Adakite-like signature of Late Miocene intrusions at the Los Pelambres giant porphyry copper deposit in the Andes of central Chile: metallogenic implications

Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and La_N/Yb_N (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb     

Pyrolysis-high resolution gas chromatography and pyrolysis gas chromatography-mass spectrometry of kerogens and kerogen precursors

A series of kerogens and kerogen precursors isolated from DSDP samples, oil shales and Recent algal mats have been examined by Curie point pyrolysis-high resolution gas chromatography and gas chromatography-mass spectrometry. This study has shown that the three main types of kerogens (marine, terrestrial and mixtures of both) can be characterized using these techniques. The marine (algal) kerogens yield principally aliphatic products and the terrestrial kerogens yield more aromatic and phenolic products with some n-alkanes and n-alkenes. The yields of n-alkanes and n-alkenes increase and phenols decrease with increasing geologic age, however, pyrolysis-GC cannot be used to characterize the influence of short term diagenesis on the kerogen structure.     

Biomarkers in sedimentary sulfides of precambrian age

Samples of the Mt Isa formation (Australia, c, 1.5 Ga), and the Shungit formation (U.S.S.R., c. 2.3 Ga) were studied by organic geochemical means. All samples were freed of any low-molecular-weight solvent soluble organic material in order to insure the authenticity of the analysed material. The isolation of biochemical compounds entrapped in sulfides was the major goal of this work.Organic compounds that were entrapped during the early stages of sulfide formation may obviously survive extended periods of time and can be released by a mild hydrogenation of the sulfides. Preliminary investigations of the hydrocarbon fraction indicate n-alkanes, monomethylalkanes, cycloalkanes, and an unknown series of branched alkanes as major constituents. Their distribution patterns show great selectivity with respect to structures and chain lengths of individual compounds. Differences between the hydrogenation reaction product and the sample extract may arise from the release of a different kind of lipid material through dissolution of the sulfides.     

Origins and evolution of rhyolitic magmas in the central Snake River Plain: insights from coupled high-precision geochronology,oxygen isotope,and hafnium isotope analyses of zircon

We present new high-precision CA-ID-TIMS and in situ U–Pb ages together with Hf and O isotopic analyses (analyses performed all on the same grains) from four tuffs from the 15?10 Ma Bruneau–Jarbidge center of the Snake River Plain and from three rhyolitic units from the Kimberly borehole in the neighboring 10?6 Ma Twin Falls volcanic center. We find significant intrasample diversity in zircon ages (ranges of up to 3 Myr) and in δ¹⁸O (ranges of up to 6‰) and ε_Hf (ranges of up to 24 ε units) values. Zircon rims are also more homogeneous than the associated cores, and we show that zircon rim growth occurs faster than the resolution of in situ dating techniques. CA-ID-TIMS dating of a subset of zircon grains from the Twin Falls samples reveals complex crystallization histories spanning 10⁴–10⁶ years prior to some eruptions, suggesting that magma genesis was characterized by the cyclic remelting of buried volcanic rocks and intrusions associated with previous magmatic episodes. Age-dependent trends in zircon isotopic compositions show that rhyolite production in the Yellowstone hotspot track is driven by the mixing of mantle-derived melts (normal δ¹⁸O and ε_Hf) and a combination of Precambrian basement rock (normal δ¹⁸O and ε_Hf down to ??60) and shallow Mesozoic and Cenozoic age rocks, some of which are hydrothermally altered (to low δ¹⁸O values) by earlier stages of Snake River Plain magmatism. These crustal melts hybridize with juvenile basalts and rhyolites to produce the erupted rhyolites. We also observe that the Precambrian basement rock is only an important component in the erupted magmas in the first eruption at each caldera center, suggesting that the accumulation of new intrusions quickly builds an upper crustal intrusive body which is isolated from the Precambrian basement and evolves towards more isotopically juvenile and lower-δ¹⁸O compositions over time.     

Protecting small cetaceans from coastal development: Impact assessment and mitigation experience in Hong Kong

Since the early 1990s, there has been an active program in Hong Kong to manage and protect local populations of small cetaceans from the effects of massive development in the area. This paper reviews the progress that has been made. Only two species regularly occur there: the Indo-Pacific humpback dolphin and the finless porpoise. Because most development has occurred in the western waters of Hong Kong, where generally only the humpback dolphin occurs, most of the work has been conducted on that species. Development of large infrastructure projects (such as airports, bridges, expressways, power plants, fuel facilities, and container ports) in Hong Kong often results in land reclamation, dredging and dumping of spoils, pipe and cable laying, percussive and bored piling work, underwater blasting, large increases in vessel traffic, and other impacts. Several mitigation measures have been used with varying levels of success, including bubble curtains/jackets, exclusion zones, ramping up of piling hammers, acoustic decoupling of noisy equipment, vessel speed limits, no-dumping policies, and silt curtains. Baseline, construction-phase, and operational-phase cetacean monitoring is often conducted to evaluate the success of conservation measures put into place. The Environmental Impact Assessment process in Hong Kong has involved cetaceans to a degree perhaps higher than anywhere else in the world, and much can be learned from studying the successes and failures of this situation.     

Chronology of the last deglaciation and Holocene environmental changes in the Sisimiut area,SW Greenland based on lacustrine records

The Sisimiut area was deglaciated in the early Holocene, c. 11 cal. ka BP. At that time the lowlands were inundated by the sea, but the isostatic rebound surpassed the global sea‐level rise, and the lowlands emerged from the sea. The pioneer vegetation in the area consisted of mosses and herbaceous plants. The oldest remains of woody plants (Empetrum nigrum) are dated to c. 10.3 cal. ka BP, and remains of Salix herbacea and Harrimanella hypnoides are found in slightly younger sediments. The maximum occurrence of statoblasts of the bryozoan Plumatella repens from c. 10 to 4.5 cal. ka BP probably reflects the Holocene thermal maximum, which is also indicated in geochemical proxies of the lake sediments. A maximum in organic matter accumulation in one of the three studied lakes c. 3 cal. ka BP can probably be ascribed to a late Holocene short‐duration temperature maximum or a period of increased aridity. Cenococcum geophilum sclerotia are common in the late Holocene, implying increased soil erosion during the Neoglaciation. A comparison with sediment and macrofossil records from inland shows similar Holocene trends and a similar immigration history. It also reveals that there has been a significant gradient throughout the Holocene, from an oceanic and stable climate at the outer coast to a more continental and unstable climate with warmer summers and drier conditions close to the margin of the Greenland ice sheet, where the buffer capacity of the sea is lower.     

Settling-velocity distributions and sorting processes on a longitudinal dune: A case study

The processes acting on a longitudinal dune are inferred from the response in the area size-sorting characteristics of the sediment of the active layer. The sediment size distributions are determined by settling and are best described by a log-hyperbolic model which provides the most information on size-sorting processes. Size-sorting characteristics are markedly different across the low round-crested part of the dune from cross-sections of the high more sharp-crested part. This results in changes in textural parameters along the lee-side consistent with changes in the lee-side separation vortex. This is the first time that the effect of wind speed up on the lee-side is observed to be reflected in the sediment; it can only be detected with the very sensitive log-hyperbolic parameters.     

Deformation fabric and microstructures in ophiolitic chromitites and host ultramafics,Sultanate of Oman

Harzburgite and dunite from the Oman ophiolite display a strong olivine fabric and microstructures typical for high temperature mantle deformation. The syntectonic, magmatically formed, chromitites occurring throughout the mantle sequence vary from almost undeformed (resembling chromitite from stratiform complexes) to highly deformed. Usually the interstitial silicates in the deformed ore possess a fabric similar to those of the host rocks, whereas a weak or poikilitic fabric is observed on relatively undeformed deposits. Chromite grains are elongated and flattened, defining strong foliations and lineations, in disseminated ore, and pull-apart-like structures perpendicular to the lineation form in the coarser massive ore. No preferred crystallographic orientation of chromite has been detected with the X-ray-texture goniometer, and it is proposed that chromite mainly deforms by passive rotation in the weaker silicate matrix, cataclasis and diffusion creep.

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Zusammenfassung Die Dunite und Harzburgite, die im Ophiolit des Oman auftreten, zeigen ein Olivingefüge und Mikrostrukturen, die typisch sind für Manteldeformationen bei hohen Temperaturen. Die syntektonischen, magmatisch gebildeten Chromitite sind über die gesamte Abfolge der Mantelgesteine zu finden. Das Ausmaß der Deformation der Chromitite reicht von gering bis stark. Fast undeformierte Chromitite gleichen denen stratiformer Komplexe. Im deformierten Erz zeigen die in Zwickeln auftretenden Silikatminerale im allgemeinen ein ähnliches Gefüge wie das Wirtsgestein; in relativ undeformierten Vorkommen zeigen sie ein schwaches oder poikilitisches Gefüge. Die Chromitkörner haben einen plattigen Habitus und bilden im Sprenkelerz ein deutliches Flächen- und Lineargefüge. Im grobkörnigen Derberz entstehen hingegen Dehnungsstrukturen (pull-apart textures) senkrecht zur Lineation. Röntgentexturgoniometrische Untersuchungen ergaben keine Regelung des Chromits, und es wird daher angenommen, daß der Chromit aufgrund passiver Rotation in der schwächeren Silikatmatrix deformiert wurde, weiterhin kommen auch Kataklase und Diffusionsmechanismen in Frage.

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Résumé Les dunites et harzburgites du complexe ophiolitique d'Oman présentent une forte fabrique de l'olivine et des microstructures typiques de déformations mantelliques de haute température. Les chromitites, d'origine magmatique syntectomque, qui se trouvent le long de la séquence mantellique varient entre des termes presque non déformés (ressemblant aux chromitites des complexes stratiformes) jusqu'à des termes très déformés. Les silicates interstitiels du minerai déformé présentent fréquemment une fabrique semblable à celle des minéraux de la roche hôte alors que l'on observe une fabrique peu développée ou bien une texture poecilitique dans les minerais des gisements relativement peu déformés. Les cristaux de chromite sont allongés et aplatis, définissant une foliation et une linéation très marquées dans les minerais disséminés; des structures d'étirement (pull-apart) perpendiculaires à la linéation apparaissent dans les minerais plus massifs. Aucune orientation cristallographique préferentielle n'a pu être mise en évidence au goniomètre de texture; on propose donc que la chromite se déforme principalement par rotation passive dans une matrice silicatée plus fragile, par cataclase et par fluage-diffusion.

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PLL Tracking Performance in the Presence of Oscillator Phase Noise

The tracking performance of a Phase Lock Loop (PLL) is affected by the influence of several error sources. In addition to thermal noise and dynamic stress error, oscillator phase noise can cause significant phase jitter which degrades the tracking performance. Oscillator phase noise is usually caused by two different effects: Allan deviation phase noise is caused by frequency instabilities of the receiver's reference oscillator and the satellite's frequency standard. It can be termed as system-inherent phase noise and is relevant for both static and dynamic applications. “External” phase noise, however, is caused by vibration and is a major problem for dynamic applications. In the context of this paper, both types of phase noise will be modeled and the resulting integrals will be evaluated for PLLs up to the third order. Besides, phase jitter induced by thermal noise and signal dynamics will also be discussed, thus providing all necessary formulas for analyzing the performance of a phase lock loop in case of different forms of stress. Since the main focus is centered on the effects of oscillator phase noise, the overall PLL performance is graphically illustrated with and without consideration of oscillator phase noise. © 2002 Wiley Periodicals, Inc.