A natural pyrolysis experiment — hopanes from hopanoic acids?

The formation or generation of hopanes are important processes during both the natural heating of organic-rich sediments and laboratory pyrolysis experiments. Molecular maturity parameters as well as the amounts (ng/g rock) of the C₃₁ hopanes and C₃₀–C₃₂ hopanoic acids were quantified in a Jurassic silty shale horizon (Isle of Skye, Scotland) as a function of distance from an igneous intrusion. The maturity profiles of the homohopanes and the hopanoic acids are comparable. There is also a correlation between the decreasing amounts of C₃₀–C₃₂ hopanoic acids and concomitant increases in C₂₉–C₃₁ hopanes suggesting that free hopanoic acids could be one potential source of hopanes in this particular horizon. Other possible sources could include hopanoic acids that are bound into the macromolecular fraction.     

Microbial control of mineral–groundwater equilibria:Macroscale to microscale

macroscale processes that perturb general groundwater chemistry and therefore mineral–water equilibria; and microscale interactions, where attached organisms locally perturb mineral–water equilibria, potentially releasing limiting trace nutrients from the dissolving mineral. In the contaminated unconfined glacio-fluvial aquifer near Bemidji, Minnesota, USA, carbonate chemistry is influenced primarily at the macroscale. Under oxic conditions, respiration by native aerobic heterotrophs produces excess carbon dioxide that promotes calcite and dolomite dissolution. Aerobic microorganisms do not colonize dolomite surfaces and few occur on calcite. Within the anoxic groundwater, calcite overgrowths form on uncolonized calcite cleavage surfaces, possibly due to the consumption of acidity by dissimilatory iron-reducing bacteria. As molecular oxygen concentration increases downgradient of the oil pool, aerobes again dominate and residual hydrocarbons and ferrous iron are oxidized, resulting in macroscale carbonate-mineral dissolution and iron precipitation. Feldspars, in contrast, weather exclusively at the microscale near attached microorganisms, principally in the anoxic region of the plume. Native organisms preferentially colonize feldspars that contain trace phosphorus as apatite inclusions, apparently as a consequence of the low P concentration in the groundwater. These feldspars weather rapidly, whereas nearby feldspars without trace P are uncolonized and unweathered. Feldspar dissolution is accompanied by the precipitation of secondary minerals, sometimes on the bacterial cell wall itself. These observations suggest a tightly linked biogeochemical system whereby microbial processes control mineral diagenesis at many scales of interaction, and the mineralogy and mineral chemistry influence microbial ecology. Only the macroscale interaction, however, is easily observable by standard geochemical methods, and documentation of the microscale interactions requires microscopic examination of microorganisms on mineral surfaces and the locally intense diagenetic reactions that result. Received, May 1999/Revised, October 1999/Accepted, October 1999     

Early Mississippian sandy siltstones preserve rare vertebrate fossils in seasonal flooding episodes

Flood‐generated sandy siltstones are under‐recognised deposits that preserve key vertebrate (actinopterygians, rhizodonts, and rarer lungfish, chondrichthyans and tetrapods), invertebrate and plant fossils. Recorded for the first time from the lower Mississippian Ballagan Formation of Scotland, more than 140 beds occur throughout a 490 m thick core succession characterised by fluvial sandstones, palaeosols, siltstones, dolostone ‘cementstones’ and gypsum from a coastal–alluvial plain setting. Sandy siltstones are described as a unique taphofacies of the Ballagan Formation (Scotland, UK); they are matrix‐supported siltstones with millimetre‐sized siltstone and very fine sandstone lithic clasts. Common bioclasts include plants and megaspores, fish, ostracods, eurypterids and bivalves. Fossils have a high degree of articulation compared with those found in other fossil‐bearing deposits, such as conglomerate lags at the base of fluvial channel sandstones. Bed thickness and distribution varies throughout the formation, with no stratigraphic trend. The matrix sediment and clasts are sourced from the reworking of floodplain sediments including desiccated surfaces and palaeosols. Secondary pedogenic modification affects 30% of the sandy siltstone beds and most (71%) overlie palaeosols or desiccation cracks. Sandy siltstones are interpreted as cohesive debris flow deposits that originated by the overbank flooding of rivers and due to localised floodplain sediment transport at times of high rainfall; their association with palaeosols and desiccation cracks indicates seasonally wet to dry cycles throughout the Tournaisian. Tetrapod and fish fossils derived from floodplain lakes and land surfaces are concentrated by local erosion and reworking, and are preserved by deposition into temporary lakes on the floodplain; their distribution indicates a local origin, with sediment transported across the floodplain in seasonal rainfall episodes. These deposits are significant new sites that can be explored for the preservation of rare non‐marine fossil material and provide unique insights into the evolution of early terrestrial ecosystems.     

Estimation of Biodegradation Rates Using Respiration Tests During In Situ Bioremediation of Weathered Diesel NAPL

Respiration tests were carried out during a seven month bioremediation field trial to monitor biodegradation rates of weathered diesel non-aqueous phase liquid (NAPL) contaminating a shallow sand aquifer. Multiple depth monitoring of oxygen concentrations and air-filled porosity were carried out in nutrient amended and nonamended locations to assess the variability of degradation rate estimates calculated from respiration tests.
The field trial consisted of periodic addition of nutrients (nitrogen and phosphorus) and aeration of a 100 m² trial plot. During the bioremediation trial, aeration was stopped periodically, and decreases in gaseous oxygen concentrations were logged semi-continuously using data loggers attached to recently developed in situ oxygen probes placed at multiple depths above and within a thin NAPL-contaminated zone. Oxygen usage rate coefficients were determined by fitting zero-and first-order rate equations to the oxygen concentration reduction curves, although only zero-order rates were used to calculate biodegradation rates. Air-filled porosity estimates were found to vary by up to a factor of two between sites and at different times.
NAPL degradation rates calculated from measured air-filled porosity and oxygen usage rate coefficients ranged up to 69 mg kg^-1 day^-1. These rates are comparable to and higher than rates quoted in other studies, despite the high concentrations and weathered state of the NAPL at this test site. For nutrient-amended sites within the trial plot, estimates of NAPL degradation rates were two to three times higher than estimates from nonamended sites. Rates also increased with depth.     

South Australian rainfall variability and climate extremes

Rainfall extremes over South Australia are connected with broad-scale atmospheric rearrangements associated with strong meridional sea surface temperature (SST) gradients in the eastern Indian Ocean. Thirty-seven years of winter radiosonde data is used to calculate a time series of precipitable water (PW) and convective available potential energy (CAPE) in the atmosphere. Principle component analysis on the parameters of CAPE and PW identify key modes of variability that are spatially and seasonally consistent with tropospheric processes over Australia. The correlation of the leading principle component of winter PW to winter rainfall anomalies reveal the spatial structure of the northwest cloudband and fronts that cross the southern half of the continent during winter. Similarly the second and third principle components, respectively, reveal the structures of the less frequent northern and continental cloudbands with remarkable consistency. 850 hPa-level wind analysis shows that during dry seasons, anomalous offshore flow over the northwest of Australia inhibits advection of moisture into the northwest, while enhanced subsidence from stronger anticyclonic circulation over the southern half of the continent reduces CAPE. This coincides with a southward shift of the subtropical ridge resulting in frontal systems passing well to the south of the continent, thus producing less frequent interaction with moist air advected from the tropics. Wet winters are the reverse, where a weaker meridional pressure gradient to the south of the continent allows rain-bearing fronts to reach lower latitudes. The analysis of SSTs in the Indian Ocean indicate that anomalous warm (cool) waters in the southeast Indian Ocean coincide with a southward (northward) shift in the subtropical ridge during dry (wet) seasons.     

Asset Management and Safety Assessment of Levees and Earthen Dams Through Comprehensive Real-Time Field Monitoring

Assessing the health of and maintaining civil infrastructure has been an increased concern in the wake of natural disasters such as Hurricane Katrina in 2005 and the summer 2007 flood events in the UK. The variability of properties within geotechnical systems makes predictions of soil behavior extremely difficult, especially when soil models are not calibrated with field-measured performance. Unfortunately the current state of the art in geotechnical system health assessment is either based on very expensive monitoring systems for real-time information or on periodic measurement of ground surface displacements. Accordingly, a need has arisen for a system capable of in situ, real-time monitoring of levees, embankments, and other earthen structures. The work presented herein highlights the development of novel, affordable sensing technologies for use in a framework to monitor, manage and ensure the safety of geotechnical infrastructure. MEMS (micro-electro-mechanical systems)-based in-place inclinometer system, Measurand’s ShapeAccelArray (SAA), is now established as a sensing tool for simultaneous measurement of 3D soil acceleration and 3D ground deformation up to a depth of one hundred meters, with an accuracy of ±1.5 mm per 30 m. Each sensor array is connected to a wireless sensor node to enable real-time monitoring as well as remote sensor configuration. This system is now being further developed to include digitally integrated pore pressure measurement in the form of vibrating wire piezometers equipped with microprocessors (called SAAPs). The SAAPs are able to convert vibrating wire data to digital data downhole, and they integrate easily into the SAA system. In situ testing was conducted in a levee in England subjected to significant tidal loading (up to 6 m of fluctuation during spring tides) through collaboration with the European Union’s UrbanFlood project. In addition to the SAAs and SAAPs installed in three sections of the levee, the site was also instrumented with other sensors from Alert Solutions and TenCate, providing values for comparison. The likelihood of this levee to experience deformation and the density of instrumentation installed in the bank made this the ideal location to test the new SAAP system. The additional insight into subsurface behavior provided by the SAAPs is integral in the development of a comprehensive system for monitoring and management of civil infrastructure. The preliminary testing indicates the suitability of this new multi-parameter system for inclusion in a multi-scale monitoring and health assessment framework, which will be implemented in New Orleans, LA in 2012.     

Ostracods: The ultimate survivors

Ostracods are tiny crustacean arthropods just a few millimetres long, with a bivalved carapace made of calcium carbonate that covers the whole body, and into which the animal can retreat from the world outside. Because of their diminutive size they are largely overlooked as fossils, but they have a fascinating history. Silent witnesses to life in the seas since the time of trilobites, they have a fossil record extending back to the Early Ordovician, and possibly the Cambrian. Ostracods have survived nearly 500 million years of Earth history including the ‘big five’ mass extinctions of the Phanerozoic Eon; they are true survivors. They are almost perfectly adapted for the aquatic environments in which they live, and can be found from the ocean abyssal plains to damp leaf litter. The ostracod carapace is a triumph of biological engineering that has been re‐configured into myriad different morphologies according to environment. Streamlined and agile species plough through the ocean water column, sometimes reaching a ‘giant’ size of a centimetre in length, whilst their tinier sea bottom cousins make elaborately ornamented carapaces to withstand the pressures of living at the seabed, or shape their carapaces into forms that facilitate burrowing into sediment. Ostracods are key components of aquatic ecosystems. As primary consumers they are food for larger animals both in seabed and planktonic habitats, and they recycle much of the organic detritus produced by larger animals and plants. Delve into the history of ostracods and it is possible to find pioneers who triumphed in the plankton, early colonisers of terrestrial aquatic ecosystems, and ostracods that literally conquered the land. And in more recent times, ostracods have even hitched rides on rockets into space.     

A regional response in mean westerly circulation and rainfall to projected climate warming over Tasmania, Australia

Coupled ocean–atmosphere general circulation models (GCMs) lack sufficient resolution to model the regional detail of changes to mean circulation and rainfall with projected climate warming. In this paper, changes in mean circulation and rainfall in GCMs are compared to those in a variable resolution regional climate model, the Conformal Cubic Atmospheric Model (CCAM), under a high greenhouse gas emissions scenario. The study site is Tasmania, Australia, which is positioned within the mid-latitude westerlies of the southern hemisphere. CCAM projects a different response in mean sea level pressure and mid-latitude westerly circulation to climate warming to the GCMs used as input, and shows greater regional detail of the boundaries between regions of increasing and decreasing rainfall. Changes in mean circulation dominate the mean rainfall response in western Tasmania, whereas changes to rainfall in the East Coast are less related to mean circulation changes. CCAM projects an amplification of the dominant westerly circulation over Tasmania and this amplifies the seasonal cycle of wet winters and dry summers in the west. There is a larger change in the strength than in the incidence of westerly circulation and rainfall events. We propose the regional climate model displays a more sensitive atmospheric response to the different rates of warming of land and sea than the GCMs as input. The regional variation in these results highlight the need for dynamical downscaling of coupled general circulation models to finely resolve the influence of mean circulation and boundaries between regions of projected increases and decreases in rainfall.