Clustering current climate regions of Turkey by using a multivariate statistical method

In this study, the hierarchical clustering technique, called Ward method, was applied for grouping common features of air temperature series, precipitation total and relative humidity series of 244 stations in Turkey. Results of clustering exhibited the impact of physical geographical features of Turkey, such as topography, orography, land–sea distribution and the high Anatolian peninsula on the geographical variability. Based on the monthly series of nine climatological observations recorded for the period of 1970–2010, 12 and 14 clusters of climate zones are determined. However, from the comparative analyses, it is decided that 14 clusters represent the climate of Turkey more realistically. These clusters are named as (1) Dry Summer Subtropical Semihumid Coastal Aegean Region; (2) Dry-Subhumid Mid-Western Anatolia Region; (3 and 4) Dry Summer Subtropical Humid Coastal Mediterranean region [(3) West coast Mediterranean and (4) Eastern Mediterranean sub-regions]; (5) Semihumid Eastern Marmara Transition Sub-region; (6) Dry Summer Subtropical Semihumid/Semiarid Continental Mediterranean region; (7) Semihumid Cold Continental Eastern Anatolia region; (8) Dry-subhumid/Semiarid Continental Central Anatolia Region; (9 and 10) Mid-latitude Humid Temperate Coastal Black Sea Region [(9) West Coast Black Sea and (10) East Coast Black Sea sub-regions]; (11) Semihumid Western Marmara Transition Sub-region; (12) Semihumid Continental Central to Eastern Anatolia Sub-region; (13) Rainy Summer Semihumid Cold Continental Northeastern Anatolia Sub-region; and (14) Semihumid Continental Mediterranean to Eastern Anatolia Transition Sub-region. We believe that this study can be considered as a reference for the other climate-related researches of Turkey, and can be useful for the detection of Turkish climate regions, which are obtained by a long-term time course dataset having many meteorological variables.     

Variability of polar motion oscillations with periods from 20 to 150 days in 1979–1991

Variability of short period oscillations of polar motion with periods ranging from 20 to 150 days were investigated in the period 1979–1991. The new computation method of time variable band pass filter spectra and the Wavelet Transform method were applied. These oscillations are elliptical with variable amplitudes. Modulation periods of amplitude variations of these oscillations of about two and three years were found. Correlations of short period oscillations of polar motion and of effective atmospheric angular momentum (EAAM) excitation functions show annual variations and connections of their increases with El Niño phenomena.     

Variations of the geomagnetic field at the time of reversals

Summary Paleomagnetic investigations of sediments from the Early Quaternary enabled the variations of the geomagnetic field during reversals to be studied. Regularities in the motion of the virtual geomagnetic N paleopole and the related changes in the intensity of the geomagnetic field were determined. The initial phase of the reversal, which took place in the Eastern Hemisphere, is accompanied by an increase in the intensity of the geomagnetic field. A strong decrease occurred at the time the N paleopole was moving around30°N geographic latitude. After the irreversible reversal had been concluded, the intensity of the geomagnetic field stabilized at values corresponding to the field intensity prior to the reversal. The reversible reversal is accompanied by an repeated increase in the itensity of the geomagnetic field.

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Nature and onset age of neotectonic regime in the northern core of Isparta Angle,SW Turkey

The Isparta Angle (IA) is a reverse Λ-shaped morphotectonic structure located to the north of Antalya Gulf in the Eastern Mediterranean Sea. It resulted from the northward curvature of the originally E–W-trending Tauride orogenic belt owing to the nappe emplacements and related clockwise and anti-clockwise rotations in a time period of Early Paleocene to Early Pliocene. The IA is included in the southwest Anatolian tensional neotectonic domain and characterized by a series of grabens and horsts bounded by active normal faults of dissimilar length and trend. The evolutionary history of the graben-horst system is episodic. It is evidenced by two graben fills. These are older and modern (younger) graben fills separated by an intervening angular unconformity. The modern graben fill is nearly flat-lying (non-deformed) whereas older graben fill was deformed into a series of anticlines and synclines with ENE-trending curvi-linear axes by a short-term compressive tectonic regime operated in NNW–SSE direction during Late Pliocene. The diagnostic structures taking a part in the development of grabens and shaping the northern section of the IA are the margin-boundary normal faults. They occur in numerous single and several fault zones displaying a basin ward facing step-like land shape. Most of fault segments, particularly the master faults, are active and have a capacity of creating destructive earthquakes with a magnitude (up to Mw?=?7.0). This is evidenced by both the historical and instrumental period earthquakes. Both the focal mechanism solution of earthquakes and the stereographic plots of slip-plane data, measured on the active margin-boundary faults of various grabens comprising the IA, on the Schmidt lower hemisphere net obviously reveal that the IA is under the influence of the tensional neotectonic regime, not a compressive tectonic regime, i.e. the sinistral strike-slip shearing along the Pliny arc has not propagated yet onshore, and its commencement age is Early Quaternary.     

Hydrogeochemistry and environmental isotopes of ground water in Jeju volcanic island,Korea: implications for nitrate contamination

Ground water from springs and public supply wells was investigated for hydrochemistry and environmental isotopes of ³H, ¹⁸O and D in Jeju volcanic island, Korea. The wells are completed in a basaltic aquifer and the upper part of hydrovolcanic sedimentary formation. Nitrate contamination is conspicuous in the coastal area where most of the samples have nitrate concentrations well above 1 mg NO₃ N/l. Agricultural land use seems to have a strong influence on the distribution of nitrate in ground water. Comparison of stable isotopic compositions of precipitation and ground water show that ground water mostly originates from rainy season precipitation without significant secondary modification and that local recharge is dominant. ³H concentration of ground water ranged from nearly zero to 5 TU and is poorly correlated with vertical location of well screens. The occurrence of the ³H‐free, old ground water is due to the presence of low permeability layers near the boundary of the basaltic aquifer and the hydrovolcanic sedimentary formation, which significantly limits ground water flow from the upper basaltic aquifer. The old ground water exhibited background‐level nitrate concentrations despite high nitrate loadings, whereas young ground water had considerably higher nitrate concentrations. This correlation of ³H and nitrate concentration may be ascribed to the history of fertilizer use that has increased dramatically since the early 1960s in the island. This suggests that ³H can be used as a qualitative indicator for aquifer vulnerability to nitrate contamination. Copyright © 2005 John Wiley & Sons, Ltd.     

Multivariate statistical analysis of underground gas storage caverns on groundwater chemistry in Korea

An understanding of groundwater flow and chemistry is important to operate underground storage caverns. Groundwater flow is mainly affected by cavern operating conditions. Groundwater chemistry is modified by disinfection activities for removing possible biological clogging and by mixing with cement pore water. It is important to discern these two effects, because wells affected by the disinfection activities may have hydrological connections with water curtains used to inject the disinfectant. However, it is difficult to separate these two effects using graphical methods because of their similar chemical characteristics. Instead, multivariate statistical analysis, such as principal component analysis (PCA) and factor analysis (FA), can be used. Groundwater samples for chemical analysis were obtained from four surveys in 1999–2000. Based on the results from PCA and FA, it appears that there were temporal variations of seepage water into the propane area when the cavern operation fluctuated, but we could not observe such variation in the butane area. These changes may occur mainly at depth, where water flow is slow and water renewal in the cavern surrounding is limited. Copyright © 2008 John Wiley & Sons, Ltd.     

40Ar/39Ar hornblende dating of a microgranodiorite dyke: implications for early Permian extension in the Moldanubian Zone of the Bohemian Massif

Laser fusion ⁴⁰Ar/³⁹Ar ages of titanian pargasite from a microgranodiorite dyke swarm in the southern Bohemian Massif effectively date the early Permian (late Autunian) emplacement of dykes into a cool Moldanubian crust. This intrusion represents the youngest magmatic phase recorded in this part of the Moldanubian Zone. Strontium and neodymium isotopic ratios of microgranodiorites point to magma derivation from re-melting the lower crustal rocks with a possible component of upper mantle composition. Spatial and temporal association of the dykes with movements on a major N-S (NNE-SSW) tectonic discontinuity (Blanice-Kaplice-Rödl fault zone) suggests that their emplacement corresponds to the maximum age of fault movements associated with the E/W-oriented extension in this part of the Bohemian Massif.     

L’influence de certaines substances toxiques,contenues dans les eaux d’égouts municipaux,sur les bactériesEscherichia coli etPseudomonas fluorescens

The toxic influence of phenol, aniline, pyridine and chrome, substances often found in municipal wastewaters, on the bacteriaEscherichia coli andPseudomonas fluorescens was examined. The non-toxic, growth limiting, toxic and lethal doses were determined on the basis of observations made ofE. coli andP. fluorescens reproduction and respiration patterns. Comparative test series were set up with the various doses in different nutrient cultures to ascertain whether the bacterias’ multiplication process or carbohydrate decomposition was more sensitive to the chemicals.     

Secular evolution of the vertical column abundances of CHCIF2 (HCFC-22) in the Earth's atmosphere inferred from ground-based IR solar observations at the Jungfraujoch and at Kitt Peak,and comparison with model calculations

Series of high-resolution infrared solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, between 06/1986 and 11/1992, and at Kitt Peak National Observatory, Tucson, Arizona (U.S.A.), from 12/1980 to 04/1992, have been analyzed to provide a comprehensive ensemble of vertical column abundances of CHCIF₂ (HCFC-22; Freon-22) above the European and the North American continents. The columns were derived from nonlinear least-squares curve fittings between synthetic spectra and the observations containing the unresolved 2v ₆ Q-branch absorption of CHCIF₂ at 829.05 cm^–1. The changes versus time observed in these columns were modeled assuming both an exponential and a linear increase with time. The exponential rates of increase at one-sigma uncertainties were found equal to (7.0±0.35)%/yr for the Junfraujoch data and (7.0±0.23)%/yr for the Kitt Peak data. The exponential trend of 7.0%/yr found at both stations widely separated in location can be considered as representative of the global increase of the CHCIF₂ burden in the Earth's atmosphere during the period 1980 to 1992. When assuming two realistic vertical volume mixing ratio profiles for CHCIF₂ in the troposphere, one quasi constant and the other decreasing by about 13% from the ground to the tropopause, the concentrations for mid-1990 were found to lie between 97 and 111 pptv (parts per trillion by volume) at the 3.58 km altitude of the Jungfraujoch and between 97 and 103 pptv at Kitt Peak, 2.09 km above sea level. Corresponding values derived from calculations using a high vertical resolution-2D model and recently compiled HCFC-22 releases to the atmosphere, were equal to 107 and 105 pptv, respectively, in excellent agreement with the measurements. The model calculated lifetime of CHCIF₂ was found equal to 15.6 years. The present results are compared critically with similar data found in the literature. On average, the concentrations found here are lower by 15–20% than those derived from in situ investigations; this difference cannot be explained by the absolute uncertainty of ±11% assigned presently to the infrared remote measurements.     

Crystal-field spectra for blue and green diopsides synthesized in the join CaMgSi2O6-CaCrAlSiO6

Synthetic diopsides in the join CaMgSi₂O₆ CaCrAlSiO₆ have been studied by means of crystal-field theory. These diopsides are either blue or pale green in colour. The former forms at lower temperatures and the latter at higher temperatures. The optical spectra and colours can be unequivocally explained based on the assumption that Cr³⁺ions occupy both tetrahedral and octahedral sites in the diopsides. In the blue diopsides Cr³⁺ions are present in two kinds of spin state, i.e., tetrahedrally coordinated low spin and octahedrally coordinated high spin. On heating the blue diopsides, tetrahedral occupancy of chromium decreases sharply due to spin transformation from tetrahedral low spin to octahedral high spin. Above 1,160° C nearly all chromium ions are present in octahedral sites with high spin state and the diopsides become pale green in colour. Some petrogenetic applications of the resultes are discussed.