Seismic velocity estimation from post-critical wide-angle reflections in layered structures

The travel time inversion of wide-angle seismic data is a technique commonly used in the deep seismic sounding. We propose an application of this technique to a smaller scale of a sedimentary layer, where the characteristics of seismic observations changes significantly. Field observations confirmed by synthetic analysis recognize the dominant amplitudes of wide-angle post-critical reflections. A case study is presented in this paper, of a joint interpretation of conventional reflection seismic with reflection imaging, combined with the wide-angle travel time inversion of additional full-spread observations. A joint interpretation results in a precise recognition of the seismic velocity distribution, that is further used for the seismic depth conversion with the uncertainty analysis of the depth of the reflecting horizons. Despite the salt layer in the studied structure this method is able to precisely recognize the seismic velocities of the sub-salt structures.     

Geo‐questionnaire: A Method and Tool for Public Preference Elicitation in Land Use Planning

Geo‐questionnaire involves an integration of sketchable maps with questions, aimed at eliciting public preferences and attitudes about land allocation and services. Respondents can link their answers with corresponding locations on a map by marking points or sketching polygon features. Geo‐questionnaires have been used to learn about perceptions and preferences of city residents for specific types of land use, place‐based services, and development projects. This article reports on results of an empirical study, in which an online geo‐questionnaire was designed and implemented to elicit preferences of residents in guiding an urban development plan. Preferences collected in the form of polygon sketches were processed using GIS operations and mapped for visual interpretation. The article focuses on aggregation and analysis of respondent preferences including the analysis of positional and attribute uncertainty. Results of the study show that geo‐questionnaire is a scalable method for eliciting public preferences with a potential for meaningfully informing land use planning.     

Evaluating transition-metal catalysis in gas generation from the Permian Kupferschiefer by hydrous pyrolysis

Transition metals in source rocks have been advocated as catalysts in determining extent, composition, and timing of natural gas generation (Mango, F. D. (1996) Transition metal catalysis in the generation of natural gas. Org. Geochem.24, 977-984). This controversial hypothesis may have important implications concerning gas generation in unconventional shale-gas accumulations. Although experiments have been conducted to test the metal-catalysis hypothesis, their approach and results remain equivocal in evaluating natural assemblages of transition metals and organic matter in shale. The Permian Kupferschiefer of Poland offers an excellent opportunity to test the hypothesis with immature to marginally mature shale rich in both transition metals and organic matter. Twelve subsurface samples containing similar Type-II kerogen with different amounts and types of transition metals were subjected to hydrous pyrolysis at 330° and 355 °C for 72 h. The gases generated in these experiments were quantitatively collected and analyzed for molecular composition and stable isotopes. Expelled immiscible oils, reacted waters, and spent rock were also quantitatively collected. The results show that transition metals have no effect on methane yields or enrichment. δ¹³C values of generated methane, ethane, propane and butanes show no systematic changes with increasing transition metals. The potential for transition metals to enhance gas generation and oil cracking was examined by looking at the ratio of the generated hydrocarbon gases to generated expelled immiscible oil (i.e., GOR), which showed no systematic change with increasing transition metals. Assuming maximum yields at 355 °C for 72 h and first-order reaction rates, pseudo-rate constants for methane generation at 330 °C were calculated. These rate constants showed no increase with increasing transition metals. The lack of a significant catalytic effect of transition metals on the extent, composition, and timing of natural gas generation in these experiments is attributed to the metals not occurring in the proper form or the poisoning of potential catalytic microcosms by polar-rich bitumen, which impregnates the rock matrix during the early stages of petroleum formation.     

Evidence of probable paleotsunami deposits on Kho Khao Island, Phang Nga Province, Thailand

The 2004 tsunami deposits and probable paleotsunami deposits were studied at the southern Kho Khao Island, on Andaman Sea coast of Thailand. The 2004 tsunami laid down about 8?cm of fining upward medium sand and locally about 40?cm of massive coarse sand with common mud clasts. The sediments were characterized by the presence of marine foraminiferal assemblage; however, already after 5?years many of carbonate foraminiferal tests were partly or completely dissolved. The probable paleotsunami deposits form layer about 1?m thick. It consists of massive very coarse sand with common big shells and mud clasts. Its composition suggests a marine origin and the presence of mud clasts, and similarity to the 2004 tsunami deposits suggests that the layer was left by paleotsunami, which took place probably during the late Holocene, even though two shells within the layer gave ¹⁴C ages of 40,000?years or more.     

U‐Pb zircon dating of metaigneous rocks from the Nordbreen Nappe of Svalbard’s Ny‐Friesland suggests their affinity to Northeast Greenland

SIMS U‐Pb zircon dating of metaigneous rocks of the Nordbreen Nappe from the West Ny‐Friesland terrane (Eastern Basement Province of Svalbard) yields crystallization ages of 1,761 ± 4 Ma for a felsic metatuff and 1,373 ± 4 Ma for a metagabbro dyke. The Palaeoproterozoic age of the metatuff is similar to previously obtained ages for various felsic rocks from the study area, whereas the Mesoproterozoic age of the metagabbro has not been thus far documented on Svalbard. However, a similar age pattern has been reported from Northeast Greenland. Therefore, we conclude that the West Ny‐Friesland terrane can be correlated with age equivalent units of Northeast Greenland. We also explore similarities and dissimilarities between the study area and other terranes of Svalbard and speculate on regional‐scale correlations. Together, the presented new ages provide critical piercing points in palaeogeographic reconstructions of the relatively poorly understood circum‐Arctic region.     

Dynamic stratigraphy of composite peripheral unconformity in a foredeep basin

This study employs facies analysis and basic principles of sequence stratigraphy to correlate isolated outcrop sections and reveal the depositional history of the Chmielnik Formation – a prominent mid‐Serravalian clastic wedge formed on the basinward forebulge flank of the Polish Carpathian Foredeep. The coarse‐grained clastic wedge, up to 30 m thick and spanning ca 1·1 Ma within biozone NN6, consists of fluvio‐deltaic, foreshore and shoreface deposits with a range of large littoral sand bars, all enveloped in muddy offshore‐transition deposits. Its dynamic stratigraphy indicates rapid shoreline shifts and environmental changes due to the interplay of forebulge tectonism, sediment supply and third‐order eustatic cycles. A similar interplay of tectonism and eustasy is recognizable in the whole middle Miocene sedimentary succession deposited on the forebulge flank, demonstrating an extreme case of an accommodation‐controlled shelf and indicating tectonic cycles of the forebulge uplift and subsidence spanning ca 800 to 900 ka. The episodes of forebulge uplift correlate with the main pulses of orogen thrusting. The resulting composite peripheral unconformity differs markedly from the idealized model of a ‘steady‐state’ stepwise onlap driven by forebulge continuous retreat. It is concluded that the foredeep peripheral unconformities, instead of being simplified in accordance with this idealized model, should rather be studied in detail because they bear a valuable high‐resolution record of regional events and give unique insights into the local role of tectonics, eustasy and sediment supply.     

Cerium and Ytrium in apatite as records of magmatic processes: Insight into fractional crystallization,magma mingling and fluid saturation

Apatite is a versatile mineral crystallizing at different stages of silicic magma evolution. Its composition may record that of magma, but could also be affected by interaction with fluids. The focus of this study is the well-recognized magma mingling process that was previously detected using plagioclase composition and in this study complementary record is sought in apatite. The apatite was analysed in two dioritic enclaves (primitive and hybrid) and host quartz monzonite, which is an igneous rock emplaced at ca. 340 Ma in mylonitized Góry Sowie gneisses (NE Bohemian Massif). The apatite was analysed in-situ by microprobe that allowed for chemical characterization of different apatite populations in quartz monzonite and analyses of thin acicular apatite in the enclaves. Apatite population in the quartz monzonite was chemically distinct from that in both enclave types and characterized by higher Y and lower Ce contents, such values are usually typical for peraluminous magmas. As such, the apatite transfer from felsic to mafic magma should be well recorded in apatite composition, which was not the case. Monzonite apatite composition was not commonly observed in the hybrid enclave despite massive plagioclase transfer and only rare resorbed cores with low Ce and Y contents were present. However, such low Ce and Y cores crystalized at the latest stage of apatite crystallization in the quartz monzonite, whereas the plagioclase transfer was an early episode. Therefore, we conclude that apatite transfer was limited during mingling and the apatite composition in the quartz monzonite is best explained by an early Cl-Ce-rich fluid removal and then fractional crystallization, while apatite in the primitive enclave is affected only by fractional crystallization. Altogether, Ce and Y composition of apatite is a valuable tool to record diverse magmatic processes such as fluid removal and precipitation from fluid in addition to fractionation of different REE phases and should be further explored.     

Stable 18O and 13C isotope records of Viviparus diluvianus (Kunth, 1865) shells from Holsteinian (MIS 11) lakes of eastern Poland as palaeoenvironmental and palaeoclimatic proxies

The oxygen and carbon stable isotope composition of Viviparus diluvianus shells was determined in the palaeolakes of the Holsteinian interglacial (MIS 11) in eastern Poland: the Ortel Królewski, Hrud, Ossówka, Roskosz and Szymanowo lakes. The occurrence of V. diluvianus covers the Taxus zone, the so‐called intra‐interglacial cooling period (Pinus‐Larix zone), the climatic optimum (Carpinus‐Abies zone) and the post‐optimal period with an undefined pollen zone. The isotope record of V. diluvianus shells allowed palaeoclimate and palaeoenvironmental reconstructions. δ¹⁸O and δ¹³C vary from −8.7‰ in the post‐optimal period to −4.8‰ in the optimal period, and from −10.6‰ at the beginning of the Taxus zone to −4.2‰ at the climatic optimum, respectively. A positive correlation of the isotope curves indicates closed‐water bodies, and only at Roskosz was some occasional overflow inferred. Higher oxygen isotopes correspond to an increase in temperature and/or enhanced evaporation, which is well marked in the Carpinus‐Abies zone, whereas samples enriched in ¹³C are correlated with periods demonstrating a lower water level and higher productivity in the lakes. Episodes of lake shallowing and dense aquatic vegetation occurred in the Pinus‐Larix zone and during the climatic optimum. The isotope ratios for the climatic optimum significantly exceed those of the other periods, thus pointing to warmer conditions. An estimation of relative changes of average summer temperatures using the δ¹⁸O/temperature gradient yielded variation of 1–2 °C within the lakes. Absolute temperature reconstructions indicate the effects of specific local conditions. Hence, V. diluvianus shells offer a reliable proxy in qualitative studies of interglacial lake records.