Organic components in thermally altered coal waste: Preliminary petrographic and geochemical investigations

The petrographic and geochemical composition of coal wastes exposed to fire in the minestone dump of Piekary Ślą¹skie town (Upper Silesia, Poland) was investigated using samples collected at various distances from a recent fire site. The question as to whether geochemical biomarker maturity parameters could be applied to assess thermal changes in organic matter caused by waste dump fires, was examined using the data obtained. Geochemical parameters were correlated with observed petrographic changes in the organic matter caused by oxidation and heating. Petrographic analyses included the determination of maceral group contents (vitrinite, liptinite and inertinite), mineral matter and coke contents, and reflectance measurements on organic matter. All results were supported by proximate and ultimate analyses. Geochemical analysis included ultrasonic solvent extraction of bitumen followed by gas chromatography–mass spectrometry (GC–MS) of the extracts. In petrographic terms, the influence of heating was seen in reflectance variations and as oxidation rims, cracks, pores and coke development. Some zoned oxidation rims may be interpreted as re-heating episodes. In terms of chemical fingerprints, less thermally-stable compounds such as lighter n-alkanes, cyclic isoprenoids, methyl- and dimethylnaphthalenes, methyphenanthrenes and five-ring polycyclic aromatic hydrocarbons were destroyed or evaporated in the most fire-affected material. The presence/absence of particular compound groups was used to assess heating temperatures. Biomarker parameters of thermal maturity were used to assess alterations in organic matter around the waste dump fires, especially those indices and ratios with higher maturity ranges, e.g. (3-methylbiphenyl + 4-methylbiphenyl)/dibenzofurane and Σdimethylbiphenyls/Σmethyldibenzofuranes.     

Palaeomagnetism of some late Mesozoic dolerite sills of East Central Spitsbergen, Svalbard Archipelago

Summary. Two late Mesozoic dolerite sills, situated near Agardhbukta on the east coast of Vestspitsbergen and dated radiométrically at 100 ± 4 Myr BP, have been sampled in five localities and subjected to detailed mineralogical and rock magnetic studies to determine the direction and origin of their magnetization. Although the sills lie outside the Tertiary orogenic belt, one locality (no. 4) has undergone strong hydrothermal alteration and a small part of another locality (no. 3) has also been affected. A conventional procedure based on examination of Zijderveld diagrams, applied to specimens demagnetized by alternating fields and thermally, yielded similar remanence directions at all five localities, except at the altered part of locality 3. Using a least squares computer méthod of analysis of step demagnetization data, comparable directions were isolated from all localities, including the altered part of locality 3. Except in this last case, all directions were reversed. The adjusted mean direction obtained from this analysis is D = 159.0°, I = 62.2°, α₉₅= 9.0° yielding a palaeomagnetic pole situated at 225.0°, 54.3°N comparable with pole positions obtained from other late Mesozoic igneous rocks on Spitsbergen and distinct from palaeopoles derived from Mesozoic rocks in North America and Eurasia. This suggests that during the late Mesozoic Svalbard existed as a semi-independent microplate.     

Application of turning bands technique to simulate values of copper ore deposit parameters in Rudna mine (Lubin-Sieroszowice region in SW part of Poland)

ABSTRACT

The turning bands simulation is a valuable and highly useful tool in solving various geological-mining, environmental and geological-engineering problems when it is essential to determine the uncertainty of the estimates of simulated values Z_s (realizations) and assess the risk. This paper presents an investigative methodology and the results of calculations connected with the use of conditional turning bands simulation and bundled indicator kriging, making it possible to analyse the risk at different levels of uncertainty in the solution of optimization of the exploitation problems encountered in the mining of the polymetallic copper ore deposits in the Lubin-Sieroszowice region (Foresudetic monocline, the SW part of Poland). Examples of the evaluation of simulated values Z_s and probability P average values Z* of the deposit parameters within the block located in the Rudna Mine (the block R-3) area are provided.     

New insights into lake responses to rapid climate change: the Younger Dryas in Lake Gościąż, central Poland

The sediment profile from Lake Gościąż in central Poland comprises a continuous, seasonally resolved and exceptionally well-preserved archive of the Younger Dryas (YD) climate variation. This provides a unique opportunity for detailed investigation of lake system responses during periods of rapid climate cooling (YD onset) and warming (YD termination). The new varve record of Lake Gościąż presented here spans 1662 years from the late Allerød (AL) to the early Preboreal (PB). Microscopic varve counting provides an independent chronology with a YD duration of 1149+14/–22 years, which confirms previous results of 1140±40 years. We link stable oxygen isotopes and chironomid-based air temperature reconstructions with the response of various geochemical and varve microfacies proxies especially focusing on the onset and termination of the YD. Cooling at the YD onset lasted ~180 years, which is about a century longer than the terminal warming that was completed in ~70 years. During the AL/YD transition, environmental proxy data lagged the onset of cooling by ~90 years and revealed an increase of lake productivity and internal lake re-suspension as well as slightly higher detrital sediment input. In contrast, rapid warming and environmental changes during the YD/PB transition occurred simultaneously. However, initial changes such as declining diatom deposition and detrital input occurred already a few centuries before the rapid warming at the YD/PB transition. These environmental changes likely reflect a gradual increase in summer air temperatures already during the YD. Our data indicate complex and differing environmental responses to the major climate changes related to the YD, which involve different proxy sensitivities and threshold processes.     

Cerium and Ytrium in apatite as records of magmatic processes: Insight into fractional crystallization,magma mingling and fluid saturation

Apatite is a versatile mineral crystallizing at different stages of silicic magma evolution. Its composition may record that of magma, but could also be affected by interaction with fluids. The focus of this study is the well-recognized magma mingling process that was previously detected using plagioclase composition and in this study complementary record is sought in apatite. The apatite was analysed in two dioritic enclaves (primitive and hybrid) and host quartz monzonite, which is an igneous rock emplaced at ca. 340 Ma in mylonitized Góry Sowie gneisses (NE Bohemian Massif). The apatite was analysed in-situ by microprobe that allowed for chemical characterization of different apatite populations in quartz monzonite and analyses of thin acicular apatite in the enclaves. Apatite population in the quartz monzonite was chemically distinct from that in both enclave types and characterized by higher Y and lower Ce contents, such values are usually typical for peraluminous magmas. As such, the apatite transfer from felsic to mafic magma should be well recorded in apatite composition, which was not the case. Monzonite apatite composition was not commonly observed in the hybrid enclave despite massive plagioclase transfer and only rare resorbed cores with low Ce and Y contents were present. However, such low Ce and Y cores crystalized at the latest stage of apatite crystallization in the quartz monzonite, whereas the plagioclase transfer was an early episode. Therefore, we conclude that apatite transfer was limited during mingling and the apatite composition in the quartz monzonite is best explained by an early Cl-Ce-rich fluid removal and then fractional crystallization, while apatite in the primitive enclave is affected only by fractional crystallization. Altogether, Ce and Y composition of apatite is a valuable tool to record diverse magmatic processes such as fluid removal and precipitation from fluid in addition to fractionation of different REE phases and should be further explored.     

Patterns of cornulitid encrustation on the Late Devonian brachiopod shells from Russia

Upper Devonian brachiopods from the Central Devonian Field, Russia have been investigated with respect to encrustation patterns of cornulitids. These Palaeozoic encrusters were very characteristic component of shelly substrates during the Devonian and may serve as valuable objects for palaeoecological studies, especially those concerning the encrusters-host relationships. On the basis of rich material, it has been shown that cornulitid abundance significantly increased in the lower Famennian. Their disparity also increased from one morphotype (robust) present in the upper Frasnian to two distinct morphotypes (robust and slender, presumably representing two different species) in the lower Famennian. The analysis of the spatial occurrence of cornulitids on two dominant lower Famennian brachiopod species (Cyrtospirifer zadonicus and Ripidiorhynchus huotinus) showed, that these encrusters preferred the marginal parts of the shells. This, together with a dominant directional growth of cornulitids toward the commissure, indicates that cornulitids benefited from food brought by feeding currents produced by the brachiopod’s lophophore. The unequivocal evidence for syn vivo association of the cornulitids and their brachiopod hosts is the presence of distinct shell malformations caused by cornulitid growth affecting the host’s shell-secreting epithelium, preserved on some lower Famennian specimens. Interestingly, these malformations were caused by a slender cornulitid morphotype only. Thus, it is evident that during food gathering from the inhalant currents, this cornulitid species exerted a distinct, negative effect on the brachiopod – a deviation of its shell growth. In this case, we may consider this particular cornulitid species as ectoparasite rather than commensal with respect to its host.     

Gully erosion as a natural hazard: the educational role of geotourism

Gully erosion is one of the greatest natural hazards in the loess areas of E. (Eastern) Poland. At the same time, permanent gullies are a major tourist attraction and can provide a basis for the development of geotourism. The study objective was to assess the possibilities of using the loess gullies for educational purposes. Detailed studies were conducted within the municipality of Kazimierz Dolny, an area with an extremely high concentration of permanent gullies. The questionnaire survey of students and tourists (nearly 300 surveys were completed) showed that the respondents’ knowledge of geomorphology was limited, despite their familiarity with gullies. In most cases, they were unable to accurately identify the determinants of gully erosion, its negative effects and methods for preventing it. An assessment of the tourism and geotourism potential of the municipality made it possible to identify the sites (gullies) that can perform an educational function, with regard to gully erosion. The establishment of the Ma?opolska Vistula Gap Geopark, whose highlights will include numerous loess gullies, can pave the way for the development of geotourism.