Ephesite,Na(LiAl2) [Al2Si2O10] (OH)2: II. Thermodynamic analysis of its stability and compatibility relations,and its geological occurrences

The trioctahedral mica ephesite, Na(LiAl₂) [Al₂Si₂O₁₀] (OH)₂, has a large -T stability field in the quaternary system NaAlSiO₄-LiAlSiO₄-Al₂O₃-H₂O. At temperatures below 400–500° C it coexists with diaspore, while at higher temperatures it occurs with corundum, until it decomposes to nepheline +eucryptite+corundum+H₂O at 600–800° C (Fig. 1). Nature faithfully reflects these phase relations; ephesite is found to coexist with diaspore or corundum in silicadeficient metamorphosed rocks or in hydrothermally altered nepheline-syenite pegmatite.Thermodynamic analysis of phase relations of ephesite in the silica saturated portion of the quinary system NaAlSiO₄-LiAlSiO₄-Al₂O₃-SiO₂-H₂O shows that the assemblage quartz+ephesite is always metastable with respect to paragonite+spodumene or paragonite+petalite at temperatures down to approximately 300° C (Fig. 3). At lower temperatures, a number of other phases like bikitaite, cookeite, Na-montmorillonite, and analcime are stabilized. Stability and compatibility relations involving these phases are presently not amenable to thermodynamic treatment due to lack of suitable data. Nevertheless, the absence of the assemblage quartz+ephesite in nature seems to vindicate our conclusion that it is metastable down to at least 300° C.The frequently encountered assemblage quartzspodumene (or petalite)-microcline-albite of some lithium pegmatites contains muscovite (±lepidolite), rather than paragonite. The absence of paragonite in such rocks is best explained by the inherent metastability of the phase-pair paragonite+microcline with respect to muscovite+albite. The pegmatite bulk compositions plot in the four-phase field spodumene (petalite)-microcline-muscovite-albite, cutting out paragonite from the observed assemblage Thus, absence of paragonite-spodumene or paragonitepetalite in nature reflects lack of suitable bulk compositions in rocks.     

Pressure-induced (Al,Si)[4]-ordering in dioctahedral micas?

Pure, synthetic 2M₁-muscovites (Ms) and 2M₁-paragonites (Pg) prepared at 7, 13.5, and 18 kbar have been subjected to careful X-ray powder diffractometry and IR powder spectrometry. The results of X-ray studies show that the lattice constants of these micas are independent of the pressure employed in synthesizing them. Similarly, the IR powder spectra of Ms and Pg remain unaffected by the synthesis pressure. Neither the Al^[4]-O-Al^[4] vibrations decrease in relative intensity nor do the Si-O-Al^[4] vibrations increase in intensity with increasing pressure of synthesis, as they should, if pressure-induced (Al, Si)^[4] ordering had been operative. Finally, the v _OH bands in Ms and Pg are also found to retain their fine structural details, regardless of the pressures employed in synthesizing these phases. In particular, the half widths of v _OH in these (Al,Si)^[4]-disordered micas remain constant at around 60 cm⁻¹, compared to ∼ 10 cm⁻¹ in (Al,Si)^[4]-ordered mica margarite. In the light of this study, shortening of the b lattice parameter and progressive (Al,Si)^[4] ordering with increasing pressure of synthesis of muscovites reported by Velde (1980) would appear to be anomalous. Consequently, any discussion of the effect of (Al,Si)^[4] ordering on the stability of muscovite is a moot point at present.     

Two- and three-dimensional gravity modeling along western continental margin and intraplate Narmada-Tapti rifts: Its relevance to Deccan flood basalt volcanism

The western continental margin and the intraplate Narmada-Tapti rifts are primarily covered by Deccan flood basalts. Three-dimensional gravity modeling of +70mgal Bouguer gravity highs extending in the north-south direction along the western continental margin rift indicates the presence of a subsurface high density, mafic-ultramafic type, elongated, roughly ellipsoidal body. It is approximately 12.0 ±1.2 km thick with its upper surface at an approximate depth of 6.0 ±0.6 km, and its average density is {dy2935} kg/m³. Calculated dimension of the high density body in the upper crust is 300 ±30 km in length and 25 ±2.5 to 40 ±4 km in width. Three-dimensional gravity modeling of +10mgal to -30mgal Bouguer gravity highs along the intraplate Narmada-Tapti rift indicates the presence of eight small isolated high density mafic bodies with an average density of {dy2961} kg/m³. These mafic bodies are convex upward and their top surface is estimated at an average depth of 6.5 ±0.6 (between 6 and 8km). These isolated mafic bodies have an average length of 23.8 ±2.4km and width of 15.9 ±1.5km. Estimated average thickness of these mafic bodies is 12.4±1.2km. The difference in shape, length and width of these high density mafic bodies along the western continental margin and the intraplate Narmada-Tapti rifts suggests that the migration and concentration of high density magma in the upper lithosphere was much more dominant along the western continental margin rift. Based on the three-dimensional gravity modeling, it is conjectured that the emplacement of large, ellipsoidal high density mafic bodies along the western continental margin and small, isolated mafic bodies along the Narmada-Tapti rift are related to lineament-reactivation and subsequent rifting due to interaction of hot mantle plume with the lithospheric weaknesses (lineaments) along the path of Indian plate motion over the Réunion hotspot. Mafic bodies formed in the upper lithosphere as magma chambers along the western continental margin and the intraplate Narmada-Tapti rifts at estimated depths between 6 and 8 km from the surface (consistent with geological, petrological and geochemical models) appear to be the major reservoirs for Deccan flood basalt volcanism at approximately 65 Ma.     

A Breadth Averaged Numerical Model for Suspended Sediment Transport in Hooghly Estuary,East Coast of India

Sedimentation is of vital concern in the conservation, development and utilization ofour soil and water resources. The suspended sediment in estuarine waters is hazardousto navigation in estuaries, which have important ports and harbours. A breadth-averagednumerical model to study circulation and sediment transport is presented in this paper.The model is applied to Hooghly estuary, along the east coast of India. The model is fullynon-linear and uses a semi-explicit finite difference scheme to solve mass, momentum andadvection diffusion equation for suspended sediments in a vertical plane. The erosion anddeposition have been computed by empirically developed source and sink terms in thesuspended sediment equation.     

Effective medium theory and multiple linear regression-based velocity estimation in syn-rift clastic sequence of the Krishna–Godavari basin,India

An inclusion model, based on the Kuster–Toksöz effective medium theory along with Gassmann theory, is tested to forward model velocities for fluid-saturated rocks. A simulated annealing algorithm, along with the inclusion model, effectively inverts measured compressional velocity (V_P) to achieve an effective pore aspect ratio at each depth in a depth variant manner, continuously along with depth. Early Cretaceous syn-rift clastic sediments at two different depth intervals from two wells [well A (2160–2274 m) and well B (5222–5303 m)], in the Krishna–Godavari basin, India, are used for this study. Shear velocity (V_S) estimated using modelled pore aspect ratio offers a high correlation coefficient (>0.95 for both the wells) with measured data. The modelled pore aspect ratio distribution suggests the decrease in pore aspect ratio for the deeper interval, mainly due to increased effective vertical stress. The pore aspect ratio analysis in relation to total porosity and volume of clay reveals that the clay volume has insignificant influence in shaping the pore geometry in the studied intervals. An approach based on multiple linear regression method effectively predicts velocity as a linear function of total porosity, the volume of clay and the modelled pore-space aspect ratio of the rock. We achieved a significant match between measured and predicted velocities. The correlation coefficients between measured and modelled velocities are considerably high (approximately 0.85 and 0.8, for V_P and V_S, respectively). This process indicates the possible influence of pore geometry along with total porosity and volume of clay on velocity.     

A dynamical study of the frequency of merging galaxies

A study of the expected frequency of merging galaxies, involving disk-sphere systems, is conducted by use of the impulsive approximation. The results indicate that the expected frequencies of such galaxies is several orders of magnitude smaller than the observational value, if mergers taking place in a single crossing time or orbital period are considered. The expected frequency of elliptical pairs and spiral-elliptical pairs in merger is of the same order of magnitude, indicating that the two types of collisions are equally frequent. This aspect will be further investigated in subsequent papers of this series.     

Magnesian andesite and dacite lavas from Mt. Shasta,northern California: products of fractional crystallization of H<Subscript>2</Subscript>O-rich mantle melts

Mt. Shasta andesite and dacite lavas contain high MgO (3.5–5 wt.%), very low FeO*/MgO (1–1.5) and 60–66 wt.% SiO₂. The range of major and trace element compositions of the Shasta lavas can be explained through fractional crystallization (~50–60 wt.%) with subsequent magma mixing of a parent magma that had the major element composition of an H₂O-rich primitive magnesian andesite (PMA). Isotopic and trace element characteristics of the Mt. Shasta stratocone lavas are highly variable and span the same range of compositions that is found in the parental basaltic andesite and PMA lavas. This variability is inherited from compositional variations in the input contributed from melting of mantle wedge peridotite that was fluxed by a slab-derived, fluid-rich component. Evidence preserved in phenocryst assemblages indicates mixing of magmas that experienced variable amounts of fractional crystallization over a range of crustal depths from ~25 to ~4 km beneath Mt. Shasta. Major and trace element evidence is also consistent with magma mixing. Pre-eruptive crystallization extended from shallow crustal levels under degassed conditions (~4 wt.% H₂O) to lower crustal depths with magmatic H₂O contents of ~10–15 wt.%. Oxygen fugacity varied over 2 log units from one above to one below the Nickel-Nickel Oxide buffer. The input of buoyant H₂O-rich magmas containing 10–15 wt.% H₂O may have triggered magma mixing and facilitated eruption. Alternatively, vesiculation of oversaturated H₂O-rich melts could also play an important role in mixing and eruption.     

Overpressure zone under the Krishna–Godavari offshore basin: geophysical implications for natural hazard in deeper-water drilling

Accurate knowledge of pore pressure is fundamental to any safe and economic well construction. Here, we present results that are indicative of over pressure zones (OPZ) for five wells drilled under the Krishna–Godavari offshore basin (KGOB) at the Eastern Continental Margin of India (ECMI). OPZ in areas of crustal flexuring can act as potential geohazard while drilling. These wells locate at water depths of 515–1,265 m, where their penetrated-vertical-depth reaches up to 3,960 m in clastic sediments. pore pressure gradient (PPG) and fracture pressure gradient (FPG) are estimated from acoustic log for all five wells, while the Normal Compaction Trend (NCT) and pore pressure are calculated from Miller’s sonic equation. Top of OPZ is indicated by values that are higher than the NCT; departure from NCT is observed at depth intervals of 1,320–2,180 m, 1,700–3,960 m, 1,600–1,880 m, 1,420–2,609 m and 2,080–2,200 m for the respective Wells 1 through 5. The pressure data from Modular Dynamic Tester (MDT) agree well with the pore pressure values obtained from the logs. The Overburden Gradient (OBG), PPG and FPG values increase rather slowly with total depth in deeper-water of KGOB when compared to the wells located in shallow water depth. Consequently, the operating safety margin between PPG and FPG decreases as the water depth increases, and this clearly leads to an increase in the number of casing strings to reach the target depth. Certain basic conclusions on the potentiality of natural hazard for drilling operations are drawn on the basis of these results, but evidently, further studies are warranted to present a more composite picture of OPZ under KGOB.     

Post-Cyclone Sidr illness patterns in coastal Bangladesh: an empirical study

After the landfall of Cyclone Sidr along the southwestern coast of Bangladesh on November 15, 2007, emergency and public health personnel within and beyond Bangladesh anticipated a massive outbreak of water-borne and other diseases in most affected areas. Fortunately, such an outbreak did not occur. The objectives of this paper are to examine the extent and pattern of illnesses experienced by Cyclone Sidr survivors in the aftermath of its landfall and to investigate household and individual-level factors associated with such illnesses. Based on face-to-face interviews conducted among 277 randomly selected Sidr survivors living in the four most severely impacted coastal districts, this study found that the post-cyclone incidence of water-borne, respiratory, and other diseases was not unusually high. Only 52 persons suffered Sidr-related illnesses, and their illnesses were significantly associated with household income, and gender and age of the Sidr survivors. A major outbreak of such diseases was largely avoided because of the proper distribution of food and safe drinking water, as well as the timely implementation of health care intervention measures. This important finding will aid relevant authorities in successfully responding to outbreaks of diseases following a future extreme event in Bangladesh and perhaps elsewhere.