Iodine chemistry in deep anoxic basins and overlying waters of the Mediterranean Sea

Iodate (IO₃⁻) is the predominant dissolved species of iodine in the oxygenated waters of the Mediterranean Sea. Iodide (I⁻) is present in significant quantities (up to 65 nM) in oxygenated waters in the photic zone and near the interface above the anoxic and saline Bannock Basin. Lesser quantities of I⁻ (< 10 nM) are found throughout the rest of the oxic water column. An additional unidentified dissolved iodine species is present immediately above the anoxic interface.Total dissolved iodine (ΣI) increases dramatically across the seawater/brine interface. Part of this increase is undoubtedly the result of the dissolution of iodine-rich evaporites during formation of the brine bodies at the Tyro and Bannock Basins. The vertical distribution of ΣI and other dissolved chemical species (particularly PO₄³⁻) in the Bannock Basin brine, however, suggests an additional, present-day, diagenetic source of dissolved iodine to the brine. Based on the increase in the concentration of the most soluble major ions across the seawater/brine interface, 5–7 μM of the 11.5-μM increase in ΣI concentration must be attributed to diagenesis.     

Interactive 3-D computation of fault surfaces using level sets

Deformable implicit surfaces, implemented with level set methods, have demonstrated a great potential in the computational sciences for applications such as modeling, simulation, and segmentation. They allow implicit handling of complex topologies deformed by operations where large changes can occur without destroying the level set representation. The use of level set techniques for the computation and segmentation of plane-like and high positive curvature features is nontrivial. We present a technique for representing and extracting fault surfaces from 3-D seismic attribute data such that 2-manifolds can be interactively computed and segmented. We present our approach as an interactive workflow that generates highly accurate fault surfaces.     

Regional development in the United States during the 1980s: population redistribution and economic restructuring

The reduction of the rate of growth of the Brazilian population from 3% in the 1960s to 2% by 1993 resulted from a significant reduction of fertility. According to the 1986 national maternal-child health and family planning survey (PNSMIPF) results, 43.3% of women were using some type of contraception: 65.6% of married or cohabiting women. Women relied most on sterilization (17.2%), followed by oral contraceptives (OCs) (17%), the rhythm method (2.8%), the condom (1.1%), and others (5.2%). Only in the south was OC use more prevalent (28.5%) than sterilization (12.2%). The proportion of sterilization reached 27.8% in the north/center-east urban regions. In urban areas sterilization averaged 18.7% vs. 12.7% in rural areas. 26.9% of currently married women in the age range of 15-44 years had been sterilized. A 1990 international estimation indicated that the proportion of sterilization amounted to 36.9% in China, 30.95 in India, 29.7% in Brazil, 47.6% in South Korea, 30.4% in Thailand, and 36.5% in the Dominican Republic. The 1986 PNSMIPF survey also indicated that sterilized women were better informed than other women about contraception. 75% of the former had used OCs, 5% had used the diaphragm, 3% the IUD, 30% the condom, and 35% coitus interruptus at one time or other. The sterilized women had an average of 1.7 more children than those who were using other methods of contraception. 48.6% of women were sterilized before the age of 30, when they had had an average of 3.6 children. 66.6% of the sterilized women who had given birth before the age of 20 had 4 or more live births as compared to 5.9% of sterilized women aged 30 with the same number of children. 47% of women without any schooling were using some kind of contraception vs. 77% of those who had completed secondary school. A multivariate analysis also showed that the age of the mother, the number of live births, the educational status of the mother, and family income were positively correlated with sterilization.     

The partial molar volume, thermal expansivity, and compressibility of H2O in NaAlSi3O8 liquid: new measurements and an internally consistent model

The molar volumes of 19 hydrous albitic liquids (1.9 to 6.1 wt% H₂O^total) were determined at one bar and 505–765 K. These volume data were derived from density measurements on hydrous glasses at 298 K, followed by measurements of the thermal expansion of each glass from 298 K to its respective glass transition temperature. The technique exploits the fact that the volume of a glass is equal to that of the corresponding liquid at the limiting fictive temperature (T _f′), and that T _f′ can be approximated as the temperature near the onset of the rapid increase in thermal expansion that occurs in the glass transition interval. The volume data of this study were combined with available volume data for anhydrous, Na₂O-Al₂O₃-SiO₂ liquids to derive the partial molar volume (±1) of the H₂O component in an albitic melt at ∼565 K and one bar. To extend the determination of to higher temperatures and pressures, the molar volumes of the hydrous albitic liquids determined in this study were combined with those measured by previous authors at 1023–1223 K and 480–840 MPa, leading to the following fitted values (±1) at 1673 K and one bar: (±0.46)×10⁻³ cm⁻³/mol-K, and dVˉ ^H ₂ ^{O total} /dP=−3.82 (±0.36)×10⁻⁴ cm³/mol-bar. The measured molar volumes of this study and those of previous authors can be recovered with a standard deviation of 0.5%, which is within the respective experimental errors. There is a significant difference between the values for derived in this study as a function of temperature and pressure and those obtained from an existing polynomial, primarily caused by the previous absence of accurate density measurements on anhydrous silicate liquids. The coefficients of thermal expansion (=4.72×10⁻⁴/K) and isothermal compressibility ( _T =1.66×10⁻⁵/bar) for the H₂O component at 1273 K and 100 MPa, indicate that H₂O^total is the single most expansive and compressible component in silicate liquids. For example, at 1473 K and 70 MPa (conditions of a mid-ocean ridge crustal magma chamber), the presence of just 0.4 wt% H₂O will decrease the density of a basaltic liquid by more than one percent. An equivalent decrease in melt density could be achieved by increasing the temperature by 175 degrees or the decreasing pressure by 230 MPa. Therefore, even minor quantities of dissolved water will have a marked effect on the dynamic properties of silicate liquids in the crustal environment. Received: 20 August 1996 / Accepted: 15 March 1997     

Geochemistry and Rb–Sr geochronology of a ductile shear zone in the Orlica-Śnieżnik dome (West Sudetes, Poland)

Amphibolite-facies orthogneisses of the Orlica-vnie™nik dome in the West Sudetes (Poland) show a local continuous transition from weakly deformed augen gneisses to finely laminated mylonites. Field evidence indicates that ductile shearing developed pre- or syntectonically to a migmatization event. Bulk-rock compositions of variably deformed samples yield no indications for deformation- and/or fluid-enhanced element mobility and redistribution. ⁸⁷Rb-⁸⁶Sr geochronology (biotite, phengite, whole rock) places time constraints on the deformation process and the post-orogenic cooling history. Phengite- and biotite-whole-rock pairs yield Rb-Sr ages of 340 to 334 Ma and 335 to 294 Ma, respectively, independent of the degree of deformation. The weighted mean of phengite-whole-rock pairs indicates an age of 337.4DŽ.3 Ma. Combining most of the biotite-whole-rock data yields a weighted mean age of 328.6dž.4 Ma. Because of their different closure temperatures for the Rb-Sr system, these differences are interpreted to date cooling after a thermal event. Direct dating of the deformation is not possible, but the cooling history record defines a minimum age for the development of ductile shearing and the last migmatization event. These time constraints provide evidence for the initiation of crustal collapse during or immediately following peak metamorphic conditions. The results of this study further document the importance of Variscan metamorphism in the Orlica-vnie™nik dome.     

Occurrence of naphthalenesulfonates and their condensates with formaldehyde in a landfill leachate and their transport behavior in groundwater of the Upper Rhine Valley, Germany

. Naphthalenesulfonates and their condensation products with formaldehyde are manufactured in the chemical industry for broad application as tanning agents, dispersing agents, and as superplasticizers for concrete. With the disposal of waste they have found their way into the aquatic environment. Five monomeric naphthalenesulfonates and a group of dimeric sulfonated naphthalene-formaldehyde condensates (SNFC) were identified in the leachate and in groundwater observation wells downstream in the plume of the Karlsruhe-West landfill, situated in the Upper Rhine Valley in southwest Germany. For the main monomer of technical SNFC products, 2-naphthalenesulfonate (2-NS), the concentration in the leachate was 170 µg l^–1, which decreased to 9.5 µg l^–1 at a distance of about 300 m from the boundary of the landfill. In the Merdingen tracer test field, the transport of these compounds was studied under more controlled conditions in two tracer experiments with (1) two model compounds, and (2) a technical SNFC product and uranine as a reference tracer. In these experiments, the monomeric naphthalenesulfonates and the SNFC with n=2 behave as conservative tracers. Thus, the findings of the landfill study were supported by these results. Higher molecular SNFC were strongly retarded, which is attributed to adsorption to soil particles. The results of the second tracer experiment suggest a degradation of 2-NS and 2,6-naphthalenedisulfonate (2,6-NDS) after adaptation of the microorganisms in the groundwater aquifer as a consequence of the first tracer experiment.     

Impact of suboxia on sinking particulate organic carbon: Enhanced carbon flux and preferential degradation of amino acids via denitrification

Fluxes of particulate organic carbon (POC) through the oxygen deficient waters in the eastern tropical North Pacific were found to be relatively less attenuated with depth than elsewhere in the eastern North Pacific. The attenuation coefficient (b) for the flux was found to be 0.40 versus the composite value of 0.86 determined by Martin et al. (1987). To examine this further, sinking POC was collected using sediment traps and allowed to degrade in oxic and suboxic experiments. Using a kinetic model, it was found that degradation proceeded at similar rates (roughly 0.8 day⁻¹) under oxic and suboxic conditions, but a greater fraction of bulk POC was resistant to degradation in the suboxic experiments (61% vs. 23%). Amino acids accounted for 37% of POC collected at 75m, but following degradation the value dropped to 17% and 16% in the oxic and suboxic experiments respectively. POC collected from 500m was 10% amino acids. The non-AA component of POC collected at 75m was not degraded under suboxic conditions, while under oxic conditions it was. These results suggest that microbes degrading OC under suboxic conditions via denitrification preferentially utilize nitrogen-rich amino acids. This preferential degradation of amino acids suggests that 9% more nitrogen may be lost via water column denitrification than is accounted for when a more “Redfieldian” stoichiometry for POC is assumed.     

Secondary ferrimagnetic minerals in Welsh soils: a comparison of mineral magnetic detection methods and implications for mineral formation

A study of mineral magnetic parameters was carried out on a Late Pleistocene and Holocene sedimentary sequence (of nearly 18 m) from Lake Bledowo (central Poland). Sediments of Lake Bledowo have already been analysed for bulk sediment mineralogy and biogenic materials. The mineral magnetic stratigraphy confirms the major changes in palaeo-environmental conditions that have been deduced from other methods. The most important mineral magnetic change results from the authigenetic formation of ferrimagnetic greigite, Fe₃S₄, during the beginning of lacustrine conditions (± 12 000 yr BP). Our data also indicate a detrital origin of overlying ferrimagnetic iron oxides. It is suggested that they originate from brown soils developed on the boulder clay constituting the west side of the lake shore. Variations of ferrimagnetic iron oxide size are related to the early diagenetic processes in the sediment. Larger particles are present in periods with early diagenesis of organic matter in anoxic conditions. This indicates the dissolution of fine magnetic particles by iron-oxide-reducing bacteria and results in homogeneous magnetic grain sizes, despite their origin from soils, characterized by a multimodal grain-size distribution.