Assessing the Transport of Pharmaceutical Compounds in a Layered Aquifer Discharging to a Stream

A groundwater plume containing high concentrations of pharmaceutical compounds, mainly sulfonamides, barbiturates, and ethyl urethane, in addition to chlorinated ethenes and benzene was investigated. The contamination originating from a former pharmaceutical industry discharges into a multilayered aquifer system and a downgradient stream. In this study, geological and hydrogeological data were integrated into a numerical flow model to examine identified trends using statistical approaches, including principal component analysis and hierarchal cluster analysis. A joint interpretation of the groundwater flow paths and contaminant concentrations in the different compartments (i.e., groundwater and hyporheic zone) provided insight on the transport processes of the different contaminant plumes to the stream. The analysis of historical groundwater concentrations of pharmaceutical compounds at the site suggested these compounds are slowly degrading. The pharmaceutical compounds migrate in both a deep semiconfined aquifer, as well as in the shallow unconfined aquifer, and enter the stream along a 2-km stretch. This contrasted with the chlorinated ethenes, which mainly discharge to the stream as a focused plume from the unconfined aquifer. The integrated approach developed here, combining groundwater flow modeling and statistical analyses of the contaminant concentration data collected in groundwater and the hyporheic zone, lead to an improved understanding of the observed distribution of contaminants in the unconfined and semiconfined aquifers, and thus to their discharge to the stream. This approach is particularly relevant for large and long-lasting contaminant sources and plumes, such as abandoned landfills and industrial production sites, where field investigations may be very expensive.     

Retrieving virtual reflection responses at drill‐bit positions using seismic interferometry with drill‐bit noise

In the field of seismic interferometry, researchers have retrieved surface waves and body waves by cross‐correlating recordings of uncorrelated noise sources to extract useful subsurface information. The retrieved wavefields in most applications are between receivers. When the positions of the noise sources are known, inter‐source interferometry can be applied to retrieve the wavefields between sources, thus turning sources into virtual receivers. Previous applications of this form of interferometry assume impulsive point sources or transient sources with similar signatures. We investigate the requirements of applying inter‐source seismic interferometry using non‐transient noise sources with known positions to retrieve reflection responses at those positions and show the results using synthetic drilling noise as source. We show that, if pilot signals (estimates of the drill‐bit signals) are not available, it is required that the drill‐bit signals are the same and that the phases of the virtual reflections at drill‐bit positions can be retrieved by deconvolution interferometry or by cross‐coherence interferometry. Further, for this case, classic interferometry by cross‐correlation can be used if the source power spectrum can be estimated. If pilot signals are available, virtual reflection responses can be obtained by first using standard seismic‐while‐drilling processing techniques such as pilot cross‐correlation and pilot deconvolution to remove the drill‐bit signatures in the data and then applying cross‐correlation interferometry. Therefore, provided that pilot signals are reliable, drill‐bit data can be redatumed from surface to borehole depths using this inter‐source interferometry approach without any velocity information of the medium, and we show that a well‐positioned image below the borehole can be obtained using interferometrically redatumed reflection responses with just a simple velocity model. We discuss some of the practical hurdles that restrict the application of the proposed method offshore.     

Modeling the Factors Impacting Pesticide Concentrations in Groundwater Wells

This study examines the effect of pumping, hydrogeology, and pesticide characteristics on pesticide concentrations in production wells using a reactive transport model in two conceptual hydrogeologic systems; a layered aquifer with and without a stream present. The pumping rate can significantly affect the pesticide breakthrough time and maximum concentration at the well. The effect of the pumping rate on the pesticide concentration depends on the hydrogeology of the aquifer; in a layered aquifer, a high pumping rate resulted in a considerably different breakthrough than a low pumping rate, while in an aquifer with a stream the effect of the pumping rate was insignificant. Pesticide application history and properties have also a great impact on the effect of the pumping rate on the concentration at the well. The findings of the study show that variable pumping rates can generate temporal variability in the concentration at the well, which helps understanding the results of groundwater monitoring programs. The results are used to provide guidance on the design of pumping and regulatory changes for the long‐term supply of safe groundwater. The fate of selected pesticides is examined, for example, if the application of bentazone in a region with a layered aquifer stops today, the concentration at the well can continue to increase for 20 years if a low pumping rate is applied. This study concludes that because of the rapid response of the pesticide concentration at the drinking water well due to changes in pumping, wellhead management is important for managing pesticide concentrations.     

Pro‐glacial lake sedimentation from jökulhlaups (GLOF), Blåmannsisen,northern Norway

Outburst floods from glacier‐dammed lakes are major events associated with glacier thinning and volume reduction. This paper investigates jökulhlaups emanating from the glacier‐dammed lake Øvre Messingmalmvatn at Rundvassbreen, an outlet glacier of the Blåmannsisen ice cap in northern Norway. Since 2001, the lake has several times been observed to drain suddenly, causing jökulhlaup outbursts into the pro‐glacial lake Rundvatnet. Varve analysis and lead‐210 (²¹⁰Pb) dating were used to date sediment cores taken from Rundvatnet. It was found that sedimentation from jökulhlaups is recognizable in the lake as distinct sand layers embedded in the varved silt‐clay sequence which represents the normal lake sedimentation. Sand fractions were carried in suspension because of the extreme hydraulic conditions of jökulhlaups. The thickest sand layer was deposited during the 2001 jökulhlaup which lasted three days and had a total volume of 40 ×10⁶ m³. Jökulhlaups were also recorded in 2005, 2007, 2009, and 2010; they each resulted in a sand layer. Annual sediment accumulation in Rundvatnet increased up to 10‐fold during the years with jökulhlaup outburst floods, from a normal value of 1–2 mm yr^?1 to 8–10 mm yr^?1. Five other jökulhlaups were identified from the 1910–1930 sedimentation interval, in addition to those observed in 2001–2010; there appear to have been none for 70 years during 1931–2000. Each jökulhlaup was preceded by a period when the glacier thinned to a critical volume and could no longer withstand the hydrostatic pressure of Øvre Messingmalmvatn; consequently a tunnel developed beneath the glacier, leading to a jökulhlaup. Statistical analyses of the correlations between the pro‐glacial sedimentation rate and temperature and precipitation suggested that although climate conditions are expected to influence sedimentation in the pro‐glacial catchment, a host of other interacting factors moderate the availability and delivery of sediment to the pro‐glacial system, making the processes responsible for changes in pro‐glacial sedimentation to remain uncertain. Copyright © 2014 John Wiley & Sons, Ltd.     

Candidate biomarker discovery in plasma of juvenile cod (Gadus morhua) exposed to crude North Sea oil, alkyl phenols and polycyclic aromatic hydrocarbons (PAHs)

In this study we have investigated protein changes in plasma of juvenile Atlantic cod (Gadus morhua) induced by crude North Sea oil and North Sea oil spiked with alkyl phenols and polycyclic aromatic hydrocarbons, a surrogate produced water composition. Using a proteomic approach, we identified 137 differentially expressed proteins at different levels of crude oil exposure. Many of the induced protein changes occurred at low levels of exposure. The results obtained with protein expression profiles after exposure to oil and surrogate produced water indicate effects on fibrinolysis and the complement cascade, the immune system, fertility-linked proteins, bone resorption, fatty acid metabolism as well as increased oxidative stress, impaired cell mobility and increased levels of proteins associated with apoptosis. Although the number of individuals and samples in this study is limited within each treatment group, the protein changes observed in this study represent a first screening for potential biomarker candidates in cod plasma reflecting potential effects of crude oil and produced water exposure on fish.     

Oceanic distribution and life cycle of Calanus species in the Norwegian Sea and adjacent waters

The distribution and demography of Calanus finmarchicus, C. glacialis and C. hyperboreus were studied throughout their growth season on a basin scale in the Norwegian Sea using ordination techniques and generalized additive models. The distribution and demographic data were related to the seasonal development of the phytoplankton bloom and physical characteristics of water masses. The resulting quantified relationships were related to knowledge on life cycle and adaptations of Calanus species. C. finmarchicus was the numerically dominant Calanus species in Coastal, Atlantic and Arctic waters, showing strong association with both Atlantic and Arctic waters. C. hyperboreus and C. glacialis were associated with Arctic water; however, C. glacialis was occasionally observed in the Norwegian Sea and is probably an expatriate advected into the area from various origins. Demography indicated one generation per year of C. finmarchicus, a two-year life cycle of C. hyperboreus, and both one- and two-year life cycles for C. glacialis in the water masses where they were most abundant. For the examined Calanus species, young copepodites of the new generation seemed to be tuned to the phytoplankton bloom in their main water mass. The development of C. finmarchicus was delayed in Arctic water, and mis-match between feeding stages and the phytoplankton bloom may reduce survival and reproductive success of C. finmarchicus in Arctic water. Based on low abundances of C. hyperboreus CI–III in Atlantic water and main recruitment to CI prior to the phytoplankton bloom, we suggest that reproduction of C. hyperboreus in Atlantic water is not successful.