210Pb and 137Cs dating methods in lakes: A retrospective study

²¹⁰Pb has been used for more than two decades to provide the geochronology of annually deposited sediments and to construct pollution histories. Evidence from some lakes suggests that this radionuclide may be adequately mobile to compromise dating reliability. This study provides one test of that possibility by comparing recent measurements of ²¹⁰Pb and trace metals to ones carried out more than 20 yrs in the past. ¹³⁷Cs dating is used to confirm sediment accumulation rates in the recent cores. In the three Connecticut, USA, lakes studied, sediment accumulation rates changed abruptly to higher values between 40-50 yrs ago (increasing by factors of 2.2, 2.9, and 3.0). In all three lakes, rates calculated from ²¹⁰Pb distributions both above and below this horizon agreed, within measurement uncertainty, in recent and older cores. Furthermore, when the older data were corrected for 20 yrs of burial, the changes in slope in ²¹⁰Pb distributions occurred at the same depth in each pair of cores. The depth of sharp peaks in concentrations of trace metals also matched. In general, this evidence supports the idea that sediments in these lakes have simply been buried, without significant diagenetic remobilization of ²¹⁰Pb and trace metals . Nevertheless, some important differences were also observed. For two of the three lakes, there was a significant difference in average sediment accumulation rate during the past 33 yrs as calculated from ¹³⁷Cs and ²¹⁰Pb in the recent cores. Most potential causes for this difference can be ruled out, and it appears that one of the two nuclides is remobilized compared to the other. There were also significant differences in the total inventories of both ²¹⁰Pb and trace metals (both up to 2 ×) between recent and older cores in some cases. This may be due to dissimilar sediment focusing, since it is not known for certain whether the new cores were collected at exactly the same sites as in the past.     

New perspectives on Mars’ crustal magnetic field

The planet Mars lacks, today, a planetary, dynamic magnetic field, but strong, intense, localized magnetic fields of lithospheric origin, one to two orders of magnitude larger than the terrestrial lithospheric field, are present. This lithospheric magnetic field is the result of magnetization processes in the presence of a magnetic dynamo and of demagnetization processes after the dynamo shutdown, such as impact or volcanoes. This crude scenario can be more accurately specified by interpreting global and local models of the current magnetic field of Mars. Some specific areas are studied, including the intensely magnetized Terra Sirenum, as well as the magnetic anomaly associated with Apollinaris Patera. Magnetic minerals could be of primary and/or secondary origin; this latter would imply an early hydration of a basaltic crust. A scenario, in which Mars experienced a major polar wander due to the Tharsis bulge, prior to the cessation of its dynamo, is proposed and discussed.     

Sources and history of heavy metal contamination and sediment deposition in Tivoli South Bay, Hudson River, New York

Persistent inorganic constitutents preserved in sediments of aquatic ecosystems record temporal variability of biogeochemical functioning and anthropogenic impacts.²¹⁰Pb and¹³⁷Cs dating techniques were used to study the past variations of heavy metals (Pb, Cu, and Zn) and accumulation rates of sediments for Tivoli South Bay, in the Hudson River National Estuarine Research Reserve ecosystem. South Bay, a tidal freshwater embayment of the Hudson, may play an important role in the sediment dynamics of this important river. The measured sedimentation rate range of 0.59 to 2.92 cm yr⁻¹ suggests that rapid accumulation occurred during the time period represented by the length of the cores (approximately the past 50 yr). Direct measurements of sediment exchange with the Hudson River reveal high variability in the sediment flux from one tidal cycle to the next. Net exchange does not seem to be adequate to explain sediment accumulation rates in the bay as measured by²¹⁰Pb and¹³⁷Cs. The difference may be supplied from upland streams or the Hudson River during storm events. Concentrations of the metals Pb, Cu and Zn were found to be well correlated with each other within individual cores at five of six sites tested. This suggests a common proximate source for the three metals at a specific site. The evidence is consistent with mixing in some environmental compartment before delivery to the bay. While metals self-correlate within individual cores, absolute concentrations, depth distribution patterns, and ratios of the metals to each other vary among the cores collected at different locations within the bay. Organic matter, Fe content, and particle size distribution of sediments do not account for the intercore variations in metal concentration. It is likely that cores collected from different sites may have derived metals from different sources, such as watershed streams and tidal exchange with the Hudson River.     

Phase changes and thermodynamic properties of CaTiO3. Spectroscopic data,vibrational modelling and some insights on the properties of MgSiO3 perovskite

The effect of pressure (up to 21 GPa at room temperature) and temperature (up to 1570 K at room pressure) on the Raman spectrum of CaTiO₃ is presented. No significant changes, which could be attributed to a major structural change, are observed in the spectra up to 22 GPa. The pressure shifts of the Raman modes can be related to a significant compression of the Ti-O bond. Discontinuous changes in the spectra upon heating may be related to phase changes observed by calorimetry and X-ray diffraction. The important temperature shifts of some low-frequency modes can be related to an increase in the Ti-O-Ti angle in agreement with the X-ray data showing a decrease of the structural distortion with increasing temperature. These data are compared to those available for MgSiO₃-perovskite and show that CaTiO₃ is a good structural analogue for MgSiO₃-perovskite. The present spectroscopic data are used to calculate the specific heat and entropy of CaTiO₃. The role of the low frequency modes in the calculations is emphasized. Good agreement is observed between calculated and experimentally determined values in the 0–1300 K temperature range. A similarly defined model is proposed for MgSiO₃-perovskite. It is found that the entropy lies between 57 and 64 J/mol/K at 298 K and between 190 and 200 J/mol/K at 1000 K in agreement with the values inferred from experimental equilibrium data. Finally we briefly discuss the values of the Grüneisen parameters of both perovskites inferred from macroscopic and microscopic data.     

Complete metamorphic cycle and long-lived anatexis in the c. 2.1 Ga Mistinibi Complex,Canada

Secular changes in the architecture, thermal state, and metamorphic style of global orogens are thought to have occurred since the Archean; however, despite widespread research, the driving mechanisms for such changes remain unclear. The Paleoproterozoic may prove to be a key era for investigating secular changes in global orogens, as it marks the earliest stage of an eon that saw the onset of modern-style global tectonics. The 2.1 Ga granulite-facies Mistinibi-Raude Domain (MRD), located in the Southeastern Churchill Province, Canada, offers a rare exposure of Paleoproterozoic high metamorphic grade supracrustal sequences (Mistinibi Complex, MC). Rocks from this domain were subjected to petrochronological investigations to establish P–T–t–X evolutions and to provide first order thermal state, burial and exhumation rates, and metamorphic gradients for the transient Paleoproterozoic times. To obtain comprehensive insight into the P–T–t–X evolution of the MRD, we used multi-method geochronology—Lu–Hf on garnet and U–Pb on zircon and monazite—integrated with detailed petrography, trace element chemistry, and phase equilibria modelling. Despite the extensive use of zircon and monazite as geochronometers, their behaviour in anatectic conditions is complex, leading to substantial ambiguity in interpreting the timing of prograde metamorphism. Our results indicate a clockwise metamorphic path involving significant melt extraction from the metasedimentary rocks, followed by cooling from >815°C to ~770°C at ~0.8 GPa. The timing of prograde burial and cooling from supra- to subsolidus conditions is constrained through garnet, monazite, and zircon petrochronology at 2,150–2,120 Ma and at 2,070–2,080 Ma, respectively. These results highlight long-lived residence of the rocks at mid-crustal supra-solidus conditions (55–70 Ma), with preserved prograde and retrograde supra-solidus monazite and zircon. The rocks record extremely slow burial rates (0.25–0.30 km/Ma) along a high metamorphic gradient (900–1,000°C/GPa), which appears symptomatic of Paleoproterozoic orogens. The MC did not record any significant metamorphism after 2,067 Ma, despite having collided with terranes that record high-grade metamorphism during the major 1.9–1.8 Ga Trans-Hudson orogeny. The MC would therefore represent a remnant of a local early Paleoproterozoic metamorphic infrastructure, later preserved as superstructure in the large hot Trans-Hudson orogen.     

A stepwise screening system to select storm-sensitive stalagmites: Taking a targeted approach to speleothem sampling methodology

A stepwise stalagmite sample screening process was applied in order to select a stalagmite as a sensitive recorder of recent tropical cyclone rainfall events near Belize. Field and laboratory criteria were combined in series, to screen out candidate stalagmites whose characteristics indicated lower sensitivity to stormwater infiltration. The approach described here was designed to increase the likelihood that selected stalagmites would increase the signal:noise ratio of the target phenomenon in the resulting proxy records. This four-stage method for sample selection may be an important methodological consideration for researchers attempting to use speleothems for stable isotope paleotempestology. Hallmarks of this approach include: (1) establishing a priori scientific targets, (2) applying sample criteria in the form of contra-indicators, and (3) organizing the sample screening protocol into a series of practical stages. The overall approach to stalagmite selection presented here supports cave conservation, and can be adapted readily by others in support of different scientific goals. It is hoped that other investigators will also publish field and laboratory sample selection schemes, as increased transparency will provide new information invaluable to replication efforts and to advancing the field of speleothem paleo-environmental studies.     

On a Non-local Parameterisation for Shear Turbulence and the Uniqueness of its Solutions

A non-local parameterisation of shear turbulence is proposed, which includes a dimensionless multiplicative constant as the sole tunable parameter. Analytical and numerical solutions in the case of plane Couette flow exhibit sheared velocity profiles with logarithmic behaviour near the boundaries, and the classical logarithmic flow profile is reproduced for a semi-infinite domain. We also prove that the families of analytical solutions obtained are locally unique: if the velocity is a strictly-increasing function of the distance from the boundary, a small perturbation of the velocity profile must be of the same functional form as the basic flow.     

An optimized use of limited ground based topographic data for river applications

A prime requirement for hydrological applications,such as sediment budgeting or numerical modelling,is that produced Digital Terrain Models(DTMs)accurately represent the shape of landforms,especially for river reaches where data are not homogeneous.DTM error is a function of data point measurement accuracy and density and also of the field survey strategy when limited amounts of data will be acquired.This paper aims to advance the importance of the field survey strategy for the specific,but common cases,where only limited topographic data will be available.This methodology is based on the idea that any feature can be properly described by a set of cross sections and breaklines describing both main and secondary directions of the flow.Then,a longitudinal linear interpolation can be applied to the defined homogeneous zones.This morphologically oriented(MO)method that includes data acquisition strategy and interpolation,was validated using a reference DTM derived from LiDAR measurements.An estimation of the uncertainties also is suggested based on the distance of the nearest point and the local slope using a geographically weighted regression.The proposed MO method is typically applicable to Alpine river reaches characterized by multiple channels that may always be underwater and not navigable such as an alternate bar system with secondary and transverse channels.     

Trophic importance of diatoms in an intertidal Zostera noltii seagrass bed: Evidence from stable isotope and fatty acid analyses

A current predominant paradigm emphasizes the role of epiphytic algae for invertebrates in most seagrass food webs. However, in some intertidal Zostera noltii beds, epiphyte biomass is very low compared to microphytobenthos and seagrass biomasses. We assessed the role of microphytobenthos in a temperate intertidal Z. noltii bed by combining stable isotope and fatty acid (FA) analyses on primary producers, composite sources — suspended particulate organic matter (SPOM) and sediment surface organic matter (SSOM) — and the main macrofaunal consumers. Z. noltii showed high δ¹³C (−9.9‰) and high 18:2(n-6) and 18:3(n-3) contents. Microphytobenthos was slightly more ¹³C-depleted (−15.4‰) and had high levels of diatom markers: 14:0, 16:1(n-7)c, 20:5(n-3). Low mean δ¹³C (−22.0‰) and large amounts of diatom and bacteria (18:1(n-7)c) markers indicated that SPOM was mainly composed of a mixture of fresh and decayed pelagic diatoms. Higher mean δ¹³C (−17.9‰) and high amounts of diatom FAs were found in SSOM, showing that microphytobenthic diatoms dominate. Very low percentages of 18:2(n-6) and 18:3(n-3) in consumers indicated a low contribution of Z. noltii material to their diets. Grazers, deposit and suspension-deposit feeders had δ¹³C close to microphytobenthos and high levels of diatom FAs, confirming that microphytobenthos represented the main part of their diet. Lower δ¹³C and higher amounts of flagellate FAs – 22:6(n-3) and 16:4(n-3) – in suspension feeders indicated that their diet resulted from a mixture of SPOM and microphytobenthos. These results demonstrate that invertebrates do not consume high amounts of seagrass and highlight the main role of benthic diatoms in this intertidal seagrass bed.