Nd isotope mapping of Grenvillian crustal terranes in the vicinity of the Manicouagan Impact Structure

Over 70 new Nd isotope analyses are presented for the Manicouagan area of the Grenville Province to estimate the crustal age of target rocks involved in the 214 Ma Manicouagan Impact Structure, and to reconstruct the Precambrian geological evolution of this crustal segment. The rocks fall into two main groups: Samples from the Archean-aged Gagnon Terrane to the north and west of the impact give T_DM ages averaging 2.70 Ga. Samples from the Manicouagan Imbricate Zone (MIZ) and other allochthonous lithotectonic domains to the south of the impact yield Paleoproterozoic T_DM ages averaging 2.01 Ga for the MIZ and 1.86 Ga for the southern domains. These Paleoproterozoic terranes are correlated with Makkovik-age crust in Labrador that was heavily reworked by Labradorian magmatism that increased in intensity southwards. The target rocks involved in the impact event would have consisted almost entirely of the MIZ, which formed a layer several kilometres thick, overlying Archean crust at depth.     

Pb-concentrations and Pb-isotope ratios in soils collected along an east–west transect across the United States

Analytical results for Pb-concentrations and isotopic ratios from ca. 150 samples of soil A horizon and ca. 145 samples of soil C horizon collected along a 4000-km east–west transect across the USA are presented. Lead concentrations along the transect show: (1) generally higher values in the soil A-horizon than the C-horizon (median 21 vs. 16.5 mg/kg), (2) an increase in the median value of the soil A-horizon for central to eastern USA (Missouri to Maryland) when compared to the western USA (California to Kansas) (median 26 vs. 20 mg/kg) and (3) a higher A/C ratio for the central to eastern USA (1.35 vs. 1.14). Lead isotopes show a distinct trend across the USA, with the highest ²⁰⁶Pb/²⁰⁷Pb ratios occurring in the centre (Missouri, median A-horizon: 1.245; C-horizon: 1.251) and the lowest at both coasts (e.g., California, median A-horizon: 1.195; C-horizon: 1.216). The soil C-horizon samples show generally higher ²⁰⁶Pb/²⁰⁷Pb ratios than the A-horizon (median C-horizon: 1.224; A-horizon: 1.219). The ²⁰⁶Pb/²⁰⁷Pb-isotope ratios in the soil A horizon show a correlation with the total feldspar content for the same 2500-km portion of the transect from east-central Colorado to the Atlantic coast that shows steadily increasing precipitation. No such correlation exists in the soil C horizon. The data demonstrate the importance of climate and weathering on both Pb-concentration and ²⁰⁶Pb/²⁰⁷Pb-isotope ratios in soil samples and natural shifts thereof in the soil profile during soil-forming processes.     

Regional circulation around Heard and McDonald Islands and through the Fawn Trough,central Kerguelen Plateau

The fine-scale circulation around the Heard and McDonald Islands and through the Fawn Trough, Kerguelen Plateau, is described using data from three high-resolution CTD sections, Argo floats and satellite maps of chlorophyll a, sea surface temperature (SST) and absolute sea surface height (SSH). We confirm that the Polar Front (PF) is split into two branches over the Kerguelen Plateau, with the NPF crossing the north-eastern limits of our survey carrying 25 Sv to the southeast. The SPF was associated with a strong eastward-flowing jet carrying 12 Sv of baroclinic transport through the deepest part of Fawn Trough (relative to the bottom). As the section was terminated midway through the trough this estimate is very likely to be a lower bound for the total transport. We demonstrate that the SPF contributes to the Fawn Trough Current identified by previous studies. After exiting the Fawn Trough, the SPF crossed Chun Spur and continued as a strong north-westward flowing jet along the eastern flank of the Kerguelen Plateau before turning offshore between 50°S and 51.5°S. Measured bottom water temperatures suggest a deep water connection between the northern and southern parts of the eastern Kerguelen Plateau indicating that the deep western boundary current continues at least as far north as 50.5°S. Analysis of satellite altimetry derived SSH streamlines demonstrates a southward shift of both the northern and southern branches of the Polar Front from 1994 to 2004. In the direct vicinity of the Heard and McDonald islands, cool waters of southern origin flow along the Heard Island slope and through the Eastern Trough bringing cold Winter Water (WW) onto the plateau. Complex topography funnels flow through canyons, deepens the mixed layer and increases productivity, resulting in this area being the preferred foraging region for a number of satellite-tracked land-based predators.     

The case for human causes of increased atmospheric CH4 over the last 5000 years

We propose that humans significantly altered atmospheric CH₄ levels after 5000 years BP and that anthropogenic inputs just prior to the industrial revolution accounted for up to 25% of the CH₄ level of 725 ppb (parts per billion). We base this hypothesis on three arguments: (1) the 100 ppb increase in atmospheric CH₄ that occurred after 5000 years BP follows a pattern unprecedented in any prior orbitally driven change in the ice-core record; (2) non-anthropogenic explanations for this increase (expansion of boreal peat lands or tropical wetlands) are inconsistent with existing evidence; and (3) inefficient early rice farming is a quantitatively plausible means of producing anomalously large CH₄ inputs to the atmosphere prior to the industrial revolution. If the areas flooded for farming harbored abundant CH₄-producing weeds, disproportionately large amounts of CH₄ would have been produced in feeding relatively small pre-industrial populations.     

The distribution of 210Pb and 210Po in the surface waters of the Pacific Ocean

By modelling the observed distribution of²¹⁰Pb and²¹⁰Po in surface waters of the Pacific, residence times relative to particulate removal are determined. For the center of the North Pacific gyre these are τ_Po = 0.6years andτ_Pb = 1.7years. The surface ocean τ_Pb is determined by particulate transport rather than plankton settling. The fact that it is about two orders of magnitude smaller than τ_Pb for the deep ocean implies a sharp change in the adsorptive quality of particles during descent through the water column.     

The balance and redistribution of potential vorticity within the ocean

The balance and redistribution of potential vorticity in a turbulent, inhomogeneous ocean is examined analytically. In the first part of the paper, we derive a vorticity conservation law describing the way in which vorticity is lost and gained in a closed ocean basin. We show that the potential vorticity within the ocean can only be altered by molecular diffusion at the bounding surfaces, or by the advective input of vorticity via the turbulent velocity at the free upper surface. An imbalance between these two effects within the body of the ocean leads to a net temporal change in the total potential vorticity, which we are able to express in terms of the temporal changes in the magnitude and orientation of a vector formed by the surface velocity and density and the earth's rotation. Finally, the steady-state balance of integrated vorticity is found to be between the surface wind-stress curl and the molecular diffusion at the solid boundaries.We then consider the localized redistribution of potential vorticity in detail. In recent papers, Green (1970) and Welander (1973) have purported to show that an internal redistribution of potential vorticity can give rise to important forces in the atmosphere (Green) and the ocean (Welander). Using their recipe leads in some cases to such unphysical results as a breakdown of the laws of conservation of angular momentum. Such consequences cause us to question the validity of the argument, and lead us to a close examination' of Welander's mechanism. (Green's argument is more general and does not lend itself to such close examination.) Our investigation reveals important flaws not only in Welander's argument, but also in the classical mixing-length theory of Prandtl (1925) and of Taylor (1915) on which it is modelled. More specifically, the internal redistribution process presented in these theories is found to be incomplete since it fails to take into account the lift force exerted on individual parcels of fluid as they are transported by the turbulent motions. Inclusion of these lift forces not only permits the unification of the classical mixing-length theories, but also shows that the forces claimed by Welander do not in fact arise.     

A numerical study of damping

Diagonal damping matrices were computed for three systems which have non-proportional damping matrices. These diagonal damping matrices were computed on three bases, as follows: 1. After normalizing the equations of motion by the modal matrix, the diagonal terms are retained ignoring the non-diagonal terms. 2. Diagonal damping matrix is established by the optimization algorithm which minimizes the mean square error of the frequency response. 3. Diagonal damping is determined from the normalized differential equation by matching the peaks of the coupled and uncoupled system. The frequency responses for the three cases of one of the three systems are presented together with a comparison of the energy dissipation.