Determining accurate temperature-time paths from U-Pb thermochronology: An example from the Kaapvaal craton, southern Africa

Thermochronology has revolutionized our understanding of the establishment and evolution of lithospheric thermal structure. However, many potential benefits provided by the application of diffusion theory to thermochronology have yet to be fully exploited. This study uses apatite (T_c = 450-550 °C) and titanite (T_c = 550-650 °C) U-Pb ID-TIMS thermochronology at the single- to sub-grain scale to separate the variable effects of volume diffusion of Pb from metamorphic (over)growth above and below the T_c of a mineral. Data are presented from two ca. 3227 Ma tonalite samples from north and south of the Barberton Greenstone Belt (BGB), southern Africa. Two distinct populations of apatite from a sample north of the BGB record fast cooling followed by metamorphic growth ∼10 Myr later. Both apatite and titanite dates from south of the BGB show a strong correlation with the grain size and record 100 Myr of post-emplacement cooling. Complex core-rim zoning observed in cathodoluminescence images of apatite is interpreted to reflect metamorphic overgrowth above the T_c. The age and topology of grain size versus date curves from titanite and apatite are used in combination with a finite-difference numerical model to show that slow, non-linear, cooling and not thermal resetting is responsible for the observed distribution. The thermal histories from either side of the BGB are very different and provide unique insight into the BGB’s tectonic evolution: a ∼70 Myr period of apparent stability after ca. 3.2 Ga terrane assembly was followed by fast exhumation south of the BGB that led to lower-crustal melting and intrusion of granitic batholiths ca. 3.14-3.10 Ga.     

Calcium isotope fractionation in coccoliths of cultured Calcidiscus leptoporus, Helicosphaera carteri, Syracosphaera pulchra and Umbilicosphaera foliosa

Four species of marine calcifying algae, the coccolithophores Calcidiscus leptoporus, Helicosphaera carteri, Syracosphaera pulchra and Umbilicosphaera foliosa were grown in laboratory cultures under temperatures varying between 14 and 23 °C, and one species, C. leptoporus, under varying [CO₃²⁻], ranging from 105 to 219 μmol/kg. Calcium isotope compositions of the coccoliths resemble in both absolute fractionation and temperature sensitivity previous calibrations of marine calcifying species e.g. Emiliania huxleyi (coccolithophores) and Orbulina universa (planktonic foraminifera) as well as inorganically precipitated CaCO₃, but also reveal small species specific differences. In contrast to inorganically precipitated calcite, but similar to E. huxleyi and O. universa, the carbonate ion concentration of the medium has no statistically significant influence on the Ca isotope fractionation of C. leptoporus coccoliths; however, combined data of E. huxleyi and C. leptoporus indicate that the observed trends might be related to changes of the calcite saturation state of the medium. Since coccoliths constitute a significant portion of the global oceanic CaCO₃ export production, the Ca isotope fractionation in these biogenic structures is important for defining the isotopic composition of the Ca sink of the ocean, one of the key parameters for modelling changes to the marine Ca budget over time. For the present ocean our results are in general agreement with the previously postulated and applied mean value of the oceanic Ca sink (Δ_sed) of about − 1.3‰, but the observed inter- and intra-species differences point to possible changes in Δ_sed through earth history, due to changing physico-chemical conditions of the ocean and shifts in floral and faunal assemblages.     

Light curves of SN 1998A and comparison with similar unusual SNe

Following the proposal by Damineli that the central object of Eta Carinae may be an early-type binary, we perform numerical simulations of the X-ray emission from colliding stellar winds. A synthetic light curve has been generated which qualitatively agrees with the recent X-ray variability, and provides further support for the binary model. In particular, the model predicts a rise in the observed X-ray emission towards periastron, followed by a sharp drop and subsequent recovery. This is indeed what is seen in the RXTE light curve, although some problems concerning the X-ray spectrum at periastron still need to be explained. The simulations suggest that the width of the periastron dip will provide strong constraints on the binary and stellar wind properties of the components of Eta Car.     

The radioracemization of isovaline. Cosmochemical implications

The optically pure d- and l-enantiomers of isovaline (I), which cannot be racemized by ordinary chemical mechanisms involving α-hydrogen removal, and which has been isolated in apparently racemic form from the Murchison meteorite, have been subjected to partial radiolysis by the ionizing radiation from a 3000 Ci ⁶⁰Co γ-ray source. Both in the anhydrous and hydrated solid states and as solid sodium or hydrochloride salts each enantiomer suffered significant radioracemization of the undestroyed residue during its partial radiolysis. The sodium salt of isovaline in 0.1 M aqueous solution suffered extensive radiolysis with relatively small radiation doses, but showed no detectable radioracemization. The significance of these observations with respect to the primordial enantiomeric composition of the isovaline (and other amino acids) indigenous to meteroties is discussed.     

Estimating Sea-Level Allowances for Atlantic Canada using the Fifth Assessment Report of the IPCC

Abstract

Sea-level allowances at 22 tide-gauge sites along the east coast of Canada are determined based on projections of regional sea-level rise for the Representative Concentration Pathway 8.5 (RCP8.5) from the Fifth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC AR5) and on the statistics of historical tides and storm surges (storm tides). The allowances, which may be used for coastal infrastructure planning, increase with time during the twenty-first century through a combination of mean sea-level rise and the increased uncertainty of future projections with time. The allowances show significant spatial variation, mainly a consequence of strong regionally varying relative sea-level change as a result of glacial isostatic adjustment (GIA). A methodology is described for replacement of the GIA component of the AR5 projection with global positioning system (GPS) measurements of vertical crustal motion; this significantly decreases allowances in regions where the uncertainty of the GIA models is large. For RCP8.5 with GPS data incorporated and for the 1995–2100 period, the sea-level allowances range from about 0.5?m along the north shore of the Gulf of St. Lawrence to more than 1?m along the coast of Nova Scotia and southern Newfoundland.     

Blast vibration control in the presence of delay scatter and random fluctuations between blastholes

It is becoming increasingly important, from an environmental viewpoint, to minimize vibrations induced in urban dwellings by blasting. The present study illustrates how the delay interval between blastholes can be chosen to control and minimize the vibration energy within the structural response band of most houses. In particular, it is shown that the only possibility of reducing such energy is to employ a delay interval in the range 10–35 ms. However, the induced vibrations are also dependent upon the accuracy of the delay initiators as well as the level of random fluctuations between each blasthole signature. It is shown that only very accurate electronic delays give the possibility of utilizing fully the delay sequence in order to control structural vibrations. If the vibration emission from each blasthole is totally uncorrelated with that of any other blasthole then the resulting amplitude spectrum of the blast will be totally unpredictable. This situation occurs irrespective of the delay initiation sequence or its accuracy. Under these conditions it is impossible to predict the blast-induced energy lying within the structural response band.     

Towards a theory of targeting

A representative economic model is used to analyze local policies to reestablish full employment. It addresses three types of barriers: 1. Rigid wages, 2. Occupational (or industrial) immobility, and 3. Geographic immobility. These factors are considered in the framework of three types of policies: 1. Laissez-faire, 2. Narrowly targeted employment incentives, and 3. Broadly targeted incentives. The paper concludes that the usefulness of the abstract model will depends upon the ability of local development officials to combine the implications of the model with information about the local economic development narrative. In turn, the narrative depends upon an in-depth local knowledge of history, institutions, practices and personalities.     

Changes in Climate Extremes Over the Australian Region and New Zealand During the Twentieth Century

Analyses of high quality data show that there have been some interesting recent changes in the incidence of some climate extremes in the Australian region and New Zealand.     

Sedimentary processes and facies of the waterlaid Anvil Spring Canyon alluvial fan, Death Valley, California

The Anvil Spring Canyon fan of the Panamint Range piedmont in central Death Valley was built entirely by water-flow processes, as revealed by an analysis of widespread 2- to 12-m-high stratigraphic cuts spanning the 9·7 km radial length of this 2·5–5·0° sloping fan. Two facies deposited from fan sheetfloods dominate the fan from apex to toe. The main one (60–95% of cuts) consists of sandy, granular, fine to medium pebble gravel that regularly and sharply alternates with cobbly coarse to very coarse pebble gravel in planar couplets 5–25 cm thick oriented parallel to the fan surface. The other facies (0–25% of cuts) comprises 10- to 60-cm-thick, wedge-planar and wedge-trough beds of pebbly sand and sandy pebble gravel in backsets sloping 3–28°. Both facies are interpreted as resulting from rare, sediment-charged flash floods from the catchment, and were deposited by supercritical standing waves of expanding sheetfloods on the fan. Standing waves were repeatedly initiated, enlarged, migrated, and then terminated either by gradually rejoining the flood or by more violent breakage and washout. The frequent autocyclic growth and destruction of standing waves during an individual sheetflood resulted in the deposition of multiple coarse and fine couplet and backset sequences 50–250 cm thick across the active depositional lobe of the fan. Erosional intensity during washout of the standing wave determined whether early-phase backset-bed deposits or washout-phase sheetflood couplet deposits were selectively preserved in a given cycle. Two minor facies are also found in the Anvil fan. Pebble–cobble gravel lags (0–20% of cuts) are present above erosional scours into the sheetflood couplet and backset deposits. They consist of coarse gravel concentrated through fine-fraction winnowing of the host sheetflood facies by sediment-deficient water flows. This reworking occurred during recessional flood stage or from non-catastrophic discharge during the long intervals between major flash floods. This facies is common at the surface, giving rise to a ‘braided-stream’ appearance. However, it is stratigraphically limited, present as thin, continuous to discontinuous beds or lenses that bound 50- to 250-cm-thick sheetflood sequences. The other minor facies of the Anvil fan consists of clast-supported and imbricated, thickly stratified, pebbly, cobbly, boulder gravel present in narrow, radially aligned ribbons nested within sheetflood deposits. This facies is interpreted as representing deposition in the incised channel of the fan, a subenvironment characterized by greater flow competence resulting from maintained depth from channel-wall confinement, and by more frequent water flows and winnowing events caused by its direct connection with the catchment feeder channel.