart basin resulting from the motion of the Dead Sea Transform fault. Since the 1960s, a slice of brine of about 35 km³ has been lost. The water table is dropping more rapidly in the lake than in the coastal zone creating an ever‐increasing head difference. Consequently, groundwater moves towards the sea to compensate for the imbalance, provoking the reactivation of the area's paleo‐channels with subsidence, sinkholes, and landslides. Since the 1980s, industrial‐touristic infrastructure has covered newly emerging lands in geomorphic hazards‐prone areas of the coastal zone. Time series analysis of high to very high resolution visible/radar satellite images acquired from the 1970s to present, revealed major landscape evolution. Such dynamic systems prevailing in recent decades permitted the study of human/environment interactions to help minimize their effects. Major deformations of an industrial dike were analysed and quantified. The results underline the necessity in the Anthropocene of careful analysis of relevant data sources acquired before and during subsidence, particularly in karst topography zones and prior to the development of major human activities in economically appealing environments around the world. Copyright © 2016 John Wiley & Sons, Ltd.     

New constraints on the delivery of cometary water and nitrogen to Earth from the N/N isotopic ratio

New independent constraints on the amount of water delivered to Earth by comets are derived using the ¹⁵N/¹⁴N isotopic ratio, measured to be roughly twice as high in cometary CN and HCN as in the present Earth. Under reasonable assumptions, we find that no more than a few percent of Earth’s water can be attributed to comets, in agreement with the constraints derived from D/H. Our results also suggest that a significant part of Earth’s atmospheric nitrogen might come from comets. Since the ¹⁵N/¹⁴N isotopic ratio is not different in Oort-cloud and Kuiper-belt comets, our estimates apply to the contribution of both types of objects.     

Pyroxenes microstructure in comet 81P/Wild 2 terminal Stardust particles

Abstract— We report the examination by transmission electron microscopy (TEM) of four Stardust terminal particles extracted from two neighboring tracks (32 an 69). The particles are made of well‐preserved crystalline grains dominated by low‐Ca pyroxene ranging from nearly pure enstatite to pigeonite. Some olivine grains are also found, in chemical equilibrium with the surrounding pyroxenes. Various microstructures are observed, as a function of the composition of the grains. They include (100)‐twinned pigeonite, clino/ortho domains in enstatite and exsolution in a Ca‐rich grain. The microstructures are mostly consistent with a formation by cooling from high‐temperature phases, which could be associated to igneous processes. Some dislocations in glide configuration are also present, probably attesting for small intensity shocks. Possible effects of the rapid heating/cooling stage and thermal shock associated to the collect are discussed. It appears that most of the microstructural features reported here are plausibly pristine.