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91.
Total mercury concentrations were determined in surficial sediments, eleven species of benthic organisms and six species of fish from Haifa Bay, Israel. The results show that essentially all of the shallow water zone of the Bay receives anthropogenic mercury. A mercury-cell chlor-alkali plant was identified as the source of pollution. Surficial sediments in the vicinity of the plant, containing up to 0·99 μg Hg/g dry weight, were up to 157 times enriched in mercury relative to an unpolluted area. Mercury levels in the benthic organisms reflected the levels in the sediments. Maximal concentrations reaching 38·7 and 18·2 μg Hg/g dry weight were found in the carnivorous gastropod molluscs Arcularia circumcinta and Arcularia gibbosula, respectively. In all fish species, specimens caught in Haifa Bay had higher mercury concentrations in the muscle tissue than specimens caught south of the Bay. A maximal value of 1·66 μg Hg/g wet weight was recorded in Diplodus sargus. 相似文献
92.
Thermogenic organic matter dissolved in the abyssal ocean 总被引:1,自引:2,他引:1
Formation and decay of thermogenic organic matter are important processes in the geological carbon cycle, but little is known about the fate of combustion-derived and petrogenic compounds in the ocean. We explored the molecular structure of marine dissolved organic matter (DOM) for thermogenic signatures in different water masses of the Southern Ocean. Ultrahigh-resolution mass spectrometry via the Fourier transform-ion cyclotron resonance technique (FT-ICR-MS) revealed the presence of polyaromatic hydrocarbons (PAHs) dissolved in the abyssal ocean. More than 200 different PAHs were discerned, most of them consisting of seven condensed rings with varying numbers of carboxyl, hydroxyl, and aliphatic functional groups. These unambiguously thermogenic compounds were homogenously distributed in the deep sea, but depleted at the sea surface. Based on the structural information alone, petrogenic and pyrogenic compounds cannot be distinguished. Surface depletion of the PAHs and first estimates for their turnover rate (> 1.2 · 1012 mol C per year) point toward a primarily petrogenic source, possibly deep-sea hydrothermal vents, which is thus far speculative because the fluxes of combustion-derived and petrogenic matter to the ocean are not well constrained. We estimate that > 2.4% of DOM are thermogenic compounds, and their global inventory in the oceans is > 1.4 · 1015 mol C, significantly impacting global biogeochemical cycles. 相似文献
93.
Charlene P. Bargeron David J. Hydes David K. Woolf Boris A. Kelly-Gerreyn Mohammed A. Qurban 《Estuarine, Coastal and Shelf Science》2006,69(3-4):478
Seasonal new production (g C m−2) estimates obtained from dissolved oxygen and nitrate concentrations in surface waters (5 m depth) along a track between the UK (Portsmouth) and northern Spain (Bilbao) are compared. An oxygen flux method, in combination with a ship of opportunity (SOO), was tested on the northwest European shelf for its value in distinguishing high production in frontal regions. Dissolved oxygen, nitrate and chlorophyll a samples were collected monthly from February to July 2004, alongside continuous autonomous measurements of salinity, temperature and chlorophyll fluorescence. Depth integrated new production estimates for all the individually analysed hydrographic regions of the route were produced.Results from three widely used gas-exchange parameterizations gave seasonal (February–July) new production estimates of 54–68 g C m−2 for the Ushant region of the western English Channel and 31–40 g C m−2 for the shelf slope, averaging 24–31 g C m−2 for the route. This is double the route average obtained using the nitrate assimilation method (17 g C m−2) and within the ranges of previous estimates in the same region. The oxygen flux method gave a fivefold enhancement compared to the nitrate method in the Ushant frontal region and a threefold enhancement in the English Channel and shelf break regions. Determining oxygen fluxes to estimate new production may be more reliable than nitrate assimilation in active tidal or frontal regions of shelves where nitrate may be added to the system post-winter through advection or entrainment. 相似文献
94.
Boris Garfinkel 《Celestial Mechanics and Dynamical Astronomy》1984,34(1-4):459-463
In 1911 E. W. Brown conjectured that the family of long-periodic orbits in the Trojan case of the restricted problem of three bodies terminates in an asymptotic orbit that passes through the Langrangian point L3 for t=±. The paper refutes this conjecture analytically, thereby confirming the previously published numerical refutation by Henrard (1983). 相似文献
95.
Nadezhda KANYGINA Andrey TRETYAKOV Dmitriy ALEXEIEV Kirill DEGTYAREV Anfisa SKOBLENKO Natalia SOLOSHENKO Boris ERMOLAEV 《《地质学报》英文版》2024,98(1):67-82
The combined petrographic, petrological, geochemical and geochronological study of the Neoproterozoic gneisses of the Sarychabyn and Baskan complexes of the Junggar Alataw of South Kazakhstan elucidate the Precambrian tectonic evolution of the Aktau–Yili terrane. It is one of the largest Precambrian crustal blocks in the western Central Asian orogenic belt. The U-Pb single-grain zircon ages indicate that granite-gneisses formed from the same source and crystallised in the early Neoproterozoic ca. 930–920 Ma. The chemical composition of gneisses corresponds to A2-type granites. The whole-rock Nd isotopic characteristics (εNd(t) = ?4.9 to ?1.0 and TNd(DM-2st) = 1.9 to 1.7 Ga) indicate the involvement of Paleoproterozoic crustal rocks in magma generation. Early Neoproterozoic ca. 930–920 Ma A-type granitoids in the Aktau–Yili terrane of South and Central Kazakhstan might reflect within-plate magmatism adjacent to the collisional belt or a local extension setting in back-arc areas of the continental arc. 相似文献
96.
Kelly-Gerreyn BA Hydes DJ Hartman MC Siddorn J Hyder P Holt MW 《Marine pollution bulletin》2007,54(7):850-862
This study evaluates the ship of opportunity (Ferrybox) concept for both sustained monitoring of UK shelf sea waters and numerical model validation. Release of phosphate from the wreck of a chemical tanker (MV Ece) in the western English Channel (49.73 degrees N, 3.25 degrees W) in March 2006 is used to demonstrate the importance of sustained observations in decision support systems and policy development. The Ferrybox system continuously collects sea surface (5m) data from a suite of autonomous electronic sensors installed on a passenger ferry operating year-round between Portsmouth (UK) and Bilbao (Spain). The detection of anomalously high concentrations of phosphate (1.54mmolm(-3), four times the usual level) and onset of phytoplankton growth close to the wreck site in March 2006 was placed in the context of multiple years of measurements (phosphate, nitrate, silicate and chlorophyll) collected from the Ferrybox system (2003-2006) and the long-term time series station E1 (50.03 degrees N, 4.65 degrees W, 1930-1987) in the English Channel. With regard to decision support, release of phosphate from the tanker is unlikely to pose a threat as phytoplankton growth at the end of winter is not unusual in this region and dissolved inorganic nitrogen rather than phosphate (DIN:DIP=10-18) is likely to ultimately limit algal growth in spring 2006. With regard to policy development, the Oslo and Paris (OSPAR) commissions recommendation of sampling every three years in "non-problem areas" is likely to provide statistically inadequate data, given the interannual and decadal variability identified in the Ferrybox and E1 data: the Ferrybox data show that oceanic winter nutrient concentrations varied by 35-50% between 2003/2004 and 2005/2006 due to deeper mixing of water off-shelf in early 2005/2006 and comparisons between the Ferrybox and E1 years show that the western English Channel is currently experiencing a low in phosphate concentrations similar to those in the 1960s. The importance of Ferrybox data in evaluating the reliability of predictive operational models needed in decision support is also demonstrated, by highlighting both strengths and weaknesses in a state-of-the-art ecosystem model designed for UK shelf waters. 相似文献
97.
Boris Shustov Mikhail Sachkov Ana I. Gómez de Castro Maohai Huang Klaus Werner Norbert Kappelmann Isabella Pagano 《Astrophysics and Space Science》2009,320(1-3):187-190
The World Space Observatory UltraViolet (WSO–UV) is an international space mission devoted to UV spectroscopy and imaging. The observatory includes a 170 cm aperture telescope capable of high-resolution and long slit low-resolution spectroscopy, and deep UV and optical imaging. The observatory is designed for observations in the ultraviolet domain where most of astrophysical processes can be efficiently studied with unprecedented capability. 相似文献
98.
Meghan E. Gray Christian Wolf Marco Barden Chien Y. Peng Boris Häußler Eric F. Bell Daniel H. McIntosh Yicheng Guo John A. R. Caldwell David Bacon Michael Balogh Fabio D. Barazza Asmus Böhm Catherine Heymans Knud Jahnke Shardha Jogee Eelco van Kampen Kyle Lane Klaus Meisenheimer Sebastian F. Sánchez y Taylor Lutz Wisotzki Xianzhong Zheng David A. Green R. J. Beswick D. J. Saikia Rachel Gilmour Benjamin D. Johnson Casey Papovich 《Monthly notices of the Royal Astronomical Society》2009,393(4):1275-1301
We present an overview of the Space Telescope A901/2 Galaxy Evolution Survey (STAGES). STAGES is a multiwavelength project designed to probe physical drivers of galaxy evolution across a wide range of environments and luminosity. A complex multicluster system at z ∼ 0.165 has been the subject of an 80-orbit F606W Hubble Space Telescope (HST) /Advanced Camera for Surveys (ACS) mosaic covering the full span of the supercluster. Extensive multiwavelength observations with XMM–Newton , GALEX, Spitzer , 2dF, Giant Metrewave Radio Telescope and the 17-band COMBO-17 photometric redshift survey complement the HST imaging. Our survey goals include simultaneously linking galaxy morphology with other observables such as age, star formation rate, nuclear activity and stellar mass. In addition, with the multiwavelength data set and new high-resolution mass maps from gravitational lensing, we are able to disentangle the large-scale structure of the system. By examining all aspects of an environment we will be able to evaluate the relative importance of the dark matter haloes, the local galaxy density and the hot X-ray gas in driving galaxy transformation. This paper describes the HST imaging, data reduction and creation of a master catalogue. We perform the Sérsic fitting on the HST images and conduct associated simulations to quantify completeness. In addition, we present the COMBO-17 photometric redshift catalogue and estimates of stellar masses and star formation rates for this field. We define galaxy and cluster sample selection criteria, which will be the basis for forthcoming science analyses, and present a compilation of notable objects in the field. Finally, we describe the further multiwavelength observations and announce public access to the data and catalogues. 相似文献
99.
Two coupled general circulation models, i.e., the Meteorological Research Institute (MRI) and Geophysical Fluid Dynamics Laboratory (GFDL) models, were chosen to examine changes in mixed layer depth (MLD) in the equatorial tropical Pacific and its relationship with ENSO under climate change projections. The control experiment used pre-industrial greenhouse gas concentrations whereas the 2 × CO2 experiment used doubled CO2 levels. In the control experiment, the MLD simulated in the MRI model was shallower than that in the GFDL model. This resulted in the tropical Pacific’s mean sea surface temperature (SST) increasing at different rates under global warming in the two models. The deeper the mean MLD simulated in the control simulation, the lesser the warming rate of the mean SST simulated in the 2 × CO2 experiment. This demonstrates that the MLD is a key parameter for regulating the response of tropical mean SST to global warming. In particular, in the MRI model, increased stratification associated with global warming amplified wind-driven advection within the mixed layer, leading to greater ENSO variability. On the other hand, in the GFDL model, wind-driven currents were weak, which resulted in mixed-layer dynamics being less sensitive to global warming. The relationship between MLD and ENSO was also examined. Results indicated that the non-linearity between the MLD and ENSO is enhanced from the control run to the 2 × CO2 run in the MRI model, in contrast, the linear relationship between the MLD index and ENSO is unchanged despite an increase in CO2 concentrations in the GFDL model. 相似文献
100.
K. S. Gavrichev M. A. Ryumin A. V. Tyurin V. M. Gurevich L. N. Komissarova 《Geochemistry International》2010,48(4):390-397
The heat capacity of synthetic pretulite ScPO4(c) was measured by adiabatic calorimetry within a temperature range of 12.13–345.31 K, and the temperature dependence of
the pretulite heat capacity at 0–1600 K was derived from experimental and literature data on H
0(T)-H
0(298.15 K) for Sc orthophosphate. This dependence was used to calculate the values of the following thermodynamic functions:
entropy, enthalpy change, and reduced Gibbs energy. They have the following values at 298.15 K: C
p
0 (298.15 K) = 97.45 ± 0.06 J K−1 mol−1, S
0(298.15 K) = 84.82 ± 0.18 J K−1 mol−1, H
0(298.15 K)-H
0(0) = 14.934 ± 0.016 kJ mol−1, and Φ
0(298.15 K) = 34.73 ± 0.19 J K−1mol−1. The enthalpy of formation Δ
f
H
0(ScPO4, 298.15 K) = − 1893.6 ± 8.4 kJ mol−1. 相似文献