The July–August 2001 eruption of Mt. Etna (Sicily)

The July–August 2001 eruption of Mt. Etna stimulated widespread public and media interest, caused significant damage to tourist facilities, and for several days threatened the town of Nicolosi on the S flank of the volcano. Seven eruptive fissures were active, five on the S flank between 3,050 and 2,100 m altitude, and two on the NE flank between 3,080 and 2,600 m elevation. All produced lava flows over various periods during the eruption, the most voluminous of which reached a length of 6.9 km. Mineralogically, the 2001 lavas fall into two distinct groups, indicating that magma was supplied through two different and largely independent pathways, one extending laterally from the central conduit system through radial fissures, the other being a vertically ascending eccentric dike. Furthermore, one of the eccentric vents, at 2,570 m elevation, was the site of vigorous phreatomagmatic activity as the dike cut through a shallow aquifer, during both the initial and closing stages of the eruption. For 6 days the magma column feeding this vent was more or less effectively sealed from the aquifer, permitting powerful explosive and effusive magmatic activity. While the eruption was characterized by a highly dynamic evolution, complex interactions between some of the eruptive fissures, and changing eruptive styles, its total volume (~25×10 ⁶ m ³ of lava and 5–10×10 ⁶ m ³ of pyroclastics) was relatively small in comparison with other recent eruptions of Etna. Effusion rates were calculated on a daily basis and reached peaks of 14–16 m ³ s ^-1, while the average effusion rate at all fissures was about 11 m ³ s ^-1, which is not exceptionally high. The eruption showed a number of peculiar features, but none of these (except the contemporaneous lateral and eccentric activity) represented a significant deviation from Etna's eruptive behavior in the long term. However, the 2001 eruption could be but the first in a series of flank eruptions, some of which might be more voluminous and hazardous. Placed in a long-term context, the eruption confirms a distinct trend, initiated during the past 50 years, toward higher production rates and more frequent eruptions, which might bring Etna back to similar levels of activity as during the early to mid seventeenth century.     

Dynamics of intrathermocline vortices in a gyre flow over a seamount chain

The interaction of meddies with a complex distribution of seamounts is studied in a three-layer quasi-geostrophic model on the f-plane. This study aims at understanding if and how this seamount chain can represent a barrier to the propagation of these eddies and how it can be involved in their decay. The eddies are idealized as vortex patches in the middle layer, interacting with a regional cyclonic current and with ten idealized seamounts. The numerical code is based on the contour surgery technique. The initial position, radius, shape, number and polarity of the eddies are varied. The main results are the following: (1) Though they do not describe the unsteady flow, the streamlines of the regional and topographic flow provide a useful estimate of the vortex trajectories, in particular towards the major seamounts, where stronger velocity shears are expected. (2) The tallest and widest seamounts which have the largest vorticity reservoir are able to considerably erode the vortices, but also to draw anticyclones towards the seamount top. The ability of narrower seamounts to erode vortices is related to their multiplicity. (3) Only 1/3 of the anticyclones with about 30-km radius reach the southern boundary of the seamount chain, and their erosion is larger than 50 %. The other anticyclones are either completely eroded or trapped over a wide seamount top. Cyclones are less affected by seamounts because they oppose the topographic draft towards the seamount top and they drift along the side of the seamount. (4) Large vortices resist topographic erosion more efficiently. The rate of erosion grows from a few percent to about 35–50 % as the vortex radius decreases from about 60 to 30 km. Small cyclones are not eroded, contrary to small anticyclones (which completely decay), in relation with the different trajectories of these eddies in the vicinity of the seamounts. (5) The detailed vortex shape does not appear critical for their evolution, if they are close enough to the seamount chain initially. The interaction between a group of vortices initially north of the seamount chain can modify their trajectory to such an extent that they finally avoid collision with seamounts. (6) Finally, meddy trajectories across the Horseshoe Seamounts (data from the AMUSE experiment) show qualitative similarity with the vortex paths in the model. Several events of vortex decay also occur at comparable locations (in particular over the wide and tall seamounts) in the model and observations.     

Low‐frequency modulation and trend of the relationship between ENSO and precipitation along the northern to centre Peruvian Pacific coast

The relationship between El Niño Southern Oscillation (ENSO) and precipitation along the Peruvian Pacific coast is investigated over 1964–2011 on the basis of a variety of indices accounting for the different types of El Niño events and atmospheric and oceanographic manifestations of the interannual variability in the tropical Pacific. We show the existence of fluctuations in the ENSO/precipitation relationship at decadal timescales that are associated with the ENSO property changes over the recent decades. Several indices are considered in order to discriminate the influence of the two types of El Niño, namely, the eastern Pacific El Niño and the central Pacific El Niño, as well as the influence of large‐scale atmospheric variability associated to the Madden and Julian Oscillation, and of regional oceanic conditions. Three main periods are identified that correspond to the interleave periods between the main climatic transitions over 1964–2011, i.e. the shifts of the 1970s and the 2000s, over which ENSO experiences significant changes in its characteristics. We show that the relationship between ENSO and precipitation along the western coast of Peru has experienced significant decadal change. Whereas El Niño events before 2000 lead to increased precipitation, in the 2000s, ENSO is associated to drier conditions. This is due to the change in the main ENSO pattern after 2000 that is associated to cooler oceanic conditions off Peru during warm events (i.e. central Pacific El Niño). Our analysis also indicates that the two extreme El Niño events of 1982/1983 and 1997/1998 have overshadowed actual trends in the relationship between interannual variability in the tropical Pacific and precipitation along the coast of Peru. Overall, our study stresses on the complexity of the hydrological cycle on the western side of the Andes with regard to its relationship with the interannual to decadal variability in the tropical Pacific. Copyright © 2014 John Wiley & Sons, Ltd.     

Mercury pollution in sediments,benthic organisms and inshore fishes of Haifa Bay,Israel

Total mercury concentrations were determined in surficial sediments, eleven species of benthic organisms and six species of fish from Haifa Bay, Israel. The results show that essentially all of the shallow water zone of the Bay receives anthropogenic mercury. A mercury-cell chlor-alkali plant was identified as the source of pollution. Surficial sediments in the vicinity of the plant, containing up to 0·99 μg Hg/g dry weight, were up to 157 times enriched in mercury relative to an unpolluted area. Mercury levels in the benthic organisms reflected the levels in the sediments. Maximal concentrations reaching 38·7 and 18·2 μg Hg/g dry weight were found in the carnivorous gastropod molluscs Arcularia circumcinta and Arcularia gibbosula, respectively. In all fish species, specimens caught in Haifa Bay had higher mercury concentrations in the muscle tissue than specimens caught south of the Bay. A maximal value of 1·66 μg Hg/g wet weight was recorded in Diplodus sargus.     

Hyperspectral core logging for fire reconstruction studies

Lacustrine sediments contain a wide range of proxies that enable paleoenvironmental reconstructions. For instance, charcoal can be used to document past fire regime changes. In order to analyse high-temporal- and spatial-resolution records, however, it is necessary to develop fast, low-cost and high-stratigraphic-resolution methods. We developed a new paleo-fire proxy by studying a lacustrine core from the Esterel Massif, SE France, an area affected by two recent fire events, in AD 1987 and 2003. For this purpose, we searched for charcoal deposited and preserved in the lake sediments by combining a number of complementary methods, including: classic macrocharcoal tallying, scanning spectrophotometry, scanning hyperspectral imaging and high pressure liquid chromatography analyses. Macrocharcoal quantification is efficient, but time-consuming, and only provides intermediate-resolution data (cm scale). Spectrophotometry, used classically to quantify colour, is very fast, provides high-resolution data (4 mm) and is non-destructive (core preservation). Hyperspectral data have the same advantages as spectrophotometry, but offer higher spatial resolution (64-µm pixel size) and higher spectral resolution (6 nm) for core logging applications. The main result of this research is based on hyperspectral analysis at very high stratigraphic resolution using the I-band index. This index usually measures reflectance values at [660, 670 nm] corresponding to the trough in red reflectance produced by Chlorophyll a and its diagenetic products. This [660, 670 nm] reflectance trough, however, is also affected by the presence of altered organic matter and decreases with altered organic matter such as charcoal particles. Charcoal effect on the reflectance of Chlorophyll a and its diagenetic products is identified on first derivative spectra by a characteristic pattern around 675 nm, which is also in agreement with the Chlorophyll a concentrations measured by high-pressure liquid chromatography and charcoal particles. The I-band index is hence suitable for detecting burned organic matter, by quantifying the dilution of the chlorophyll signal by the charcoal signal. Thus, this adaptation of the I-band index can be applied in fire reconstruction studies.     

Vibrational states of H<Subscript>2</Subscript>O in beryl: physical aspects

Single-crystal polarized Raman spectra (3,000–4,000 cm⁻¹ at 3 ≤ T ≤ 300 K) were measured for synthetic alkali-free and natural beryl, Be₂Al₃Si₆O₁₈·xH₂O, to determine the behavior of H₂O molecules of both Type I and Type II in the cavities. At low temperature, the H₂O molecules of Type I displace from the center of cavity and give rise to very weak hydrogen bonding with the host lattice. The H₂O Type I translational motion is characterized by substantial anharmonicity and looks like a motion of “a particle in the box” with a frequency of 6.3 cm⁻¹. Water Type II is characterized by a free rotation with respect to the C ₂ molecule axis, and it makes possible the water nuclear isomers (i.e. ortho- and para-) to be observed at low temperature.