Evaluation of recent hydro-climatic changes in four tributaries of the Niger River Basin (West Africa)

West Africa experienced severe drought during the 1970s and 1980s, posing a threat to water resources. A wetter climate more recently suggests recovery from the drought. The Mann-Kendall trend and Theil-Sen’s slope estimator were applied to detect probable trends in weather elements in four sub-basins of the Niger River Basin between 1970 and 2010. The cross-entropy method was used to detect breakpoints in rainfall and runoff, Spearman’s rank test for correlation between the two, and cross-correlation analysis for possible lags. Results showed an overall increase in rainfall and runoff and a decrease in sunshine duration. Spearman’s coefficients suggest significant (5%) moderate to strong rainfall–runoff correlation for three sub-basins. A significant lower runoff was observed around 1979, with a rainfall break around 1992, indicating possible cessation of the drought. Temperatures increased significantly, at 0.02–0.05°C year^-1, with a negative wind speed trend for most stations. Half of the stations exhibited an increase in potential evapotranspiration.

EDITOR M.C. Acreman

ASSOCIATE EDITOR Not assigned     

Chronology of the last deglaciation and Holocene environmental changes in the Sisimiut area,SW Greenland based on lacustrine records

The Sisimiut area was deglaciated in the early Holocene, c. 11 cal. ka BP. At that time the lowlands were inundated by the sea, but the isostatic rebound surpassed the global sea‐level rise, and the lowlands emerged from the sea. The pioneer vegetation in the area consisted of mosses and herbaceous plants. The oldest remains of woody plants (Empetrum nigrum) are dated to c. 10.3 cal. ka BP, and remains of Salix herbacea and Harrimanella hypnoides are found in slightly younger sediments. The maximum occurrence of statoblasts of the bryozoan Plumatella repens from c. 10 to 4.5 cal. ka BP probably reflects the Holocene thermal maximum, which is also indicated in geochemical proxies of the lake sediments. A maximum in organic matter accumulation in one of the three studied lakes c. 3 cal. ka BP can probably be ascribed to a late Holocene short‐duration temperature maximum or a period of increased aridity. Cenococcum geophilum sclerotia are common in the late Holocene, implying increased soil erosion during the Neoglaciation. A comparison with sediment and macrofossil records from inland shows similar Holocene trends and a similar immigration history. It also reveals that there has been a significant gradient throughout the Holocene, from an oceanic and stable climate at the outer coast to a more continental and unstable climate with warmer summers and drier conditions close to the margin of the Greenland ice sheet, where the buffer capacity of the sea is lower.     

Experimental impact cratering: A summary of the major results of the MEMIN research unit

This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.     

An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.     

Compositions,sources and depositional environments of organic matter from the Middle Jurassic clays of Poland

The comprehensive biomarker characteristics from previously undescribed Middle Jurassic clays of Poland are presented. The molecular composition of the organic matter (OM) derived from clays of Aalenian to Callovian age has not changed significantly through time. High relative concentrations of many biomarkers typical for terrestrial material suggest a distinct dominance of OM derived from land plants. Increasing concentrations of C₂₉-diaster-13(17)-enes towards the northern part of the basin indicate an increase in terrestrial input. This terrestrial material would have originated from the enhanced transport of organic matter from land situated at the northern bank of the basin, i.e., the Fennoscandian Shield. The organic matter was deposited in an oxic to suboxic environment, as indicated by relatively low concentrations of C₃₃–C₃₅ homohopanes, moderate to high Pr/Ph ratio values, an absence of compounds characteristic for anoxia and water column stratification, such as isorenieratane, aryl isoprenoids and gammacerane, as well as common benthic fauna and burrows. δ¹⁸O measurements from calcitic rostra of belemnites suggest that the mean value of the Middle Jurassic sea-water temperature of the Polish Basin was 13.1 °C. It is suggested that this mirrored the temperature of the lower water column because belemnites are considered here to be necto-benthic. The organic matter from the Middle Jurassic basin of Poland is immature. This is clearly indicated by a large concentration of biomarkers with the biogenic configurations, such as ββ-hopanes, hop-13(18)-enes, hop-17(21)-enes, diasterenes and sterenes. The identification of preserved, unaltered biomolecules like ferruginol, 6,7-dehydroferruginol and sugiol in Protopodocarpoxylon wood samples from these sediments present particularly strong evidence for the presence of immature OM in the Middle Jurassic sediments. Moreover, the occurrence of these polar diterpenoids is important due to the fact that they are definitely the oldest known natural products detected in geological samples.     

Determination of vertical temperature profiles for the atmospheric boundary layer by ground-based microwave radiometry

A useful method for remote sensing of vertical temperature profiles in the atmospheric boundary layer is described. From angular measurements of brightness temperature at 58 GHz, profiles have been inferred up to an altitude of 700 m. Calculations were done with an iterative inversion procedure (Smith et al., 1972) using Twomey-type smoothing (Twomey, 1963). It is shown how an initial-guess profile can be directly derived from the radiation measurements using, a nomogram.     

Diterpenoid compounds and other lipids in deep-sea sediments and their geochemical significance

Cyclic diterpenoid compounds have been found by various investigators in the geosphere (e.g. fossil resins, coals, soil, shale and deep-sea sediments). These compounds occur in significant amounts only in higher plants and are therefore potential markers of terrigenous plant lipids.Diterpenoids with the abietane skeleton (mainly dehydroabietic acid) have been identified in the lipids of sediment samples from the northeast Pacific Ocean, Black Sea and North Atlantic Ocean. The presence of these resin-derived compounds correlated with the terrigenous clay components and with the presence of pollen. The presence of polycyclic diterpenoids was also correlated with the distribution patterns and inferred sources of other sediment lipid constituents (e.g. n-alkanes, n-fatty acids, etc.).Potamic transport, followed by turbidite redistribution are the probable input mechanisms of these resin-derived compounds to the deep-sea sediments. These diterpenoids appear to be excellent biological markers of resinous higher plants.     

哀牢山-红河剪切带左行走滑作用起始时间约束

位于哀牢山-红河剪切带NW延伸方向上的点苍山变质杂岩体遭受强烈的左行走滑剪切变形、变质作用改造,岩石中保存了典型的高温矿物组合以及由它们构成的宏观和微观高温变形构造特征,其中糜棱岩中具有极其发育的长石矿物拉伸线理而形成典型的L与LS型构造岩是其一个明显的特征。本文对点苍山地区高温糜棱岩主要矿物开展了显微构造与矿物变形、变形机制及组构分析,并对于遭受高温糜棱岩化改造的一个花岗质岩体开展了SHRIMP锆石U-Pb定年分析。结果表明岩石中长石、角闪石、石英等主要矿物具有典型的达角闪岩相条件下的高温晶质塑性变形和动态生长特征,它们也为走滑剪切变形活动提供了充分的微观构造证据。对于点苍山高温糜棱岩化改造的眼球状或似斑状二长花岗岩的显微构造分析结果表明,这套花岗质岩石从走滑剪切前期岩浆的侵位之后经历了早期强烈的岩浆期后交代作用—亚岩浆流动—高温固态塑性剪切变形的递进演化过程。由此可见,岩浆的上升与就位受左行走滑剪切作用的制约,岩体又遭受了强烈剪切变形改造。同时对这套构造前期就位花岗质岩石中的锆石进行定年分析,获得33.88±0.32Ma的岩浆结晶年龄,为此,我们有充分的理由认为,在点苍山地区哀牢山-红河剪切带左行走滑剪切作用的起始时间至少应该为早渐新世30.88±0.32Ma。     

Kinetic rate laws derived from order parameter theory IV: Kinetics of Al,Si disordering in Na-feldspars

The kinetic rate laws of Al-Si disordering under dry conditions (T = 1353K, 1253 K, 1223 K, 1183 K) and in the presence of water (p = 1 kbar, T = 1023 K, 1073 K, 1103 K) were studied both experimentally and theoretically. A gradual change of the degree of order was found under dry conditions. For intermediate degrees of order broad distributions of the order parameter Q _od occur. The variations of Q _od are correlated with structural modulations as observed in the transmission electron microscope. The time evolution of the mean value of Q _od can be well described by the rate law: $$\frac{{dQ_{od} }}{{dt}} = - \frac{\gamma }{{RT}}\exp \sum\limits_{i = 1}^n {X_i^2 } \left[ {\frac{{ - (G_a^0 + \varepsilon (\Delta Q_{od} )^2 )}}{{RT}}} \right]\frac{{dG}}{{dQ_{od} }}$$ with the excess Gibbs energy G and G _a ⁰ = 433.8 kJ/mol, ?= -27.4 kJ/mol, γ = 1.687 · 10¹⁴ h ^?1. Under wet conditions, two processes were found which occur simultaneously. Firstly, some material renucleated with the equilibrium degree of order. Secondly, the bulk of the material transformed following the same rate law as under dry conditions but with the reduced activation energy G _a ⁰ = 332.0 kJ/mol and ? = -43.0 kJ/ mol, γ = 1.047 · 10¹³ h^?1. The applicability of the kinetic theory is discussed and some ideas for the analysis of geological observations are evolved.     

A tephrostratigraphic record for the last glacial–interglacial cycle from Lake Ohrid,Albania and Macedonia

Here we present a tephrostratigraphic record (core Co1202) recovered from the northeastern part of Lake Ohrid (Republics of Macedonia and Albania) reaching back to Marine Isotope Stage (MIS) 6. Overall ten horizons (OT0702‐1 to OT0702‐10) containing volcanic tephra have been recognised throughout the 14.94 m long sediment succession. Four tephra layers were visible at macroscopic inspection (OT0702‐4, OT0702‐6, OT0702‐8 and OT0702‐9), while the remaining six are cryptotephras (OT0702‐1, OT0702‐2, OT0702‐3, OT0702‐5, OT0702‐7 and OT0702‐10) identified from peaks in K, Zr and Sr intensities, magnetic susceptibility measurements, and washing and sieving of the sediments. Glass shards of tephra layers and cryptotephras were analysed with respect to their major element composition, and correlated to explosive eruptions of Italian volcanoes. The stratigraphy and the major element composition of tephra layers and cryptotephras allowed the correlation of OT0702‐1 to AD 472 or AD 512 eruptions of Somma‐Vesuvius, OT0702‐2 to the FL eruption of Mount Etna, OT0702‐3 to the Mercato from Somma‐Vesuvius, OT0702‐4 to SMP1‐e/Y‐3 eruption from the Campi Flegrei caldera, OT0702‐5 to the Codola eruption (Somma‐Vesuvius or Campi Flegrei), OT0702‐6 to the Campanian Ignimbrite/Y‐5 from the Campi Flegrei caldera, OT0702‐7 to the Green Tuff/Y‐6 eruption from Pantelleria Island, OT0702‐8 to the X‐5 eruption probably originating from the Campi Flegrei caldera, OT0702‐9 to the X‐6 eruption of generic Campanian origin, and OT0702‐10 to the P‐11 eruption from Pantelleria Island. The fairly well‐known ages of these tephra layers and parent eruptions provide new data on the dispersal and deposition of these tephras and, furthermore, allow the establishment of a chronological framework for core Co1202 for a first interpretation of major sedimentological changes. Copyright © 2009 John Wiley & Sons, Ltd.