Competition between iron- and carbon-based colloidal carriers for trace metals in a freshwater assessed using flow field-flow fractionation coupled to ICPMS

Flow field-flow fractionation (FlFFF) coupled to an inductively coupled plasma mass spectrometer (ICPMS) has been used to determine the chemical composition of colloids from a freshwater sample as a function of size. Organic carbon and iron are the most abundant colloidal components, and are considered as the major carrier phases for other chemical elements present. The size distribution of organic carbon colloids shows a single peak with an estimated hydrodynamic diameter between 1 and 1.5 nm, while the iron colloids show a more complex distribution centred at larger colloid sizes with estimated hydrodynamic diameters up to 5 nm. The association of 32 trace elements with these two carrier colloids has been quantified by deconvolution analysis, and the resulting distributions are shown to be chemically consistent. The observed distributions are also shown to be broadly consistent with predictions from speciation modelling for the subset of 8 elements for which appropriate stability constants are available.     

Particle Size Distributions of Clay-rich Sediments and Pure Clay Minerals: A Comparison of Grain Size Analysis with Sedimentation Field-Flow Fractionation

Two clay-rich coastal sediment samples have been characterised together with three pure clays identified as major components of the sediment samples. The mineralogy of the sediments was determined by X-ray diffraction, and their bulk properties measured (organic carbon content, leachable iron and manganese, surface area and cation exchange capacity). A simple approach is used to model the properties of the sediments from those of their pure clay components. Good agreement is found for cation exchange capacity and specific surface area indicating that the clay minerals are the most important constituents influencing the sediments' surface properties. Particle size distributions were assessed by conventional grain size analysis, and also by Sedimentation Field-Flow Fractionation (SedFFF). These two approaches yield sharply differing size distributions; in particular, conventional grainsize analysis indicates a much greater proportion of submicron particles. Similar results are obtained from analysis of pure clays. The most likely reason for this is artifacts introduced in the unavoidable 1 m prefractionation used for SedFFF.     

Cryptic diversity and phylogeography of the island‐associated barnacle Chthamalus moro in Asia

Pleistocene glaciations were among the important historic events that shaped the population structures of marine organisms. Genetic studies of different marine fauna and flora have demonstrated the effect of Pleistocene glaciations on taxa that reside in marginal seas. However, how marine island species responded to Pleistocene glaciations remains relatively unstudied, especially in Asia. Genetic analyses based on the island‐associated barnacle Chthamalus moro collected from 14 sites in Asia reveal that C. moro comprises three distinct lineages, with COI divergence ranging from 3.9 to 8.3%. Population genetic analyses on respective lineages reveal signs of demographic expansion within the Pleistocene epoch at different times. The Ogasawara lineage, which has a more oceanic distribution, expanded the earliest, followed by the population expansion of the Ryukyu and Southern lineages that inhabit islands closer to the continent. The data suggest that the inhabitants of outer islands may have been less affected by Pleistocene glaciations than those that reside closer to the continent, as the former were able to maintain a large, stable, effective population size throughout the late Pleistocene.     

Abandoned,Lost and Discarded Fishing Gear from the Fishing Sector of Kerala,India

Ocean Science Journal - Abandoned, lost or otherwise discarded fishing gear (ALDFG) is rapidly becoming a major global environmental problem. In the present study, a survey of 390 fishermen...     

Water Content Ratio: An Effective Substitute for Liquidity Index for Prediction of Shear Strength of Clays

Undrained shear strength of saturated clays is a very important property in geo-technical engineering practice. Since the collection of undisturbed samples and testing the same is difficult task and time consuming process, any attempt to obtain correlations between shear strength and consistency limits would be highly desirable. Several attempts have been made in the past to correlate shear strength with Liquidity index. The computation of Liquidity index involves the value of plastic limit determined by Casagrande thread rolling method; but the determination of the same is relatively a difficult task in geotechnical engineering practice especially so in less plastic soils. It has been shown that a good linear correlation exists between log of shear strength and water content ratio (ratio of water content to liquid limit). With the help of numerous experimental results, it could be established that water content ratio could replace the well-known parameter liquidity index to predict shear strength. This enables to eliminate the determination of the plastic limit. The relation between water content ratio and liquidity index depends on the liquid limit to plastic limit ratio, irrespective of the geological origin of the soil.