A new procedure for separating and measuring radiogenic isotopes (U, Th, Pa, Ra, Sr, Nd, Hf) in ice cores

A new method for the radiogenic isotope (U–Th–Pa–Ra, Sr, Nd, Hf) analysis of the soluble and insoluble components found within ice cores is presented. Melting experiments with rock standards in the presence of EDTA indicate that carbonates, as well as silicates, can be buffered sufficiently to preclude dissolution. The use of EDTA allows adsorbing species, such as Th and Hf, to remain in solution during melting thus fully separating the dust (insoluble) and sea salt (soluble) components of the ice after filtration. A new elemental separation scheme for low sample masses, less than 5 mg solid material, utilizes 4 primary ion exchange columns and two “clean-up” columns to fully isolate U, Th, Pa, Ra, Sr, Nd, and Hf while maintaining high yields. Elution schemes measured for USGS rock standards and a Chinese loess are presented to provide a comparison for variable matrix compositions. Mass spectrometer techniques were modified to measure small aliquots of the standards, equivalent to the amounts found in ice core samples, 10 ng and less. A MC-ICPMS was employed for the measurement of U, Th, Pa, Ra, and Hf; results of the experiments show that with ion yields up to 1%, rock standards have errors for ²³⁴U/²³⁸U of 1%, ²³⁰Th/²³²Th of 1.5%, [²²⁸Ra] of 9%, and ¹⁷⁶Hf/¹⁷⁷Hf of 100 ppm. MC-TIMS measurements of Sr and Nd show similar errors for small sample sizes: ⁸⁷Sr/⁸⁶Sr of 50 ppm and ¹⁴³Nd/¹⁴⁴Nd of 80 ppm. This new analytical method increases the number of possible tracers measured from a single sample, reducing separation times and sample consumption, as well as providing the addition of a radiometric clock, U-series, to the traditional suite of isotopic tracers, Sr, Nd, and Hf.     

The degree of urbanization across the globe is not reflected in the δN of seagrass leaves

Many studies show that seagrass δ¹⁵N ratios increase with the amount of urbanization in coastal watersheds. However, there is little information on the relationship between urbanization and seagrass δ¹⁵N ratios on a global scale. We performed a meta-analysis on seagrass samples from 79 independent locations to test if seagrass δ¹⁵N ratios correlate with patterns of population density and fertilizer use within a radius of 10–200 km around the sample locations. Our results show that seagrass δ¹⁵N ratios are more influenced by intergeneric and latitudinal differences than the degree of urbanization or the amount of fertilizer used in nearby watersheds. The positive correlation between seagrass δ¹⁵N ratios and latitude hints at an underlying pattern in discrimination or a latitudinal gradient in the ¹⁵N isotopic signature of nitrogen assimilated by the plants. The actual mechanisms responsible for the correlation between δ¹⁵N and latitude remain unknown.     

The origin of selected lunar geochemical anomalies: Implications for early volcanism and the formation of light plains

The Apollo orbital geochemistry, photogeologic, and other remote sensing data sets were used to identify and characterize geochemical anomalies on the eastern limb and farside of the Moon and to investigate the processes responsible for their formation. The anomalies are located in the following regions: (1) Balmer basin, (2) terrain northeast of Mare Smythii, (3) near Langemak crater, (4) Pasteur crater, (5) terrain northwest of Milne basin, (6) northeast of Mendeleev basin, (7) north and northeast of Korolev basin, (8) terrain north of Taruntius crater, and (9) terrain north of Orientale basin. The anomalies are commonly associated with Imbrian- or Nectarian-aged light plains units which exhibit dark-haloed impact craters. The results of recent spectral reflectance studies of dark-haloed impact craters plus consideration of the surface chemistry of the anomalies strongly indicate that those geochemical anomalies associated with light plains deposits which display dark-haloed impact craters result from the presence of basaltic units that are either covered by varying thickness of highland debris or have a surface contaminated with significant amounts of highlands material. The burial or contamination of ancient volcanic surfaces by varying amounts of highland material appears to have been an important (though not the dominant) process in the formation of lunar light plains. Basaltic volcanism on the eastern limb and farside of the Moon was more extensive in both space and time than has been accepted.     

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.     

Low-pressure adsorption of Ar, Kr, and Xe on carbonaceous materials (kerogen and carbon blacks), ferrihydrite, and montmorillonite: Implications for the trapping of noble gases onto meteoritic matter

Noble gases trapped in meteorites are tightly bound in a carbonaceous carrier labeled “phase Q.” Mechanisms having led to their retention in this phase or in its precursors are poorly understood. To test physical adsorption as a way of retaining noble gases into precursors of meteoritic materials, we have performed adsorption experiments for Ar, Kr, and Xe at low pressures (10⁻⁴ mbar to 500 mbar) encompassing pressures proposed for the evolving solar nebula. Low-pressure adsorption isotherms were obtained for ferrihydrite and montmorillonite, both phases being present in Orgueil (CI), for terrestrial type III kerogen, the best chemical analog of phase Q studied so far, and for carbon blacks, which are present in phase Q and can be considered as possible precursors.Based on adsorption data obtained at low pressures relevant to the protosolar nebula, we propose that the amount of noble gases that can be adsorbed onto primitive materials is much higher than previously inferred from experiments carried out at higher pressures. The adsorption capacity increases from kerogen, carbon blacks, montmorillonite to ferrihydrite. Because of its low specific surface area, kerogen can hardly account for the noble gas inventory of Q. Carbon blacks in the temperature range 75 K-100 K can adsorb up to two orders of magnitude more noble gases than those found in Q. Irreversible trapping of a few percent of noble gases adsorbed on such materials could represent a viable process for incorporating noble gases in phase Q precursors. This temperature range cannot be ruled out for the zone of accretion of the meteorite precursors according to recent astrophysical models and observations, although it is near the lower end of the temperatures proposed for the evolving solar nebula.     

Distinguishing volcanic debris avalanche deposits from their reworked products: the Perrier sequence (French Massif Central)

Debris avalanches associated with volcanic sector collapse are usually high-volume high-mobility phenomena. Debris avalanche deposit remobilisation by cohesive debris flows and landslides is common, so they can share textural characteristics such as hummocks and jigsaw cracks. Distinguishing original deposits from reworked products is critical for geological understanding and hazard assessment because of their different origin, frequency and environmental impact. We present a methodology based on field evidence to differentiate such epiclastic breccias. Basal contact mapping constrained by accurate altitude and location data allows the reconstruction of deposit stratigraphy and geometry. Lithological analysis helps to distinguish the different units. Incorporation structures, kinematic indicators and component mingling textures are used to characterise erosion and transport mechanisms. We apply this method to the enigmatic sequence at Perrier (French Massif Central), where four units (U1–U4) have been interpreted either as debris flow or debris avalanche deposits. The sequence results from activity on the Monts Dore Volcano about 2 Ma ago. The epiclastic units are matrix supported with an almost flat top. U2 and U3 have clear debris flow deposit affinities such as rounded clasts and intact blocks (no jigsaw cracks). U1 and U4 have jigsaw cracked blocks with matrix injection and stretched sediment blocks. U1 lacks large blocks (>10 m wide) and has a homogenous matrix with an upward increase of trapped air vesicle content and size. This unit is interpreted as a cohesive debris flow deposit spawned from a debris avalanche upstream. In contrast, U4 has large mega-blocks (up to 40 m wide), sharp contacts between mixed facies zones with different colours and numerous jigsaw fit blocks (open jigsaw cracks filled by monogenic intra-clast matrix). Mega-blocks are concentrated near the deposit base and are spatially associated with major substratum erosion. This deposit has a debris avalanche distal facies with local debris flow affinities due to partial water saturation. We also identify two landslide deposits (L1 and L2) resulting from recent reworking that has produced a similar facies to U1 and U4. These are distinguishable from the original deposits, as they contain blocks of mixed U1/U4 facies, a distinctly less consolidated and more porous matrix and a fresh hummocky topography. This work shows how to differentiate epiclastic deposits with similar characteristics, but different origins. In doing so, we improve understanding of present and past instability of the Monts Dore and identify present landslide hazards at Perrier.     

Geochemistry of high-grade eclogites and metarodingites from the Central Alps

Analyses for major, minor, and trace element contents of metamorphosed, variably rodingitized mafic rocks demonstrate substantial removal of Na and as much as three-fold gains in Ca as a consequence of rodingitization. Modest declines in Si and Fe can be explained in terms of dilution effects. Losses in K and Ba do not correlate with Ca% and may have been caused by an alteration process not related to the rodingitization. The Ca-metasomatism was not accompanied by a gain in Sr. The relative contents of Ti, Zr, Hf, Y, Co, Sc, and heavy REE show no readily detectable changes, despite the rodingitization (±other alteration) and subsequent metamorphisms, namely, eclogite facies (T800° C, P 20kbar) followed by amphibolite facies, sillimanite zone. Protoliths were tholeiitic basalt or diabase, and gabbro, with trace element contents indicative of a spreading center origin. Trace element and REE patterns indicate low-pressure fractionation of this magma, with plagioclase stable. This petrogenesis is consistent with prior conclusions on the shallow crustal origin of the protolith of the eclogite-metarodingite-garnet lherzolite suite in the Cima Lunga-Adula nappe, Central Alps. Based on their bulk chemical composition, the mafic rocks in this suite could be the equivalent of Mesozoic ophiolitic rocks in the more external parts of the Alps.     

Impacts of Holocene climatic variations on alluvial fan activity below snowpatches in subarctic Québec

In the Lake Guillaume-Delisle area of subarctic Québec, storm-generated alluvial fans have been active sporadically throughout the Holocene. In this study, we propose that the persistence of late-lying snowpatches in fan catchments during Holocene cold episodes promoted alluvial fan activity by lowering the precipitation threshold required to trigger a torrential event. This hypothesis was tested by characterizing the depositional processes responsible for alluvial fan formation below snowpatches, and by reconstructing the Holocene alluvial fan activity. Stratigraphic and sedimentary analyses conducted on seven alluvial fans revealed that they were deposited by torrential activity leading to waterlaid, transient, or hyperconcentrated deposition. The chronology of the storm-generated alluvial fans — based on 22 radiocarbon dates — indicates that torrential activity was enhanced during the cooler Late Holocene (i.e., after ca. 3500 cal. yr BP). Snowier winters and cooler summers were beneficial to nival activity, allowing the persistence of larger snowpatches throughout the summer and fall seasons. Rainfall-induced thaw of such snowpatches during rainstorm events is inferred to have contributed to alluvial fan activity by increasing water availability. Three peaks of alluvial activity occurred during the Late Holocene (2950–2750, 1900–1400, and 800–300 cal. yr BP) and are indicative of increased storminess resulting in higher fan activity. Increased fan activity during cooler episodes was concurrent with increased runoff activity in the immediate pronival area. This stresses the importance of nivation below snowpatches and pinpoints the role of nivation in enhancing geomorphological activity during period of cooler and more humid climate in subarctic environments.