Composite magnetic anisotropy fabrics: experiments, numerical models and implications for the quantification of rock fabrics

Magnetic fabrics from rocks with multiple mineral-preferred orientations may have anisotropy ellipsoids whose shape and orientation arise from the addition of two or more component fabrics. Our numerical models and experiments demonstrate that such composite magnetic fabrics do not directly reflect the shapes and/or orientations of the individual mineral fabrics and we provide criteria for the recognition and interpretation of composite fabrics in natural rocks. These criteria include:

1. (1) the orientation of the maximum susceptibility axis is located at the intersection of two planar fabrics, and

2. (2) the shape of the susceptibility ellipsoid changes from oblate to prolate and the degree of anisotropy decreases, as the relative intensity of two planar component fabrics becomes equal and as the angle between the planar fabrics increases.

Composite magnetic fabrics are observed in the shales and slates of the Martinsburg Formation, Lehigh Gap, Pennsylvania. Modeling of the AMS (anisotropy of magnetic susceptibility) and ARMA (anhysteretic remanent magnetization anisotropy) behavior constrains the relative degree of anisotropy of the bedding-parallel and cleavage-parallel fabrics. In particular, ARMA model results allow a good estimate of magnetite fabric strength.

We conclude that, in the presence of composite magnetic fabrics, quantitative measures of finite strain in deformed rocks are limited by the ability to accurately determine the degree of anisotropy and relative susceptibility of each component fabric. Such determinations require knowledge of the mineral(s) that are responsible for the measured magnetic fabric and their behavior during deformation.     

Magnetite activities across the MgAl2O4-Fe3O4 spinel join,with application to thermobarometric estimates of upper mantle oxygen fugacity

The activity of Fe₃O₄ component in MgAl₂O₄-Fe₃O₄ spinels has been measured at 900° and 1000° C and 1 atm total pressure using a zirconia oxygen electrolyte. As previously reported for the dilute Fe₃O₄ concentration region (Mattioli and Wood 1986a), magnetite activity at 1000° C is greater than at 900° C at constant Fe₃O₄ mole fraction, for compositions across the MgAl₂O₄-Fe₃O₄ join between 20 and 80 mol% Fe₃O₄ component. The 1-atm solvus crest lies between 900° and 1000° C and, at 900° C the limbs are at Fe₃O₄ mole fractions of 0.2 and 0.6 approximately.Application of the O'Neill and Navrotsky (1983, 1984) cation distribution model indicates that the unusual activity — composition behavior of Fe₃O₄ is caused by changes in the equilibrium state of disorder of mixed MgAl₂O₄-Fe₃O₄ spinels relative to the disordered Fe₃O₄ standard state. In addition, both stoichiometric volumes (Mattioli et al. 1987) and activities across the MgAl₂O₄-Fe₃O₄ join suggest that short range order is significant for this binary. Excess free energy terms must be added to ideal Fe₃O₄ activities formulated from equilibrium cation distributions in complex MgAl₂O₄-Fe₃O₄ spinels in order to increase Fe₃O₄ activities to values consistent with observation and to generate the apparent region of immiscibility at 900° C.We have applied our activity data to the estimation of upper mantle spinel-lherzolite oxygen fugacities. We calculated that minimum 's are about 2 log units below the synthetic QFM buffer at 15 kbar total pressure for Fe₃O₄ concentration of 2 mol%, in a Cr-free spinel phase. If a preliminary calibration of an additional 25 mol% Fe²⁺-substitution as FeCr₂O₄ or FeAl₂O₄ component is incorporated into Fe₃O₄ activity, then olivine-orthopyroxene-spinel assemblages of depleted-Type 1-spinel-lherzolite xenoliths indicate 's close to QFM at 15 kbar. This is in good agreement with previous thermobarometric estimates and in sharp contrast to 1 atm intrinsic measurements near IW.     

Aperçu sur les amas sulfurés massifs des hercynides Marocaines

Massive sulfide deposits located on Hercynian islets of northwestern Morocco exhibit four main characteristics:

They are strata-bound massive pyrrhotite deposits mined for sulfur and/or base metals occasionally occurring as sulfides of workable grade.

Volcanic rocks with which these massive sulfide orebodies are associated are scarce, although always present as acid flows of submarine emissions of either rhyolitic or more often quartz-keratophyric nature. Later on, basic plutonics intruded the pelitic country rocks.

Stockworks underlying the massive sulfide orebodies are common, but not systematic. When present, they occur in siltite ± phyllite ± carbonate rocks at the wall of massive sulfide lenses. They consist of fissural disseminations transformed by epimetamorphic recrystallization and by one schistosity generally concordant with s₀.

Associated alterites and exhalites belong to three types, i.e., sericitite (or biotite-rich rock), chloritite, and/or chert (jasper).

Generally well located in a back-arc basin environment characterized by a two-phase geological history, i.e., “extension and volcanism, compression and metamorphism”, these volcano-sedimentary deposits exhibit distal features with regard to the volcanism coeval with their sedimentation. They are mostly linked with strongly reducing environmental properties entailing pyrrhotite and/or magnetite syngenetic deposition, whatever the iron activity.     

On the validity of the chapman-enskog description of the solar wind

The validity of the Chapman-Enskog method in the calculation of the heat conductivity of the solar wind is studied. The predictions of the Chapman-Enskog theory are compared with known results of rarefied gas kinetic theory. The results suggest that the use of the Chapman-Enskog theory to describe the transport processes in the solar wind is not strictly justified.     

Sixty volumes of the Journal du Conseil / ICES Journal of Marine Science

Article 1 of the ICES Convention of 1964 sets out the fundamentalpurposes of the Council and includes as the third and finalpoint: "to publish or otherwise disseminate the results of researchand investigations carried out under its auspices or to encouragethe publication thereof". Publication and dissemination of informationabout the living resources and their environment have been atthe heart of ICES from the first     

Toward a radiometric ice clock: uranium ages of the Dome C ice core

Ice sheets and deep ice cores have yielded a wealth of paleoclimate information based on continuous dating methods while independent radiometric ages of ice have remained elusive. Here we demonstrate the application of (²³⁴U/²³⁸U) measurements to dating the EPICA Dome C ice core based on the accumulation of ²³⁴U in the ice matrix from recoil during ²³⁸U decay out of dust bound within the ice. Measured (²³⁴U/²³⁸U) activity ratios within the ice generally increase with depth while the surface areas of the dust grains are relatively constant. Using a newly designed device for measuring surface area for small samples, we were able to estimate reliably the recoil efficiency of nuclides from dust to ice. The resulting calculated radiometric ages range between 80 ka and 870 ka. Measured samples in the upper 3100 m fall on the previously published age-depth profile. Samples in the 3200–3255 m section show a marked change from 723–870 ka to 85 ka indicating homogenization of the deep ice prior to resetting of the (²³⁴U/²³⁸U) age in the basal layers. The mechanism for homogenization is likely enhanced lateral ice flow due to high basal melting and geothermal heat flux.     

Cliff-top storm deposits on Banneg Island, Brittany, France: Effects of giant waves in the Eastern Atlantic Ocean

This study is based on the morphosedimentary analysis of the cliff-top storm deposits accumulated on the coast of Banneg Island located in the archipelago of Molène (Brittany, France). These CTSDs comprise large, tabular clasts quarried from the upper part of the cliff and the backing scoured platform by giant oceanic storm waves impacting directly the western coast of the island. An analysis of the distribution and the geomorphology of these accumulations were carried out using the DGPS topographic surveys. Most of the clasts are organised into imbricate boulder clusters or ridges deposited between 7.5 and 14.5 masl. 52 accumulations were inventoried from the north to the south of the island, representing a global volume of 1000 m³. The median size of the clasts calculated is equivalent to 0.8 × 0.6 × 0.4 m and a weight of 0.6 t. The largest one measuring 5.3 × 3.9 × 0.5 m (≈ 32 t) is located in the centre of the island (ridge #28). It has been deposited 14 m inland from the edge of the cliff at the elevation of 9 m. Sediment analysis shows that clast sizes become smaller with increasing distance from the shoreline, but there is no relationship between the sorting and the distance inland. A study of the hydrodynamic conditions inducing clast transport was undertaken by an analysis of the wave data from the 1989 to the 1990 winter storms. Models of wave runup indicate that their highest water levels may have reached up to 19 masl, 5 to 10 m higher than the top of the cliff. Submersion by giant storm waves has been more important and frequent in the centre and the south of the island. Wave data over the 1979 to the 2007 period shows that no events as powerful as those of the 1989 to the 1990 winter were recorded during the last 30 years. Yet, it appears that the 1979–1990 decade was characterized by important morphogeneous events while the following period (1990–2007) has experienced a sharp decrease in storm events. These variations could be attributed to the inversion from a negative towards a positive phase in the North Atlantic Oscillation index.     

Phase relationship between sea level and abrupt climate change

Direct traces of past sea levels are based on the elevation of old coral reefs at times of sea level highstands. However, these measurements are discontinuous and cannot be easily correlated with climate records from ice cores. In this study we show a new approach to recognizing the imprint of sea level changes in continuous sediment records taken from the continental slope at locations that were continuously submerged, even during periods of sea level lowstand. By using a sediment core precisely synchronized with Greenland ice cores, we were able to recognize major floods of the Mediterranean continental shelf over the past 270 kyr. During the last glacial period five flooding events were observed at the onset of the warmest Greenland interstadials. Consistent correspondence between warm climate episodes and eustatic sea level rises shows that these global flooding events were generated by pronounced melting of the Northern Hemisphere ice sheets, due to rapid intensification of Atlantic Meridional Overturning Circulation.The method described in this study opens a new perspective for inter-hemispheric synchronization of marine climate records if applied in other continental margins from the Southern Hemisphere or the equatorial regions.