Laboratory measurements of seismic attenuation and Young's modulus dispersion in a partially and fully water‐saturated porous sample made of sintered borosilicate glass

We measured the extensional‐mode attenuation and Young's modulus in a porous sample made of sintered borosilicate glass at microseismic to seismic frequencies (0.05–50 Hz) using the forced oscillation method. Partial saturation was achieved by water imbibition, varying the water saturation from an initial dry state up to ～99%, and by gas exsolution from an initially fully water‐saturated state down to ～99%. During forced oscillations of the sample effective stresses up to 10 MPa were applied. We observe frequency‐dependent attenuation, with a peak at 1–5 Hz, for ～99% water saturation achieved both by imbibition and by gas exsolution. The magnitude of this attenuation peak is consistently reduced with increasing fluid pressure and is largely insensitive to changes in effective stress. Similar observations have recently been attributed to wave‐induced gas exsolution–dissolution. At full water saturation, the left‐hand side of an attenuation curve, with a peak beyond the highest measured frequency, is observed at 3 MPa effective stress, while at 10 MPa effective stress the measured attenuation is negligible. This observation is consistent with wave‐induced fluid flow associated with mesoscopic compressibility contrasts in the sample's frame. These variations in compressibility could be due to fractures and/or compaction bands that formed between separate sets of forced‐oscillation experiments in response to the applied stresses. The agreement of the measured frequency‐dependent attenuation and Young's modulus with the Kramers–Kronig relations and additional data analyses indicate the good quality of the measurements. Our observations point to the complex interplay between structural and fluid heterogeneities on the measured seismic attenuation and they illustrate how these heterogeneities can facilitate the dominance of one attenuation mechanism over another.     

Numerically quantifying energy loss caused by squirt flow

In interconnected microcracks, or in microcracks connected to spherical pores, the deformation associated with the passage of mechanical waves can induce fluid flow parallel to the crack walls, which is known as squirt flow. This phenomenon can also occur at larger scales in hydraulically interconnected mesoscopic cracks or fractures. The associated viscous friction causes the waves to experience attenuation and velocity dispersion. We present a simple hydromechanical numerical scheme, based on the interface-coupled Lamé–Navier and Navier–Stokes equations, to simulate squirt flow in the frequency domain. The linearized, quasi-static Navier–Stokes equations describe the laminar flow of a compressible viscous fluid in conduits embedded in a linear elastic solid background described by the quasi-static Lamé–Navier equations. Assuming that the heterogeneous model behaves effectively like a homogeneous viscoelastic medium at a larger spatial scale, the resulting attenuation and stiffness modulus dispersion are computed from spatial averages of the complex-valued, frequency-dependent stress and strain fields. An energy-based approach is implemented to calculate the local contributions to attenuation that, when integrated over the entire model, yield results that are identical to those based on the viscoelastic assumption. In addition to thus validating this assumption, the energy-based approach allows for analyses of the spatial dissipation patterns in squirt flow models. We perform simulations for a series of numerical models to illustrate the viability and versatility of the proposed method. For a 3D model consisting of a spherical crack embedded in a solid background, the characteristic frequency of the resulting P-wave attenuation agrees with that of a corresponding analytical solution, indicating that the dissipative viscous flow problem is appropriately handled in our numerical solution of the linearized, quasi-static Navier–Stokes equations. For 2D models containing either interconnected cracks or cracks connected to a circular pore, the results are compared with those based on Biot's poroelastic equations of consolidation, which are solved through an equivalent approach. Overall, our numerical simulations and the associated analyses demonstrate the suitability of the coupled Lamé–Navier and Navier–Stokes equations and of Biot's equations for quantifying attenuation and dispersion for a range of squirt flow scenarios. These analyses also allow for delineating numerical and physical limitations associated with each set of equations.     

A high-resolution operational forecast system for oil spill response in Belfast Lough

This paper presents a high-resolution operational forecast system for providing support to oil spill response in Belfast Lough. The system comprises an operational oceanographic module coupled to an oil spill forecast module that is integrated in a user-friendly web application. The oceanographic module is based on Delft3D model which uses daily boundary conditions and meteorological forcing obtained from COPERNICUS and from the UK Meteorological Office. Downscaled currents and meteorological forecasts are used to provide short-term oil spill fate and trajectory predictions at local scales. Both components of the system are calibrated and validated with observational data, including ADCP data, sea level, temperature and salinity measurements and drifting buoys released in the study area. The transport model is calibrated using a novel methodology to obtain the model coefficients that optimize the numerical simulations. The results obtained show the good performance of the system and its capability for oil spill forecast.     

Volcanic emissions and atmospheric pollution:A study of nanoparticles

The influence of emissions of an active volcano on the composition of nanoparticles and ultrafine road dust was identified in an urban area of the Andes.Although many cities are close to active volcanoes,few studies have evaluated their influence in road dust composition.Air quality in urban areas is significantly affected by nonexhaust emissions(e.g.road dust,brake wear,tire wear),however,natural sources such as volcanoes also impact the chemical composition of the particles.In this study,elements from volcanic emissions such as Si>Al>Fe>Ca>K>Mg,and Si-Al with K were identified as complex hydrates.Similarly,As,Hg,Cd,Pb,As,H,Cd,Pb,V,and salammoniac were observed in nanoparticles and ultrafine material.Mineral composition was detected in the order of quartz>mullite>calcite>kaolinite>illite>goethite>magnetite>zircon>monazite,in addition to salammoniac,a tracer of volcanic sources.The foregoing analysis reflects the importance of carrying out more studies relating the influence of volcanic emissions in road dust in order to protect human health.The road dust load(RD₁₀)ranged between 0.8 and 26.8 mg m^?2in the city.     

Plastic ingestion by Procellariiformes in Southern Brazil

The Procellariiformes are the birds most affected by plastic pollution. Plastic fragments and pellets were the most frequent items found in the digestive tract of eight species of Procellariiformes incidentally caught by longline fisheries as well as beached birds in Southern Brazil. Plastic objects were found in 62% of the petrels and 12% of the albatrosses. The Great shearwater, Manx shearwater, Cory's shearwater and Antarctic fulmar were found to have greater quantities and frequencies of occurrence of plastic. There was no significant difference in the number of plastics between the birds from longline fisheries and beached birds. No correlation was found between the number of prey and number of plastics in the digestive tract of the birds analyzed, but this does not discard the hypothesis that, in some cases, the presence of plastic in the digestive tract has a negative effect on the feeding efficiency of these birds.     

Late Pleistocene: Holocene record of environmental changes in Lake Zirahuen,Central Mexico

Geochemical data obtained from X-ray fluorescence, physical properties, total organic and inorganic carbon content (TOC/TIC), and diatom analysis from a 6.61-m-long sedimentary sequence near the modern northern shore of Lake Zirahuen (101° 44′ W, 19° 26′ N, 2000 m asl) provide a reconstruction of lacustrine sedimentation during the last approximately 17 cal kyr BP. A time scale is based on ten AMS ¹⁴C dates and by tephra layers from Jorullo (AD 1759-1764) and Paricutin (AD 1943-1952) volcanoes. The multiproxy analyses presented in this study reveal abrupt changes in environmental and climatic conditions. The results are compared to the paleo-record from nearby Lake Patzcuaro. Dry conditions and low lake level are inferred in the late Pleistocene until ca. 15 cal kyr BP, followed by a slight but sustained increase in lake level, as well as a higher productivity, peaking at ca. 12.1 cal kyr BP. This interpretation is consistent with several regional climatic reconstructions in central Mexico, but it is in opposition to record from Lake Patzcuaro. A sediment hiatus bracketed between 12.1 and 7.2 cal kyr BP suggests a drop in lake level in response to a dry early Holocene. A deeper, more eutrophic and turbid lake is recorded after 7.2 cal kyr BP. Lake level at the coring site during the mid Holocene is considered the highest for the past 17 cal kyr BP. The emplacement of the La Magueyera lava flows (LMLF), dated by thermoluminiscence at 6560 ± 950 year, may have reduced basin volume and contributed to the relative deepening of the lake after 7.2 cal kyr BP. The late Holocene (after 3.9 cal kyr BP) climate is characterized by high instability. Extensive erosion, lower lake levels, dry conditions and pulses of high sediment influx due to high rainfall are inferred for this time. Further decrease in lake level and increased erosion are recorded after ca. AD 1050, at the peak of Purepechas occupation (AD 1300–1521), and until the eighteenth century. Few lacustrine records extend back to the late Pleistocene—early Holocene in central Mexico; this paper contributes to the understanding of late Pleistocene-Holocene paleoclimates in this region.     

Study of the effect of temperature, irradiance and salinity on growth and yessotoxin production by the dinoflagellate Protoceratium reticulatum in culture by using a kinetic and factorial approach

A complete first order orthogonal plan was used to optimize the growth and the production of yessotoxin (YTX) by the dinoflagellate Protoceratium reticulatum in culture by controlling salinity, temperature and irradiance. Initially, an approach to the kinetic data of cellular density and YTX production for each one of the experimental design conditions was performed. The P. reticulatum growth and YTX production were fitted to logistical equations and to a first-order kinetic model, respectively. The parameters obtained from this adjustment were used as dependent variables for the formulation of the empirical equations of the factorial design tested. The results showed that in practically all the cases for both, P. reticulatum growth and YTX production, irradiance is the primary independent variable and has a positive effect in the range 50-90 micromol photons m(-2) s(-1). Additionally, in certain specific cases, temperature reveals significant positive effects when maintained between 15 and 23 degrees C and salinity in the range of 20-34 displays negative effects. Despite the narrow ranges used in the work, results showed the suitability of factorial analysis to evaluate the optimal conditions for growth and yessotoxin production by the dinoflagellate P. reticulatum.     

Joint Audio-Magnetotelluric and Passive Seismic Imaging of the Cerdanya Basin

The structure of Cerdanya Basin (north-east of Iberian Peninsula) is partly known from geological cross sections, geological maps and vintage geophysical data. However, these data do not have the necessary resolution to characterize some parts of Cerdanya Basin such as the thickness of soft soil, geometry of bedrock or geometry of geological units and associated faults. For all these reasons, the main objective of this work is to improve this deficiency carrying out a detailed study in this Neogene basin applying jointly the combination of passive seismic methods (H/V spectral ratio and seismic array) and electromagnetic methods (audio-magnetotelluric and magnetotelluric method). The passive seismic techniques provide valuable information of geometry of basement along the profile. The maximum depth is located near Alp village with a bedrock depth of 500 m. The bedrock is located in surface at both sites of profile. The Neogene sediments present a shear-wave velocity between 400 and 1000 m/s, and the bedrock basement presents a shear-wave velocity values between 1700 and 2200 m/s. These results are used as a priori information to create a 2D resistivity initial model which constraints the inversion process of electromagnetic data. We have obtained a 2D resistivity model which is characterized by (1) a heterogeneous conductivity zone (<40 Ohm m) that corresponds to shallow part of the model up to 500 m depth in the centre of the profile. These values have been associated with Quaternary and Neogene sediments formed by silts, clays, conglomerates, sandstones and gravels, and (2) a deeper resistive zone (1000–3000 Ohm m) interpreted as Palaeozoic basement (sandstones, limestones and slates at NW and conglomerates and microconglomerates at SE). The resistive zone is truncated by a discontinuity at the south-east of the profile which is interpreted as the Alp-La Tet Fault. This discontinuity is represented by a more conductive zone (600 Ohm m approx.) and is explained as a combination of fractured rock and a fluid network. The result highlights that the support between different geophysical methods is essential in producing geophysical meaningful models.