Particle size distribution and dissolution properties of metals in cyclone fly ash

The particles in the examined cyclone fly ash were all smaller than 0.25 mm. in diameter, and particles smaller than 0.075 mm. in diameter accounted for 88.4 % of the ash weight. This result indicates that cyclone fly ash consists of particles with a small diameter. The metals in the cyclone fly ash were enriched in small particles. The highest concentrations for zinc, copper, lead, cadmium and molybdenum in the cyclone fly ash were found in the smallest particle size fraction (< 0.075 mm.) and for Barium, chromium, nickel, Vanadium and Cobalt in the second to smallest particle size fraction (0.075-0.125 mm.). From an environmental and toxicological standpoint, the smallest particles are of the greatest concern when ash is handed at landfill disposal sites (transport and disposal especially in stormy weather conditions), and some studies have reported risks to workers from prolonged exposure to ash. The results of the comparison of various dissolution methods for metals showed that the digestion procedures with nitric acid alone (USEPA 3051) or with a mixture of nitric acid + hydrogen peroxide (USEPA 3050B) slightly underestimated the metal concentrations in the cyclone fly ash. Although the use of hydrofluoric acid is often necessary for the determination of a number of elements associated with siliceous minerals, its use can result in loss of trace elements during dissolution.     

Present-day and future precipitation in the Baltic Sea region as simulated in a suite of regional climate models

Here we investigate simulated changes in the precipitation climate over the Baltic Sea and surrounding land areas for the period 2071–2100 as compared to 1961–1990. We analyze precipitation in 10 regional climate models taking part in the European PRUDENCE project. Forced by the same global driving climate model, the mean of the regional climate model simulations captures the observed climatological precipitation over the Baltic Sea runoff land area to within 15% in each month, while single regional models have errors up to 25%. In the future climate, the precipitation is projected to increase in the Baltic Sea area, especially during winter. During summer increased precipitation in the north is contrasted with a decrease in the south of this region. Over the Baltic Sea itself the future change in the seasonal cycle of precipitation is markedly different in the regional climate model simulations. We show that the sea surface temperatures have a profound impact on the simulated hydrological cycle over the Baltic Sea. The driving global climate model used in the common experiment projects a very strong regional increase in summertime sea surface temperature, leading to a significant increase in precipitation. In addition to the common experiment some regional models have been forced by either a different set of Baltic Sea surface temperatures, lateral boundary conditions from another global climate model, a different emission scenario, or different initial conditions. We make use of the large number of experiments in the PRUDENCE project, providing an ensemble consisting of more than 25 realizations of climate change, to illustrate sources of uncertainties in climate change projections.     

Use of atmospheric radiation measurement program data from Barrow, Alaska, for evaluation and development of snow-albedo parameterizations

Summary Snow albedo is determined from the ratio of out-going to incoming solar radiation using three years of broadband shortwave radiometer data obtained from the Barrow, Alaska, Atmospheric Radiation Measurement (ARM) site. These data are used for the evaluation of various types of snow-albedo parameterizations applied in numerical weather prediction or climate models. These snow-albedo parameterizations are based on environmental conditions (e.g., air or snow temperature), snow related characteristics (e.g., snow depth, snow age), or combinations of both. The ARM data proved to be well suited for snow-albedo evaluation purposes for a low-precipitation tundra environment. The evaluation confirms that snow-age dependent parameterizations of snow albedo work well during snowmelt, while parameterizations considering meteorological conditions often perform better during snow accumulation. Current difficulties in parameterizing snow albedo occur for long episodes of snow-event free conditions and episodes with a high frequency of snow events or strong snowfall. In a further step, the first two years of the ARM albedo dataset is used to develop a snow-albedo parameterization, and the third year’s data serves for its evaluation. This parameterization considers snow depth, wind speed, and air temperature which are found to be significant parameters for snow-albedo modeling under various conditions. Comparison of all evaluated snow-albedo parameterizations with this new parameterization shows improved snow-albedo prediction. Correspondence: Nicole M?lders, Geophysical Institute and College of Natural Science and Mathematics, University of Alaska Fairbanks, 903 Koyukuk Drive, P.O. Box 757320, Fairbanks, AK 99775-7320, USA     

Effect of Surface Heterogeneity on the Boundary-Layer Height: A Case Study at a Semi-Arid Forest

We investigate the effects of an isolated meso-\(\gamma \)-scale surface heterogeneity for roughness and albedo on the atmospheric boundary-layer (ABL) height, with a case study at a semi-arid forest surrounded by sparse shrubland (forest area: \(28~\text{ km }^2\), forest length in the main wind direction: 7 km). Doppler lidar and ceilometer measurements at this semi-arid forest show an increase in the ABL height over the forest compared with the shrubland on four out of eight days. The differences in the ABL height between shrubland and forest are explained for all days with a model that assumes a linear growth of the internal boundary layer of the forest through the convective ABL upwind of the forest followed by a square-root growth into the stable free atmosphere. For the environmental conditions that existed during our measurements, the increase in ABL height due to large sensible heat fluxes from the forest (\(600~\text {W~m}^{-2}\) in summer) is subdued by stable stratification in the free atmosphere above the ABL, or reduced by high wind speeds in the mixed layer.     

A comprehensive model inter-comparison study investigating the water budget during the BALTEX-PIDCAP period

Summary A comparison of 8 regional atmospheric model systems was carried out for a three-month late summer/early autumn period in 1995 over the Baltic Sea and its catchment area. All models were configured on a common grid using similar surface and lateral boundary conditions, and ran in either data assimilation mode (short term forecasts plus data assimilation), forecast mode (short term forecasts initialised daily with analyses) or climate mode (no re-initialisation of model interior during entire simulation period). Model results presented in this paper were generally post processed as daily averaged quantities, separate for land and sea areas when relevant. Post processed output was compared against available analyses or observations of cloud cover, precipitation, vertically integrated atmospheric specific humidity, runoff, surface radiation and near surface synoptic observations. The definition of a common grid and lateral forcing resulted in a high degree of agreement among the participating model results for most cases. Models operated in climate mode generally displayed slightly larger deviations from the observations than the data assimilation or forecast mode integration, but in all cases synoptic events were well captured. Correspondence to near surface synoptic quantities was good. Significant disagreement between model results was shown in particular for cloud cover and the radiative properties, average precipitation and runoff. Problems with choosing appropriate initial soil moisture conditions from a common initial soil moisture field resulted in a wide range of evaporation and sensible heat flux values during the first few weeks of the simulations, but better agreement was shown at later times. Received September 8, 2000 Revised April 3, 2001     

Schuppung und Faltung im glazialtektonischen Experiment

Zusammenfassung Die wichtigsten glazialen Stauchungsvorgänge wurden experimentell nachgeahmt. Als Versuchsmaterial fanden erwärmte Sand-Paraffin-Gemenge mit eingelegten Schichten von Modellgips Verwendung. Bei Temperaturen über dem Schmelzpunkt des Paraffins besitzen sie ähnlich günstige Eigenschaften wie der meist bevorzugte Tonschlamm, bei Zimmertemperatur sind sie erhärtet und erlauben, im Gegensatz zum Tonschlamm, beliebige Profilschnitte und damit Einblicke in den inneren Bau.Die Experimente ergaben Zusammenhänge zwischen Veränderungen im Versuchsansatz und verschiedenen Störungstypen. Es entstanden:Schuppen bei Stauchung vor dem Modell einer Eiszunge,Falten bei Stauchung unter Belastung,Horizontal eingeschlichtete Streifen bei Bewegung des Modelles unter seiner Sohle.Die Beobachtungen stimmen weitgehend überein mit den Lagerungsstörungen in eisentstandenen Formen entsprechender Bildungsbedingungen.     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

Stratigraphy and geochemistry of pillow basalts within the ophiolitic mélange of the Izmir–Ankara–Erzincan suture zone: implications for the geotectonic character of the northern branch of Neotethys

The Izmir-Ankara-Erzincan suture zone of Turkey is a broad zone of ophiolitic mélange containing numerous fragmented blocks ranging in age from Triassic to Cretaceous. Stratigraphic sequences for various mélange units are compared, together with the geochemistry of associated basaltic pillow lavas of Cretaceous age. A review of geochemical data for the pillow lavas demonstrate: (a) a dominant group of alkalic basalts with enriched incompatible elements, variable Zr/Y and Zr/Nb ratios, and (b) a range of tholeiitic basalts with slightly depleted to mildly enriched (normalized) rare earth patterns, (La/Yb)_N 0.4-3.0, and generally low Zr/Y ratios. The alkalic basalts can be chemically matched to Pacific Ocean seamounts, although the close association of red radiolarites and cherts suggests that many basalts represent the margins of such structures, rather than the main seamount edifice. Nd-Sr isotope data are typical for ocean island basalts and represent an admixture of a dominant EM-1 source and a depleted MORB-like source. Enhanced δ¹⁸O compositions are a consequence of submarine alteration and not crustal contamination. Tholeiitic compositions have affinities with both N- and E-type MORB, although most are probably representative of tholeiitic ocean islands. Overall the basalts are mainly representative of structures built on the ocean floor, rather than the oceanic crust itself, being scraped off the subducting crust and preserved in the mélange of the accretionary wedge.     

Bias of ostracod stable isotope data caused by drying of sieve residues from water

Stable isotope analysis of ostracod shells is used routinely for palaeoenvironmental studies of ostracod-bearing records. Sample treatment usually involves the disaggregation of sediments and sieving; before the sieving residues were washed with water onto petri dishes and oven-dried. In our study, we compared δ¹⁸O and δ¹³C values of shells that were oven-dried from water and from ethanol alternatively. Large isotopic differences of up to 3‰ were determined for δ¹⁸O values, whereas differences in δ¹³C values were less pronounced with differences of up to 1.6‰. Stable isotope values of shells dried from water were lower for both oxygen and carbon as a result of calcite crystals precipitated on the shell surfaces during the drying process. Therefore, ostracod shells for stable isotope analysis should not be prepared by drying from water. Instead, shells should be dried from ethanol to obtain reliable stable isotope data; likewise freeze-drying is expected to provide trustworthy results.