The influences of interannual stratification variability and wind stress forcing on ENSO before and after the 1976 climate shift

In order to understand the change in oceanic variability associated with the climate shift of the mid-1970s, we analyze the contribution of momentum forcing to the leading baroclinic modes over the tropical Pacific using Simple Ocean Data Assimilation (SODA, version 2.0.2) for the period of 1958–1997. Specifically, we look at the statistical relationship between the wind projection coefficients and climate indices and attempt to provide a physical explanation for the observed changes. It is found that the wind stress projection coefficients according to the oceanic baroclinic modes are different in terms of their magnitude and phase in the tropical Pacific, reflecting a specific forcing associated with each mode before and after the 1976 climate shift. Compared to that before the 1970s, the first baroclinic mode is had a greater effect on the interannual sea surface temperature due to equatorial wave dynamics, and there was an increased delayed response of the second baroclinic mode variability to the interannual atmospheric forcing after the late 1970s. This reflects changes in ENSO feedback processes associated with the climate shift. Our analysis further indicates that, after the late 1970s, there was a decrease in the wind stress forcing projecting onto the Ekman layer, which is associated with increased mixed-layer depth. This result suggests that the changes in the ENSO properties before and after the late 1970s are largely associated with the changes in the way in which the wind stress forcing is dynamically projected onto the surface layer of the tropical Pacific Ocean over interannual timescales.     

Global changes in extreme events: regional and seasonal dimension

This study systematically analyzes the complete IPCC AR4 (CMIP3) ensemble of GCM simulations with respect to changes in extreme event characteristics at the end of the 21st century compared to present-day conditions. It complements previous studies by investigating a more comprehensive database and considering seasonal changes beside the annual time scale. Confirming previous studies, the agreement between the GCMs is generally high for temperature-related extremes, indicating increases of warm day occurrences and heatwave lengths, and decreases of cold extremes. However, we identify issues with the choice of indices used to quantify heatwave lengths, which do overall not affect the sign of the changes, but strongly impact the magnitude and patterns of projected changes in heatwave characteristics. Projected changes in precipitation and dryness extremes are more ambiguous than those in temperature extremes, despite some robust features, such as increasing dryness over the Mediterranean and increasing heavy precipitation over the Northern high latitudes. We also find that the assessment of projected changes in dryness depends on the index choice, and that models show less agreement regarding changes in soil moisture than in the commonly used ‘consecutive dry days’ index, which is based on precipitation data only. Finally an analysis of the scaling of changes of extreme temperature quantiles with global, regional and seasonal warming shows that much of the extreme quantile changes are due to a seasonal scaling of the regional annual-mean warming. This emphasizes the importance of the seasonal time scale also for extremes. Changes in extreme quantiles of temperature on land scale with changes in global annual mean temperature by a factor of more than 2 in some regions and seasons, implying large changes in extremes in several countries, even for the commonly discussed global 2°C-warming target.     

The STAGES view of red spirals and dusty red galaxies: mass-dependent quenching of star formation in cluster infall

We investigate the properties of optically passive spirals and dusty red galaxies in the A901/2 cluster complex at redshift ∼0.17 using rest-frame near-ultraviolet–optical spectral energy distributions, 24-μm infrared data and Hubble Space Telescope morphologies from the STAGES data set. The cluster sample is based on COMBO-17 redshifts with an rms precision of  σ _cz ≈ 2000 km s⁻¹  . We find that 'dusty red galaxies' and 'optically passive spirals' in A901/2 are largely the same phenomenon, and that they form stars at a substantial rate, which is only four times lower than that in blue spirals at fixed mass. This star formation is more obscured than in blue galaxies and its optical signatures are weak. They appear predominantly in the stellar mass range of  log  M _*/M_⊙=[10, 11]  where they constitute over half of the star-forming galaxies in the cluster; they are thus a vital ingredient for understanding the overall picture of star formation quenching in clusters. We find that the mean specific star formation rate (SFR) of star-forming galaxies in the cluster is clearly lower than in the field, in contrast to the specific SFR properties of blue galaxies alone, which appear similar in cluster and field. Such a rich red spiral population is best explained if quenching is a slow process and morphological transformation is delayed even more. At  log  M _*/M_⊙ < 10  , such galaxies are rare, suggesting that their quenching is fast and accompanied by morphological change. We note that edge-on spirals play a minor role; despite being dust reddened they form only a small fraction of spirals independent of environment.     

Thermodynamic functions of eskolaite Cr<Subscript>2</Subscript>O<Subscript>3</Subscript>(c) at 0–1800 K

The heat capacity of eskolaite Cr₂O₃(c) was determined by adiabatic vacuum calorimetry at 11.99–355.83 K and by differential calorimetry at 320–480 K. Experimental data of the authors and data compiled from the literature were applied to calculate the heat capacity, entropy, and the enthalpy change of Cr₂O₃ within the temperature range of 0–1800 K. These functions have the following values at 298.15 K: C _p ⁰ (298.15) = 121.5 ± 0.2 J K⁻¹mol⁻¹, S ⁰(298.15) = 80.95 ± 0.14 J K⁻¹mol⁻¹, and H ⁰(298.15)-H ⁰(0) = 15.30±0.02 kJ mol⁻¹. Data were obtained on the transitions from the antiferromagnetic to paramagnetic states at 228–457 K; it was determined that this transition has the following parameters: Neel temperature T _N = 307 K, Δ _tr S = 6.11 ± 0.12 J K⁻¹mol⁻¹ and δ _tr H = 1.87 ± 0.04 kJ mol⁻¹.     

Quantification of adamantane in organic media via infrared attenuated total reflection spectroscopy

In the present study, the quantitative determination of the diamondoid compound adamantane in organic solvents via infrared attenuated total reflection (IR-ATR) spectroscopy at unmodified waveguide surfaces was established. Limits of detection (LOD) and quantification (LOQ) of adamantane in dichloromethane, hexane and carbon tetrachloride were determined. Quantitative IR-ATR measurements additionally facilitated the determination of adamantane solubility limit in dichloromethane, hexane and carbon tetrachloride. The developed analytical strategy further enabled the successful detection and quantification of adamantane in crude oil matrices. Consequently, IR-ATR spectroscopy provides a promising strategy for on ship and in situ diamondoid analysis in harsh real world environments.     

Geodynamic evolution of crust accretion at the axis of the Reykjanes Ridge,Atlantic Ocean

The results of analysis of the anomalous magnetic field of the Reykjanes Ridge and the adjacent basins are presented, including a new series of detailed reconstructions for magnetic anomalies 1–6 in combination with a summary of the previous geological and geophysical investigations. We furnish evidence for three stages of evolution of the Reykjanes Ridge, each characterized by a special regime of crustal accretion related to the effect of the Iceland hotspot. The time interval of each stage and the causes of the variation in the accretion regime are considered. During the first, Eocene stage (54–40 Ma) and the third, Miocene-Holocene stage (24 Ma-present time at the northern Reykjanes Ridge north of 59° N and 17–11 Ma-present time at the southern Reykjanes Ridge south of 59° N), the spreading axis of the Reykjanes Ridge resembled the present-day configuration, without segmentation, with oblique orientation relative to the direction of ocean floor opening (at the third stage), and directed toward the hotspot. These attributes are consistent with a model that assumes asthenospheric flow from the hotspot toward the ridge axis. Decompression beneath the spreading axis facilitates this flow. Thus, the crustal accretion during the first and the third stages was markedly affected by interaction of the spreading axis with the hotspot. During the second, late Eocene-Oligocene to early Miocene stage (40–24 Ma at the northern Reykjanes Ridge and 40 to 17–11 Ma at the southern Reykjanes Ridge), the ridge axis was broken by numerous transform fracture zones and nontransform offsets into segments 30–80 km long, which were oriented orthogonal to the direction of ocean floor opening, as is typical of many slow-spreading ridges. The plate-tectonic reconstructions of the oceanic floor accommodating magnetic anomalies of the second stage testify to recurrent rearrangements of the ridge axis geometry related to changing kinematics of the adjacent plates. The obvious contrast in the mode of crustal accretion during the second stage in comparison with the first and the third stages is interpreted as evidence for the decreasing effect of the Iceland hotspot on the Reykjanes Ridge, or the complete cessation of this effect. The detailed geochronology of magnetic anomalies 1–6 (from 20 Ma to present) has allowed us to depict with a high accuracy the isochrons of the oceanic bottom spaced at 1 Ma. The variable effect of the hotspot on the accretion of oceanic crust along the axes of the Reykjanes Ridge and the Kolbeinsey and Mid-Atlantic ridges adjoining the former in the north and the south was estimated from the changing obliquity of spreading. The spreading rate tends to increase with reinforcing of the effect of the Iceland hotspot on the Reykjanes Ridge.     

The dark matter environment of the Abell 901/902 supercluster: a weak lensing analysis of the HST STAGES survey

We present a high-resolution dark matter reconstruction of the   z = 0.165  Abell 901/902 supercluster from a weak lensing analysis of the Hubble Space Telescope STAGES survey. We detect the four main structures of the supercluster at high significance, resolving substructure within and between the clusters. We find that the distribution of dark matter is well traced by the cluster galaxies, with the brightest cluster galaxies marking out the strongest peaks in the dark matter distribution. We also find a significant extension of the dark matter distribution of Abell 901a in the direction of an infalling X-ray group Abell 901α. We present mass, mass-to-light and mass-to-stellar mass ratio measurements of the structures and substructures that we detect. We find no evidence for variation of the mass-to-light and mass-to-stellar mass ratio between the different clusters. We compare our space-based lensing analysis with an earlier ground-based lensing analysis of the supercluster to demonstrate the importance of space-based imaging for future weak lensing dark matter 'observations'.     

A concerted research effort to advance the hydrological understanding of tropical páramos

Páramos, a neotropical alpine grassland-peatland biome of the northern Andes and Central America, play an essential role in regional and global cycles of water, carbon, and nutrients. They act as water towers, delivering water and ecosystem services from the high mountains down to the Pacific, Caribbean, and Amazon regions. Páramos are also widely recognized as a biodiversity and climate change hot spots, yet they are threatened by anthropogenic activities and environmental changes. Despite their importance for water security and carbon storage, and their vulnerability to human activities, only three decades ago, páramos were severely understudied. Increasing awareness of the need for hydrological evidence to guide sustainable management of páramos prompted action for generating data and for filling long-standing knowledge gaps. This has led to a remarkably successful increase in scientific knowledge, induced by a strong interaction between the scientific, policy, and (local) management communities. A combination of well-established and innovative approaches has been applied to data collection, processing, and analysis. In this review, we provide a short overview of the historical development of research and state of knowledge of the hydrometeorology, flux dynamics, anthropogenic impacts, and the influence of extreme events in páramos. We then present emerging technologies for hydrology and water resources research and management applied to páramos. We discuss how converging science and policy efforts have leveraged traditional and new observational techniques to generate an evidence base that can support the sustainable management of páramos. We conclude that this co-evolution of science and policy was able to successfully cover different spatial and temporal scales. Lastly, we outline future research directions to showcase how sustainable long-term data collection can foster the responsible conservation of páramos water towers.     

Complex scientific and technical trends of Russian Federation Arctic offshore hydrocarbon resource development

Based on the analysis of geological, technical and hydrometeorological conditions of the coastal part of the Arctic offshore, a concept of its hydrocarbon resource development is submitted.     

Effects of fracture intersections on seismic dispersion: theoretical predictions versus numerical simulations

The detection and characterisation of domains of intersecting fractures are important goals in several disciplines of current interest, including exploration and production of unconventional reservoirs, nuclear waste storage, CO₂ sequestration, and groundwater hydrology, among others. The objective of this study is to propose a theoretical framework for quantifying the effects of fracture intersections on the frequency‐dependent elastic properties of fluid‐saturated porous and fractured rocks. Three characteristic frequency regimes for fluid pressure communication are identified. In the low‐frequency limit, fractures are in full pressure communication with the embedding porous matrix and with other fractures. Conversely, in the high‐frequency limit, fractures are hydraulically isolated from the matrix and from other fractures. At intermediate frequencies, fractures are hydraulically isolated from the matrix porosity but can be in hydraulic communication with each other, depending on whether fracture sets are intersecting. For each frequency regime, the effective stiffness coefficients are derived using the linear‐slip theory and anisotropic Gassmann equations. Explicit mathematical expressions for the two characteristic frequencies that separate the three frequency regimes are also determined. Theoretical predictions are then applied to two synthetic 2D samples, each containing two orthogonal fracture sets: one with and another without intersections. The resulting stiffness coefficients, Thomsen‐style anisotropy parameters, and the transition frequencies show good agreement with corresponding numerical simulations. The theoretical results are applicable not only to 2D but also to 3D fracture systems and are amenable to being employed in inversion schemes designed to characterise fracture systems.