Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.     

Color of the Corona Continuum of July 11, 1991

Geomagnetism and Aeronomy - The color of the coronal continuum was determined from observations in order to search for manifestations of coronal expansion. A brief review of studies determining the...     

Petrography and geochemistry of manganiferous rocks in the Mankwadzi area in the southern Kibi‐Winneba metavolcanic belt,Ghana: Implications for genesis of Mn formations in the Birimian of West Africa

Manganiferous rocks in the Mankwadzi area in the southernmost portion of the Kibi‐Winneba metavolcanic belt, one of several Mn occurrences in the Paleoproterozoic Birimian of Ghana, are hosted in hornblende schist and amphibolite. These rocks are, in places, intruded by hornblende dyke. In outcrop, the manganiferous rocks appear to be conformable with the host schist and amphibolite, are macroscopically dark, fine‐grained and structurally massive to distinctly banded. Observed alternating light and dark occasionally macro‐folded bands suggest post‐depositional deformation of both light and dark bands. Microscopic observations revealed that the light bands are dominantly Si‐rich and the dark bands mainly of opaque minerals. Whole rock analyses of the manganiferous rocks show high contents of MnO (16.75–27.4 wt%) suggesting that the opaque minerals are likely rich in Mn. The analyzed rock samples show moderate to strong enrichments in light rare earth elements compared to heavy rare earth elements. Whereas the manganiferous rocks show perceptibly negative Eu anomaly, host hornblende schist and hornblende dyke do not. Eu anomaly in amphibolite samples is, however, uncertain as the three samples analyzed gave positive, negative and no Eu anomalies. Based on the field characteristics, microscopic and geochemical features, we suggest that the Mn occurrence in the Mankwadzi area originated via sedimentary deposition and was later modified by metamorphism, hydrothermal and/or supergene processes similar to manganiferous occurrences at Nsuta and Tambao in the Birimian of West Africa.     

The earliest stage of Izu rear‐arc volcanism revealed by drilling at Site U1437, International Ocean Discovery Program Expedition 350

The International Ocean Discovery Program Expedition 350 drilled between two Izu rear‐arc seamount chains at Site U1437 and recovered the first complete succession of rear‐arc rocks. The drilling reached 1806.5 m below seafloor. In situ hyaloclastites, which had erupted before the rear‐arc seamounts came into existence at this site, were recovered in the deepest part of the hole (～15–16 Ma). Here it is found that the composition of the oldest rocks recovered does not have rear‐arc seamount chain geochemical signatures, but instead shows affinities with volcanic front or some of the extensional zone basalts between the present volcanic front and the rear‐arc seamount chains. It is suggested that following the opening of the Shikoku back‐arc Basin, Site U1437 was a volcanic front or a rifting zone just behind the volcanic front, and was followed at ~ 9 Ma by the start of rear‐arc seamount chains volcanism. This geochemical change records variations in the subduction components with time, which might have followed eastward moving of hot fingers in the mantle wedge and deepening of the subducting slab below Site U1437 after the cessation of Shikoku back‐arc Basin opening.     

Signature of differential rotation in solar disk‐integrated chromospheric line emission

UARS SOLSTICE data have been subjected to Fourier and wavelet analyses in order to search for the signature of the solar rotation law in the disk‐integrated irradiance of UV lines. Lyman‐α, Mg II, and Ca II data show a different behaviour. In the SOLSTICE data there are significant temporal variations of the rotation rate of the UV tracers over 5—6 years. Often several distinct rotation periods appear almost simultaneously. Beside the basic period around 27 days there are signals at 32—35 days corresponding to the rotation rate at very high latitudes. For more than 5 years during another period of the solar cycle the rotational behaviour is quite different; there is an indication of differential rotation of active regions in these Ca II ground‐based data. The data contain a wealth of information about the solar differential rotation, but it proves difficult to disentangle the effects of the different emitting sources.     

On stellar encounters and their effect on cometary orbits in the Oort cloud

We systematically investigate the encounters between the Sun and neighbouring stars and their effects on cometary orbits in the Oort cloud, including the intrinsic one with the star Gl 710 (HIP 89 825), with some implications to stellar and cometary dynamics. Our approach is principally based on the combination of a Keplerian‐rectilinear model of stellar passages and the Hipparcos Catalogue (ESA 1997). Beyond the parameters of encounter, we pay particular attention to the observational errors in parallaxes and stellar velocities, and their propagation in time. Moreover, as a special case of this problem, we consider the collision probability of a star passing very closely to the Sun, taking also into account the mutual gravitational attraction between the stars. In the part dealing with the influence of stellar encounters on the orbital elements of Oort cloud comets, we derive new simple formulae calculating the changes in the cometary orbital elements, expressed as functions of the Jeans impulse formula. These expressions are then applied to calculate numerical values of the element changes caused by close encounters of neighbouring stars with some model comets in the Oort cloud. Moreover, the general condition for an ejection of comets from the cloud effected by a single encounter is derived and discussed.     

Field investigation of siltation at a tidal harbor: North Port of Incheon,Korea

Ocean Dynamics - To understand siltation processes within the North Port of Incheon, Korea, this study estimated the sedimentation rate and then determined the dominant mechanisms for the...     

Analysis of Stock Market Development and CO2 Emissions on OECD Countries via an Empirical Model

Accompanying economic growth, CO₂ emissions have polluted the natural environment worldwide. This study highlights the special problems with stock market development and CO₂ emissions in 25 Organization for Economic Cooperation and Development (OECD) countries during 1971–2007 to trace the trend of CO₂ emissions while countries grow their economies. A panel‐data model is applied to analyze the relationships between stock market (SM) development, energy consumption, gross domestic product (GDP), and CO₂ emissions in 25 OECD countries. Low‐GDP countries show different results from high‐GDP countries in the trends of SM development and CO₂ emissions, and dynamic effects occur in SM development and CO₂ emissions under various GDP conditions. There is a negative relationship between SM development and CO₂ emissions if countries enjoy high economic growth, which means that these countries avoid CO₂ emissions through SM development. However, a positive relationship is found between SM development and CO₂ emissions if countries experience low economic growth, which means that SM development does not show the boycott‐effect relationship with CO₂ emissions when countries experience low levels of economic development. This study shows a correlation between SM development and CO₂ emissions among OECD countries.