A Practical Approach for Collecting Large‐n Detrital Zircon U‐Pb Data sets by Quadrupole LA‐ICP‐MS

A measurement procedure for the rapid acquisition of U‐Pb dates for detrital zircons by quadrupole LA‐ICP‐MS was developed. The procedure achieves a threefold increase in measurement efficiency compared with the most commonly used methods. Utilising reduced background counting times and a shortened ablation period, a throughput of ~ 130 measurements/h can be achieved. The measurement procedure was characterised and validated using data from thirty‐nine sessions acquired over a twelve‐month period. Systematic measurement error in ²⁰⁶Pb/²³⁸U dates for reference materials used for quality control with ages between 28.2 and 2672 Ma was < 1.5%. Average measurement uncertainty, including both random and systematic components, was 1–4% (2s). Interrogation of time‐resolved calculated dates and signal intensities for each measurement allows for the detection and elimination of portions of measurements exhibiting age heterogeneities, zoning, lead loss and contamination by common lead. The measurement procedure diminishes the need to acquire cathodoluminescence imagery for routine detrital zircon applications further increasing throughput and reducing cost. The utility of the measurement procedure is demonstrated by the measurement of samples previously characterised by LA‐MC‐ICP‐MS.     

Effects of AO and Pacific SSTA on severe droughts in Luanhe River basin,China

Natural Hazards - In the (re)insurance industry, the risk from natural hazards such as earthquakes or floods is quantified by models for natural catastrophes, also called NatCat models. One...     

Modeling reactive transport in sediments subject to bioturbation and compaction

Current bioturbation models are marked by confusion in their treatment of porosity. Different equations appear to be needed for different biodiffusion mechanisms, i.e., interphase mixing, where biological activity causes bulk mixing of sediment affecting both tracer and porosity profiles, versus intraphase mixing, where the solid components are intermixed, but the porosity is left unchanged. Another issue is whether the model depends upon the particle type with which tracers are associated, e.g., ¹³⁷Cs on small clay particles versus ²¹⁰Pb on larger grains. This uncertainty has lead to conflicting conservation equations for radiotracers, and in particular, to the question whether the porosity should be placed inside or outside of the differential term that governs the biodiffusive flux. We have reexamined this situation in the context of multiphase, multicomponent continuum theory. Most importantly, we prove that under the assumption of steady-state porosity, there exists only one correct form of the steady-state conservation equation for a radiotracer, regardless of biodiffusion mechanism and particle type, i.e.,

     

SIMS analyses on trace and rare earth elements in coexisting clinopyroxene and mica from minette mafic enclaves in potassic syenites crystallized under high pressures

Trace and rare earth element contents were determined by SIMS technique in clinopyroxene and mica crystals from minette lamprophyric enclaves in a potassic syenite host. This co-mingled system was crystallized at high pressures, which varied about 3–5 GPa, as indicated by the presence of K-clinopyroxenes and pyrope-rich garnet with measurable amounts of K₂O and Na₂O, among the near-liquidus phases. Major and trace element composition of these lamprophyric enclaves is quite similar to those observed in silica-rich lamproites, suggesting that similar sources were involved in their origin. In a general view, the concentrations of most trace and rare earth elements in clinopyroxene of the studied enclaves are higher than those referred to by other authors. Clinopyroxene/melt partition coefficient for most trace elements are close to determinations in alkali-basalts and lamproites from Leucite Hills, with considerable differences relative to Gaussberg lamproites. Furthermore, these partition data are completely different from those determined for potassic lavas crystallized under crustal pressures. Spidergrams for clinopyroxenes exhibit negative-Sr anomalies relative to LREE, which have been associated by most authors to crystallization under low-pressures, out of garnet stability field. The presence of pyrope together with K-clinopyroxene excludes such hypotheses for the studied enclaves. Y and HREE are concentrated in clinopyroxene, whilst the other trace elements have Kd<1. LIL elements, except Rb, have incompatible (Kd<1) behavior in phlogopite. The high partition coefficient for Nb (Kd>3) determined in the studied phlogopite is unusual in lamproites, lamprophyres, and basalts, but frequently observed in phlogopite from metasomatic mantle samples, as well as in acid magmas. This partition value may indicate the lack of other mineral phase with high partition for this element during crystallization, and may be enhanced by the liquid composition progressively closer to alkali feldspar, an unsuitable structure for six-coordinated cations. Ce/Yb, Rb/Sr, and Zr/Hf ratios in clinopyroxene and mica suggest that the minettic magma could produce the host Piquiri potassic syenite by fractional crystallization. This hypothesis is not consistent with Ba concentrations in clinopyroxene and mica, which suggest that a Ba-bearing phase (e.g. alkali feldspar) should be among the fractionated phases in order to produce the potassic syenites.     

Sur la mesure de l'intensité du champ magnétique terrestre et la distribution du magnétisme dans les aimants

The measurement of the horizontal component, H, of the geomagnetic field represents an important part of geomagneticians work from 1830 to the end of the 19th century. This measurement remained difficult at the required accuracy of ${10}^{\mathrm{?9}}\text{T}$ (1 nT or $1\gamma$), till the advent of proton and optical pumping magnetometers in geomagnetic observatories, around 1955. The measurement of H consisted in determining the mutual torque between two cylindrical magnets, by measuring either oscillation periods or angular deviations. Poisson was the first, indisputably, to propose the general principle of the measurement, in 1825. But Gauss, some years later (1832), successfully operated his famous oscillation–deviation method, described since then in all the elementary manuals of physics. The computation of the mutual torque depends on the tri-dimensional distribution of the magnetization in each one of the magnets. In the absence of an accurate-enough knowledge of these distributions, Poisson, Gauss, and their successors showed how to make the computations with a minimum number of hypotheses on them. Nevertheless physicists, in particular French ones, worked on the ‘distribution of magnetism’ in magnets; the first of them was Coulomb. We come back to this question through experiments conducted in the magnetic observatory of Chambon-la-Forêt, France. To cite this article: B. Leprêtre, J.-L. Le Mouël, C. R. Geoscience 337 (2005).     

Karsts polyphasés, faciès marins et continentaux dans le Paléocène de la partie orientale des Pyrénées fran?aises

In the Eastern part of French Pyrenees, the Cucugnan area (Southern Corbières) corresponded during the early/Mid-Paleocene (Danian/Selandian) to a narrow transitional zone between the sea to the South (Pyrenean Paleocene Trough) and the continent (fluvio-palustrine and lacustrine Vitrollian deposits) to the North. To the South, in the North-Pyrenean Zone, the polygenic marine breccias and the associated Dano-Selandian Globigerinid-bearing hemipelagites have been preserved within successive paleokarsts superimposed onto the carbonate substratum (ante-Albian). Four paleosurfaces are recognized, principally filled by marine internal sediments with proximal and distal facies. To the North, in the Sub-Pyrenean Zone, a continental foreland basin is characterized by four formations of variegated Microcodium-bearing marls and channelized conglomerates, separated by erosional paleosurfaces underlining well-marked unconformities. An event correlation (chronodiagrams) between the marine realm to the South and the continental realm to the North is proposed, using the successive paleosurfaces and the lithological sequences (same number within the two realms). Our paleogeographic reconstruction shows, to the North, the Lake of Cucugnan and, to the South, a calcareous mountainous zone broken by the juxtaposition of deep paleocanyons (eroded in a continental context) later converted into rias submitted to marine oscillations. Several palinspastic transects are reconstructed: they show the polyphase control of the Frontal North-Pyrenean Overthrust on the Paleocene sedimentation and the importance of the successive intra-Vitrollian compressions/ transpressions (phase fini-crétacée auct.) inducing, within the two juxtaposed realms, emersions, erosions and karstic features which give a very contrasted paleogeography during a period characterized by plate convergence and creation of steep topographies.Manuscrit reçu le 25 septembre 2003 Révision acceptée le 4 mai 2004     

Minor changes in surface-water fertility across the oceanic anoxic event 1d (latest Albian,SE France) evidenced by calcareous nannofossils

The latest Albian sediments deposited in the Vocontian basin in south-eastern France record the oceanic anoxic event (OAE) 1d, locally named the Breistroffer interval. They are represented by argillaceous marls and marls, containing organic matter (total organic carbon varying from 0.8 to 1%). Changes in calcareous nannofossil abundance and assemblage composition as well as macrofauna abundance, ichnofossil assemblage, and bioturbation intensity were analysed in order to evaluate the main palaeoenvironmental factors controlling the deposition of the OAE 1d sediments in this area. The pelagic carbonate production is limited and the carbonate fraction is predominantly of nektonic/benthic, and of allochthonous origin from carbonate platforms. The enrichment in organic carbon within the Breistroffer interval is weak and not associated with high surface-water productivity. The organic matter is mainly terrigenous. Its record is due to (1) a good preservation under dysoxic conditions within the sediments, and (2) a weak input of allochthonous carbonates. Eustatic fluctuations strongly influenced the variations of nannofossil and macrofauna abundances. Distinctive patterns in nannofossil assemblages and macrofauna abundances within the Breistroffer interval are also recognized, reflecting changes from mesotrophic to more oligotrophic conditions which are probably controlled by climate.