Relationship of intertidal surface sediment chlorophyll concentration to hyperspectral reflectance and chlorophyll fluorescence

Estimating biomass of microphytobenthos (MPB) on intertidal mud flats is extremely difficult due to their patchy occurrence, especially at the scale of an entire mud flat. We tested two optical approaches that can be applied in situ: spectral reflectance and chlorophyll fluorescence. These two approaches were applied in 4 European estuaries with different sediment characteristics. At each site, paired replicate measurements of hyperspectral reflectance, chlorophyll fluorescence (after 15 min dark adaptation, F_o ¹⁵), sediment water content, and chlorophylla concentrations were taken (including breakdown products: [chla+phaeo]). Sediments were further characterized by grain size and organic content analysis. The spectral signatures of tidal flats dominated by benthic microalgae, mainly diatoms, could be easily distinguished from sites dominated by macrophytes; we present a 3 waveband algorithm that can be used to detect the presence of macrophytes. The normalized difference vegetation index (NDVI) was found to be most strongly correlated to sediment [chla+phaeo], except for the predominantly sandy Sylt stations. F_o ¹⁵ was also significantly correlated to sediment [chla+phaeo] in all but one grid (Sylt grid A). Our results suggest that the functional relationships (i.e., the slopes) between NDVI or fluorescence and [chla+ phaeo] were not significantly different in the muddier grids, although the intercepts could differ significantly, especially for F_o ¹⁵. This suggests a mismatch of the optical depth seen by the reflectometer or fluorometer and the depth sampled for pigment analysis. NDVI appears to be a robust proxy for sediment [chla+phaeo] and can be used to quantify MPB biomass in muddy sediments of mid latitude estuaries.     

Anoxic nitrification: Evidence from Humber Estuary sediments (UK)

Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment.     

Petrophysics and mineral exploration: a workflow for data analysis and a new interpretation framework

As mineral exploration seeks deeper targets, there will be a greater reliance on geophysical data and a better understanding of the geological meaning of the responses will be required, and this must be achieved with less geological control from drilling. Also, exploring based on the mineral system concept requires particular understanding of geophysical responses associated with altered rocks. Where petrophysical datasets of adequate sample size and measurement quality are available, physical properties show complex variations, reflecting the combined effects of various geological processes. Large datasets, analysed as populations, are required to understand the variations. We recommend the display of petrophysical data as frequency histograms because the nature of the data distribution is easily seen with this form of display. A petrophysical dataset commonly contains a combination of overlapping sub-populations, influenced by different geological factors. To understand the geological controls on physical properties in hard rock environments, it is necessary to analyse the petrophysical data not only in terms of the properties of different rock types. It is also necessary to consider the effects of processes such as alteration, weathering, metamorphism and strain, and variables such as porosity and stratigraphy. To address this complexity requires that much more supporting geological information be acquired than in current practice. The widespread availability of field portable instruments means quantitative geochemical and mineralogical data can now be readily acquired, making it unnecessary to rely primarily on categorical rock classification schemes. The petrophysical data can be combined with geochemical, petrological and mineralogical data to derive explanations for observed physical property variations based not only on rigorous rock classification methods, but also in combination with quantitative estimates of alteration and weathering. To understand how geological processes will affect different physical properties, it is useful to define three end-member forms of behaviour. Bulk behaviour depends on the physical properties of the dominant mineral components. Density and, to a lesser extent, seismic velocity show such behaviour. Grain and texture behaviour occur when minor components of the rock are the dominate controls on its physical properties. Grain size and shape control grain properties, and for texture properties the relative positions of these grains are also important. Magnetic and electrical properties behave in this fashion. Thinking in terms of how geological processes change the key characteristics of the major and minor mineralogical components allows the resulting changes in physical properties to be understood and anticipated.     

Searching for hidden Wolf–Rayet stars in the Galactic plane – 15 new Wolf–Rayet stars

We report the discovery of 15 previously unknown Wolf–Rayet (WR) stars found as part of an infrared (IR) broad-band study of candidate WR stars in the Galaxy. We have derived an empirically based selection algorithm which has selected ∼5000 WR candidate stars located within the Galactic plane drawn from the Galactic Legacy Infrared Mid-Plane Survey Extraordinaire (mid-IR) and Two-Micron All-Sky Survey (near-IR) catalogues. Spectroscopic follow-up of 184 of these reveals 11 nitrogen-rich (WN) and four carbon-rich (WC) WR stars. Early WC subtypes are absent from our sample and none shows evidence for circumstellar dust emission. Of the candidates which are not WR stars, ∼120 displayed hydrogen emission-line features in their spectra. Spectral features suggest that the majority of these are in fact B supergiants/hypergiants, ∼40 of these are identified Be/B[e] candidates.
Here, we present the optical spectra for six of the newly detected WR stars, and the near-IR spectra for the remaining nine of our sample. With a WR yield rate of ∼7 per cent and a massive star detection rate of ∼65 per cent, initial results suggest that this method is one of the most successful means for locating evolved, massive stars in the Galaxy.     

Simulating the moderating effect of a lake on downwind temperatures

A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.     

Tracing groundwater flow and sources of organic carbon in sandstone aquifers using fluorescence properties of dissolved organic matter (DOM)

The fluorescence properties of groundwaters from sites in two UK aquifers, the Penrith Sandstone of Cumbria and the Sherwood Sandstone of South Yorkshire, were investigated using excitation–emission matrix (EEM) fluorescence spectroscopy. Both aquifers are regionally important sources of public supply water and are locally impacted by pollution. The Penrith Sandstone site is in a rural setting while the Sherwood Sandstone site is in suburban Doncaster. Fluorescence analysis of samples from discrete sample depths in the Penrith Sandstone shows decreasing fulvic-like intensities with depth and also shows a good correlation with CFC-12, an anthropogenic groundwater tracer. Tryptophan-like fluorescence centres in the depth profile may also provide evidence of rapid routing of relatively recent applications of organic slurry along fractures. Fluorescence analysis of groundwater sampled from multi-level piezometers installed within the Sherwood Sandstone aquifer also shows regions of tryptophan-like and relatively higher fulvic-like signatures. The fluorescence intensity profile in the piezometers shows tryptophan-like peaks at depths in excess of 50 m and mirrors the pattern exhibited by microbial species and CFCs highlighting the deep and rapid penetration of modern recharge due to rapid fracture flow. Fluorescence analysis has allowed the rapid assessment of different types and relative abundances of dissolved organic matter (DOM), and the fingerprinting of different sources of organic C within the groundwater system. The tryptophan:fulvic ratios found in the Penrith Sandstone were found to be between 0.5 and 3.0 and are characteristic of ratios from sheep waste sources. The Sherwood Sandstone has the lowest ratios (0.2–0.4) indicating a different source of DOM, most likely a mixture of terrestrial and microbial sources, although there is little evidence of pollution from leaking urban sewage systems. Results from these two studies suggest that intrinsic fluorescence may be used as a proxy for, or complementary tool to, other groundwater investigation methods in helping provide a conceptual model of groundwater flow and identifying different sources of DOM within the groundwater system.     

Trends in Canadian Short‐Duration Extreme Rainfall: Including an Intensity–Duration–Frequency Perspective

Short-duration (5 minutes to 24 hours) rainfall extremes are important for a number of purposes, including engineering infrastructure design, because they represent the different meteorological scales of extreme rainfall events. Both single location and regional analyses of the changes in short-duration extreme rainfall amounts across Canada, as observed by tipping bucket rain gauges from 1965 to 2005, are presented. The single station analysis shows a general lack of a detectable trend signal, at the 5% significance level, because of the large variability and the relatively short period of record of the extreme short-duration rainfall amounts. The single station 30-minute to 24-hour durations show that, on average, 4% of the total number of stations have statistically significant increasing amounts of rainfall, whereas 1.6% of the cases have significantly decreasing amounts. However, regional spatial patterns are apparent in the single station trend results. Thus, for the same durations regional trends are presented by grouping the single station trend statistics across Canada. This regional trend analysis shows that at least two-thirds of the regions across Canada have increasing trends in extreme rainfall amounts, with up to 33% being significant (depending on location and duration). Both the southwest and the east (Newfoundland) coastal regions generally show significant increasing regional trends for 1- and 2-hour extreme rainfall durations. For the shortest durations of 5–15 minutes, the general overall regional trends in the extreme amounts are more variable, with increasing and decreasing trends occurring with similar frequency; however, there is no evidence of statistically significant decreasing regional trends in extreme rainfall amounts. The decreasing regional trends for the 5- to 15-minute duration amounts tend to be located in the St. Lawrence region of southern Quebec and in the Atlantic provinces. Additional analysis using criteria specified for traditional water management practice (e.g., Intensity-Duration-Frequency (IDF)) shows that fewer than 5.6% and 3.4% of the stations have significant increasing and decreasing trends, respectively, in extreme annual maximum single location observation amounts. This indicates that at most locations across Canada the traditional single station IDF assumption that historical extreme rainfall observations are stationary (in terms of the mean) over the period of record for an individual station is not violated. However, the trend information is still useful complementary information that can be considered for water management purposes, especially in terms of regional analysis.     

Possible impact melt and debris flows at Tooting Crater, Mars

Candidate examples of impact melt flows and debris flows have been identified at Tooting crater, an extremely young (<2 Myr), 29 km diameter impact crater in Amazonis Planitia, Mars. Using HiRISE and CTX images, and stereo-derived digital elevation models derived from these images, we have studied the rim and interior wall of Tooting crater to document the morphology and topography of several flow features in order to constrain the potential flow formation mechanisms. Four flow types have been identified; including possible impact melt sheets and three types of debris flows. The flow features are all located within 2 km of the rim crest on the southern rim or lie on the southern interior wall of the crater ∼1500 m below the rim crest. Extensive structural failure has modified the northern half of the crater inner wall and we interpret this to have resulted in the destruction of any impact melt emplaced, as well as volatile-rich wall rock. The impact melt flows are fractured on the meter to decameter scale, have ridged, leveed lobes and flow fronts, and cover an area >6 km × 5 km on the southern rim. The debris flows are found on both the inner wall and rim of the crater, are ∼1-2 km in length, and vary from a few tens of meters to >300 m in width. These flows exhibit varying morphologies, from a channelized, leveed flow with arcuate ridges in the channel, to a rubbly flow with a central channel but no obvious levees. The flows indicate that water existed within the target rocks at the time of crater formation, and that both melt and fluidized sediment was generated during this event.     

Impact of dynamic feedbacks between sedimentation,sea-level rise,and biomass production on near-surface marsh stratigraphy and carbon accumulation

Salt marshes accrete both organic and inorganic sediments. Here we present analytical and numerical models of salt marsh sedimentation that, in addition to capturing inorganic processes, explicitly account for above- and belowground organic processes including root growth and decay of organic carbon. The analytical model is used to examine the bias introduced by organic processes into proxy records of sedimentation, namely ¹³⁷Cs and ²¹⁰Pb. We find that accretion rates estimated using ²¹⁰Pb will be less than accretion rates estimated using the ¹³⁷Cs peak in steadily accreting marshes if (1) carbon decay is significant and (2) data for ²¹⁰Pb extend below the ¹³⁷Cs peak. The numerical model expands upon the analytical model by including belowground processes such as compaction and root growth, and by explicitly tracking the evolution of aboveground biomass and its effect on sedimentation rates. Using the numerical model we explore how marsh stratigraphy responds to sediment supply and the rate of sea-level rise. It is calibrated and tested using an extensive data set of both marsh stratigraphy and measurements of vegetation dynamics in a Spartina alterniflora marsh in South Carolina, USA. We find that carbon accumulation in marshes is nonlinearly related to both the supply of inorganic sediment and the rate of sea-level rise; carbon accumulation increases with sea-level rise until sea-level rise reaches a critical rate that drowns the marsh vegetation and halts carbon accumulation. The model predicts that changes in carbon storage resulting from changing sediment supply or sea-level rise are strongly dependent on the background sediment supply: if inorganic sediment supply is reduced in an already sediment poor marsh the storage of organic carbon will increase to a far greater extent than in a sediment-rich marsh, provided that the rate of sea-level rise does not exceed a threshold. These results imply that altering sediment supply to estuaries (e.g., by damming upstream rivers or altering littoral sediment transport) could lead to significant changes in the carbon budgets of coastal salt marshes.