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排序方式: 共有356条查询结果,搜索用时 31 毫秒
61.
Amy Gartman Mustafa Y��cel Andrew S. Madison David W. Chu Shufen Ma Christopher P. Janzen Erin L. Becker Roxanne A. Beinart Peter R. Girguis George W. Luther III 《Aquatic Geochemistry》2011,17(4-5):583-601
The sulfide (H2S/HS?) that is emitted from hydrothermal vents begins to oxidize abiotically with oxygen upon contact with ambient bottom water, but the reaction kinetics are slow. Here, using in situ voltammetry, we report detection of the intermediate sulfur oxidation products polysulfides [ $ {\text{S}}_{\text{x}}^{2 - } $ ] and thiosulfate [ $ {\text{S}}_{ 2} {\text{O}}_{ 3}^{ 2- } $ ], along with contextual data on sulfide, oxygen, and temperature. At Lau Basin in 2006, thiosulfate was identified in less than one percent of approximately 10,500 scans and no polysulfides were detected. Only five percent of 11,000 voltammetric scans taken at four vent sites at Lau Basin in May 2009 show either thiosulfate or polysulfides. These in situ data indicate that abiotic sulfide oxidation does not readily occur as H2S contacts oxic bottom waters. Calculated abiotic potential sulfide oxidation rates are <10?3 ??M/min and are consistent with slow oxidation and the observed lack of sulfur oxidation intermediates. It is known that the thermodynamics for the first electron transfer step for sulfide and oxygen during sulfide oxidation in these systems are unfavorable, and that the kinetics for two electron transfers are not rapid. Here, we suggest that different metal catalyzed and/or biotic reaction pathways can readily produce sulfur oxidation intermediates. Via shipboard high-pressure incubation experiments, we show that snails with chemosynthetic endosymbionts do release polysulfides and may be responsible for our field observations of polysulfides. 相似文献
62.
63.
The Agenian is the earliest Neogene European Land Mammal Age. It encompasses the mammalian zones MN1 (23.03–22.7 Ma) and MN2 (22.7–20.0 Ma) and roughly coincides with the Aquitanian standard age. Agenian mammalian assemblages from Western Europe encompass a mixture of rhinocerotid taxa of Oligocene affinities and of Miocene newcomers, mostly recorded in France, Germany, Switzerland, and to a lesser extent, Spain. Rhinocerotidae are documented by seven species referred to five genera (Pleuroceros pleuroceros, Protaceratherium minutum, Plesiaceratherium aquitanicum, Mesaceratherium paulhiacense, Diaceratherium lemanense, D. asphaltense, and D. aginense), further attesting to a low suprageneric diversity. Their systematics, morphology, ecology, stratigraphical and geographical ranges are detailed in the present article. Occurrences and geographical ranges of all seven rhinocerotid species are illustrated on palaeogeographical maps of the circum-Mediterranean region at 23 Ma (MN1) and 21 Ma (MN2). The richest Agenian localities (Paulhiac, MN1; Laugnac, MN2) record a specific diversity similar to that of Orleanian rhinocerotid assemblages, with up to five/six associated species. All Agenian rhinocerotid species from Western Europe are endemic to the concerned region, which is consistent with the complete geographic isolation of Western Europe by earliest Miocene times. However, all five genera are documented by twin species in coeval localities of South and Central Asia, which implies (1) vicariant speciation events by latest Oligocene times and (2) the existence of intermittent pathways for terrestrial megamammals such as rhinocerotids during the concerned interval. 相似文献
64.
65.
The Lippmann diagram for the system(Ba, Sr)SO4-H2O was computed at 25 °Cby determining the solid-phase activity coefficientsfrom first principles calculations. Directcalculations of the mixing properties of thebarite-celestite series indicate this solid solutionbehaves as non-ideal and non-regular. At 25 °C,the enthalpy of mixing shows a minimum around 50 mole% SrSO4 due to an ordering tendency. Thefree energy of mixing shows two minima that delimit awide and symmetric miscibility gap (from 2.1 to 97.9 mole% SrSO4) at this temperature. The excessfree energy of mixing requires a Guggenheim expansionseries of 5 terms to be described, where the termswith odd exponents are null as a consequence of thesymmetric distribution of the mixing properties withcomposition. The Lippmann diagram shows a peritecticpoint that corresponds to the composition of an aqueoussolution which is simultaneously at equilibrium withthe two extremes of the miscibility gap. The largedifference between the solubility products of theendmembers involves a strong preferential partitioningof the less soluble endmember towards the solid phase,which explains the extremely Ba-poor composition ofthe aqueous solution (aqueous activity fraction forBa2+ = 0.000446 ) at the peritectic point. 相似文献
66.
The Ardara pluton as part of the Donegal batholith was intruded into Neoproterozoic metasediments and metadolerites at mid-crustal
levels. The emplacement mechanism of the Ardara granite is very controversial, and mechanisms ranging from diapirism, ballooning
and stoping followed by nested diapirism have been proposed. Magnetic fabrics, rock fabrics and K/Ar dating of micas are used
here to constrain the emplacement history. The compositional zoning of the Ardara pluton is clearly reflected in the different
bulk magnetic susceptibilities between the outer quartz monzodiorite and the central granodiorite, whereas the intervening
tonalite is of intermediate nature. The magnetic carriers are characterized by the anisotropy of the magnetic susceptibility
(AMS), thermomagnetic measurements and through high field analyses (HFA). The separation of the ferrimagnetic and paramagnetic
contributions revealed that biotite and magnetite control the AMS in the quartz monzodiorite. Both minerals are oriented in
such a way that their summed contribution is constructive and originates from the shape fabric of magnetite and the texture
of biotite. Biotite is responsible mainly for the AMS in the tonalite and granodiorite. The magnetic foliation can be directly
related to the macroscopic foliation and also to the D4 structures in the country rocks. The foliation is consistent with
the geometry of the roughly circular shape and has a mostly steep to vertical dip. Towards the central granodiorite the magnetic
foliation dies out, although plagioclase texture measurements indicate a weak magmatic shape fabric. With the exception of
the tail, the Kmax axes (magnetic lineation) vary from steeply to gently plunging. The so-called lineation factor is approximately 1.01 and
therefore points to a less significant axial symmetry. These observations coincide with strain estimates on mafic enclaves
that show a very consistent pattern of K ∼0 flattening strain. Texture analyses of biotite and quartz additionally support
the observations made by the strain analyses and the magnetic fabric data. Microstructural investigations give evidence that
the fabrics are associated with the emplacement over a range of temperatures from truly magmatic to high-temperature solid-state
conditions. The age of the intrusion is still under discussion, but a new cooling age was determined by K/Ar dating of biotite
at 403.7±8 Ma corresponding to a temperature range between 450 and 300°C. For a mylonite along the southern contact between
the Ardara pluton and the country rock a K/Ar muscovite age of 378.8±7 Ma indicates a minimum age for the shear zone when
the Ardara pluton must have already been cooled down below 350±50°C.
Received: 28 January 1999 / Accepted: 28 December 1999 相似文献
67.
Sergei V.Antipin Ignacio Becker AlexANDer A.Belinski Darya M.Kolesnikova Karim Pichara Nikolay N.Samus Kirill V.Sokolovsky Alla V.Zharova Alexandra M.Zubareva 《天文和天体物理学研究(英文版)》2018,(8)
Using 172 plates taken with the 40-cm astrograph of the Sternberg Astronomical Institute(Lomonosov Moscow University) in 1976–1994 and digitized with a resolution of 2400 dpi, we discovered and studied 275 new variable stars. We present the list of our new variables with all necessary information concerning their brightness variations. As in our earlier studies, the new discoveries show a rather large number of high-amplitude Delta Scuti variables, predicting that many stars of this type remain not detected in the whole sky. We also performed automated classification of the newly discovered variable stars based on the Random Forest algorithm. The results of the automated classification were compared to traditional classification and showed that automated classification was possible even with noisy photographic data. However, further improvement of automated techniques is needed, which is especially important when considering the very large numbers of new discoveries expected from all-sky surveys. 相似文献
68.
69.
M. Merck A. Karle S. Martinez F. Arqueros K. H. Becker M. Bott-Bodenhausen R. Eckmann E. Faleiro J. Fernandez P. Fernandez V. Fonseca V. Haustein G. Heinzelmann I. Holl F. Just F. Krennrich M. Kühn E. Lorenz H. Meyer N. Müller R. Plaga J. Prahl M. Probst M. Rozanska M. Samorski H. Sander K. Sauerland C. Sesea W. Stamm 《Astroparticle Physics》1996,5(3-4):379-392
A precise knowledge of the angular resolution of scintillator arrays used to observe extended air showers (EAS) is of key importance in the search for VHE/UHE γ point sources. Four independent methods have been used to determine the mean resolution for which a value of ΔΘ63 of 0.8°(1.0°) at a proton threshold of 50 (40) TeV has been found for the HEGRA EAS-array. 相似文献
70.
A proposed new type of arsenian pyrite: Composition, nanostructure and geological significance 总被引:8,自引:0,他引:8
Artur P. Deditius Udo Becker Stephen E. Kesler 《Geochimica et cosmochimica acta》2008,72(12):2919-2933
This report describes a new form of arsenian pyrite, called As3+-pyrite, in which As substitutes for Fe [(Fe,As)S2], in contrast to the more common form of arsenian pyrite, As1−-pyrite, in which As1− substitutes for S [Fe(As,S)2]. As3+-pyrite has been observed as colloformic overgrowths on As-free pyrite in a hydrothermal gold deposit at Yanacocha, Peru. XPS analyses of the As3+-pyrite confirm that As is present largely as As3+. EMPA analyses show that As3+-pyrite incorporates up to 3.05 at % of As and 0.53 at. %, 0.1 at. %, 0.27 at. %, 0.22 at. %, 0.08 at. % and 0.04 at. % of Pb, Au, Cu, Zn, Ni, and Co, respectively. Incorporation of As3+ in the pyrite could be written like: As3++yAu++1-y(□)⇔2Fe2+; where Au+ and vacancy (□) help to maintain the excess charge. HRTEM observations reveal a sharp boundary between As-free pyrite and the first overgrowth of As3+-pyrite (20-40 nm thick) and co-linear lattice fringes indicating epitaxial growth of As3+-pyrite on As-free pyrite. Overgrowths of As3+-pyrite onto As-free pyrite can be divided into three groups on the basis of crystal size, 8-20 nm, 100-300 nm and 400-900 nm, and the smaller the crystal size the higher the concentration of toxic arsenic and trace metals. The Yanacocha deposit, in which As3+-pyrite was found, formed under relatively oxidizing conditions in which the dominant form of dissolved As in the stability field of pyrite is As3+; in contrast, reducing conditions are typical of most environments that host As1−-pyrite. As3+-pyrite will likely be found in other oxidizing hydrothermal and diagenetic environments, including high-sulfidation epithermal deposits and shallow groundwater systems, where probably kinetically controlled formation of nanoscale crystals such as observed here would be a major control on incorporation and release of As3+ and toxic heavy metals in oxidizing natural systems. 相似文献