Arsenic Control During Aquifer Storage Recovery Cycle Tests in the Floridan Aquifer

Implementation of aquifer storage recovery (ASR) for water resource management in Florida is impeded by arsenic mobilization. Arsenic, released by pyrite oxidation during the recharge phase, sometimes results in groundwater concentrations that exceed the 10 µg/L criterion defined in the Safe Drinking Water Act. ASR was proposed as a major storage component for the Comprehensive Everglades Restoration Plan (CERP), in which excess surface water is stored during the wet season, and then distributed during the dry season for ecosystem restoration. To evaluate ASR system performance for CERP goals, three cycle tests were conducted, with extensive water‐quality monitoring in the Upper Floridan Aquifer (UFA) at the Kissimmee River ASR (KRASR) pilot system. During each cycle test, redox evolution from sub‐oxic to sulfate‐reducing conditions occurs in the UFA storage zone, as indicated by decreasing Fe²⁺/H₂S mass ratios. Arsenic, released by pyrite oxidation during recharge, is sequestered during storage and recovery by co‐precipitation with iron sulfide. Mineral saturation indices indicate that amorphous iron oxide (a sorption surface for arsenic) is stable only during oxic and sub‐oxic conditions of the recharge phase, but iron sulfide (which co‐precipitates arsenic) is stable during the sulfate‐reducing conditions of the storage and recovery phases. Resultant arsenic concentrations in recovered water are below the 10 µg/L regulatory criterion during cycle tests 2 and 3. The arsenic sequestration process is appropriate for other ASR systems that recharge treated surface water into a sulfate‐reducing aquifer.     

Diatom-inference models for acid neutralizing capacity and nitrate based on 41 calibration lakes in the Sierra Nevada, California, USA

We investigated relationships among modern diatom species composition and physical and chemical characteristics of high-elevation lakes of the Sierra Nevada (California), to develop transfer functions that can be used to infer historic lake conditions. Data were collected from 50 lakes in National Parks and Forests of the central and southern Sierra Nevada. Multivariate statistical methods revealed that acid neutralizing capacity (ANC) and nitrate accounted for significant variation in diatom taxa. A training set with 242 modern diatom taxa from a subset of 41 lakes was used to develop transfer functions for ANC and nitrate using weighted averaging techniques. ANC and nitrate calibration ranges were 23.0–137 μEq/L and 0.18–9.5 μM, respectively. Coefficients of determination for the models were: ANC: R² = 0.76, and R _jackknife ²  = 0.44; NO₃: R² = 0.67, and R _jackknife ²  = 0.27. The ANC model was applied to the top 50 cm of sediments in Moat Lake to reconstruct ANC from ca. AD 350 to 2005. The reconstruction suggests that ANC declined by about 40 % (101–60 μEq/L) between the 1920s and the 1960s and then recovered to pre-1920s levels during 1980–2000. The magnitude of this ANC excursion was the largest observed during the past 1,600 years. We hypothesize that temporal variations in ANC were influenced by: (1) changes in rates of acid deposition, especially nitric acid and (2) variations in the timing and magnitude of snowmelt runoff.     

Glacier retreat and landform production on an overdeepened glacier foreland: the debris‐charged glacial landsystem at Kvíárjökull,Iceland

Glacier recession and landform development in a debris‐charged glacial landsystem characterized by an overdeepening is quantified using digital photogrammetry, digital elevation model (DEM) construction and mapping of the Icelandic glacier Kvíárjökull for the period 1945–2003. Melting of ice‐cores is recorded by surface lowering rates of 0·8 m yr^–1 (1945–1964), 0·3 m yr^–1 (1964–1980), 0·015 m yr^–1 (1980–1998) and 0·044 m yr^–1 (1998–2003). The distribution/preservation of pushed and stacked ice‐cored moraine complexes are determined by the location of the long‐term glacial drainage network in combination with retreat from the overdeepening, into which glacifluvial sediment is being directed and where debris‐rich ice masses are being reworked and replaced by esker networks produced in englacial meltwater pathways that bypassed the overdeepening and connected to outwash fans prograding over the snout. Recent accelerated retreat of Kvíárjökull, potentially due to increased mass balance sensitivity, has made the snout highly unstable, especially now that the overdeepening is being uncovered and the snout flooded by an expanding pro‐glacial, and partially supraglacial, lake. This case study indicates that thick sequences of debris‐charged basal ice/controlled moraine have a very low preservation potential but ice‐cored moraine complexes can develop into hummocky moraine belts in de‐glaciated terrains because they are related to the process of incremental stagnation, which at Kvíárjökull has involved periodic switches from transport‐dominant to ablation‐dominant conditions. Glacier recession is therefore recorded temporally and spatially by two suites of landforms relating to two phases of landform production which are likely typical for glaciers occupying overdeepenings: an early phase of active, temperate recession recorded by push moraines and lateral moraines and unconfined pro‐glacial meltwater drainage; and a later phase of incremental stagnation and pitted outwash head development initiated by the increasing topographic constraints of the latero‐frontal moraine arc and the increasing importance of the overdeepening as a depo‐centre. Copyright © 2012 John Wiley & Sons, Ltd.     

Mechanistic studies on the decomposition of carbon suboxide in a cometary ice analog

A cometary ice analog sample consisting primarily of carbon suboxide ice (C₃O₂) was produced from the irradiation of its precursor, carbon monoxide. This carbon suboxide sample was subjected to irradiation with energetic electrons at 10 K to simulate the interaction of carbon suboxide-rich cometary analog ices with ionizing radiation. The destruction of carbon suboxide as well as the production of the primary degradation products, dicarbon monoxide (C₂O), and carbon monoxide (CO), were monitored quantitatively by infrared spectroscopy in situ; the gas phase was simultaneously sampled via quadrupole mass spectrometry. A kinetic model was produced to help explain the decomposition kinetics of carbon suboxide in cometary ices and to infer the underlying reaction mechanisms.     

Comparative Study of Sand Porosity and a Technique for Determining Porosity of Undisturbed Marine Sediment

Porosity is a fundamental property of marine sediment from which wet bulk density can be easily determined and used in a variety of geoacoustic, geotechnical, and sedimentological studies, analyses, and models. However, methods of sampling marine sands suffer from the common problem of core disturbance making the in situ porosity difficult to obtain. Embedding the sediment within an epoxy resin matrix will minimize the disturbance to the microfabric and preserve the in situ sedimentary structure for subsequent study. Image analysis can then be used on thin sections to study the microfabric and porometry. A comprehensive review and analysis of published data on the porosity of predominantly clean sands has been completed and a simple, accurate, and nondestructive technique is described for preparing and measuring the porosity of marine sediment (siliciclastic sand) that has been infiltrated aboard ship immediately upon sample collection and chemically fixed and infiltrated with epoxy shortly thereafter. The average porosity of 36 samples of marine sand collected offshore Fort Walton Beach, Florida, and embedded with resin was determined to be 41.30%. From the review of published data the average porosity of sand was determined to be 37.7%, 42.3%, and 46.3% for packed, natural (in situ), and loose packing conditions, respectively, for a range of sorting coefficients and grain sizes.     

Mississippi prodelta crusts: A clay fabric and geotechnical analysis

Abstract

"Crust”; zones, as defined by shear strength profiles, have been delineated in Mississippi prodelta sediments since the advent of the remote wire‐line probe. Attempts to map the distribution of the “crust”; on the prodelta have been hampered by sparsity of in situ measurements and its apparent lateral discontinuity. Evidence based on clay fabric, geotechnical properties, and the location of selected cores within certain geomorphic zones, suggests the “crusts”; are associated with zones of shearing during an episode of submarine sediment movement on the prodelta.

The clay fabric within the “crust”; zone differs from that found above and below in the high‐porosity sediments. A noticeable degree of clay platelet preferential alignment is characteristic of sediments within the “crust.”; This preferred orientation occurs as localizations rather than as an overall alignment of all the particles. The clay fabric of the higher‐porosity sediments above and below the “crust”; is typified by randomly arranged clay particles and domains, sharing edge‐to‐face contacts which create an open framework. Apparent increases in the coarse silt fraction in the “crust”; zone were observed initially in scanning electron and transmission electron micrographs and later confirmed by grain size analysis. The presence of this silt apparently contributes to the increase in shear strength within the “crust.”; Clay particle arrangement in close proximity to these larger grains is modified in such a manner as to reduce water contents. Transmission electron microscopy and scanning electron microscopy observations of the “crust”; reveal that the void ratio decreases, resulting in a concomitant reduction in the water content as reflected in the geotechnical properties profiles. The type of fabric exhibited by the “crust”; suggests a remolding and dewatering of initially porous silty clay sediments in response to shear stresses operating on the prodelta.

Core samples were recovered from sediments exhibiting a “crust”; in areas identified by other researchers as unstable, based on seismic and acoustic profiles and sidescan sonar records. The prodelta has been modified by a peripheral mudflow at the location where the cores were collected for this study.     

In situ U-Pb, O and Hf isotopic compositions of zircon and olivine from Eoarchaean rocks, West Greenland: New insights to making old crust

The sources and petrogenetic processes that generated some of the Earth’s oldest continental crust have been more tightly constrained via an integrated, in situ (U-Pb, O and Hf) isotopic approach. The minerals analysed were representative zircon from four Eoarchaean TTG tonalites and two felsic volcanic rocks, and olivine from one harzburgite/dunite of the Itsaq Gneiss Complex (IGC), southern West Greenland. The samples were carefully chosen from localities with least migmatisation, metasomatism and strain. Zircon was thoroughly characterized prior to analysis using cathodoluminescence, scanning electron, reflected and transmitted light imaging. The zircon from all but one sample showed only minor post-magmatic recrystallisation. ²⁰⁷Pb/²⁰⁶Pb dating of oscillatory-zoned zircon using SHRIMP RG (n = 142) indicates derivation of the felsic igneous rocks from different batches of magma at 3.88, 3.85, 3.81, 3.80 and 3.69 Ga.Analyses of ¹⁸O/¹⁶O compositions of olivine from a harzburgite/dunite (n = 8) using SHRIMP II in multi-collector mode, indicate that the oxygen isotopic composition of this sample of Eoarchaean mantle (δ¹⁸O_Ol = 6.0 ± 0.4‰) was slightly enriched in ¹⁸O, but not significantly different from that of the modern mantle. Zircon δ¹⁸O measurements from the six felsic rocks (n = 93) record mean or weighted mean compositions ranging from 4.9 ± 0.7‰ to 5.1 ± 0.4‰, with recrystallised domains showing no indication of oxygen isotopic exchange during younger tectonothermal events. δ¹⁸O_Zr compositions indicate that the primary magmas were largely in equilibrium with the mantle or mantle-derived melts generated at similar high temperatures, while calculated tonalite δ¹⁸O_WR compositions (6.7-6.9‰) resemble those of modern adakites.LA-MC-ICPMS zircon ¹⁷⁶Hf/¹⁷⁷Hf analyses were obtained from six samples (n = 122). Five samples record weighted mean initial ε_Hf compositions ranging from to 0.5 ± 0.6 to −0.1 ± 0.7 (calculated using λ¹⁷⁶Lu = 1.867 × 10⁻¹¹ yr⁻¹), while one sample records a composition of 1.3 ± 0.7, indicating the magmas were generated from a reservoir with a time averaged, near chondritic Lu/Hf. The derivation of TTG magmas from a chondritic Lu/Hf source implies either that there was not voluminous continental crustal growth nor major mantle differentiation leading to Lu/Hf fractionation during the Hadean or Eoarchaean, or alternatively that rapid recycling of an early formed crust allowed the early mantle to maintain a chondritic Lu/Hf.Previous studies have demonstrated that ancient TTG rocks were mostly produced by dehydration melting of mafic rocks within the stability field of garnet, probably in flatly-subducted or buried oceanic crust. The oxygen isotopic signatures measured here at high spatial resolution allow the source materials to be better defined. Melting of a mixed mafic source consisting of ∼80% unaltered gabbro (δ¹⁸O_WR = 5.5‰) with ∼20% hydrothermally altered gabbro/basalt (δ¹⁸O_WR = 4.0‰) would produce tonalite magmas within the average compositional range observed. ¹⁸O-enriched components such as altered shallow basaltic oceanic crust and pelagic or continental sediments were not present in the sources of these TTG melts. The absence of high ¹⁸O signatures may indicate either the rarity of low temperature altered sediments, or their effective removal from the down-going slab.     

Likely Population-Level Effects of Contaminants on a Resident Estuarine Fish Species: Comparing <Emphasis Type="Italic">Gillichthys mirabilis</Emphasis> Population Static Measurements and Vital Rates in San Francisco and Tomales Bays

Gillichthys mirabilis population static measurements (abundance, age, and size class structures) and vital rates (growth, mortality, recruitment) were monitored on an annual basis from 2002 to 2007. Population-level metrics were used to gauge habitat quality at two study sites (a contaminated site and a reference site) in two large northern California estuaries (San Francisco and Tomales Bays). San Francisco Bay populations exhibited slower growth and higher mortality rates and contained higher amounts of contaminants than Tomales Bay. Recruitment rates were highest at contaminated sites (Stege Marsh and Walker Creek) in 3 years out of 5 years, suggesting low adult survival. This study suggests that population-level effects on a residential fish may be attributed to estuarine contamination on the US Pacific coast.     

Earth science training and development in Africa: a United Kingdom perspective

The paper discusses earth science training and development in Anglophone Africa, focusing particularly on support to geological survey organisations (GSOs). A distinction is drawn between ‘education’ and ‘training’, the latter used here in a vocational sense. Both are part of a continuing process of career development for earth scientists. First degree level education underpins all subsequent training. The onus for the latter lies with the employers, which need to develop appropriate training programmes for their staff that are compatible with an individual's career development and their own organisations' needs. There are relatively few graduate employees as a percentage of total staff in most African GSOs compared with GSOs elsewhere in the world and the experience of many of the younger scientists may be limited. This, and the often limited resources available, indicate a continuing need for support through development and institutional strengthening programmes. The main approaches to training and development are outlined and examples are given of some applications of these approaches. The training providers include ‘western’ and former Soviet earth science institutions, organisations such as the Association of Geoscientists in Development, and geological societies such as the Geological Society of Africa. The changing emphasis of developing country technical assistance requirements is reviewed. These include a shift from the leader-trainee approach by the provider to an advisory approach. The encouraging emergence of cross-border and regional training and development programmes within Africa is noted.