Characteristics and implications of some Loch Lomond Stadial moraine ridges and later landforms,eastern Lake District,northern England

Moraine ridges and mounds of inferred Loch Lomond Stadial (LLS) age have been mapped at three sites (Fordingdale, Swindale and Wet Sleddale) in part of the eastern Lake District, northern England, and indicate glaciers were more widespread than envisaged by Sissons (1980, Transactions of the Royal Society of Edinburgh: Earth Sciences, Vol. 71, pp. 13–27). The moraines delimit closely the downslope/downvalley limits of the former glaciers but there is no geomorphological evidence with which to define their upslope/upvalley margins. The former glaciers are considered to have been nourished within the confines of their individual valley, cirque and hillside embayment respectively, rather than being outlet glaciers of plateau icefields. Estimated equilibrium line altitudes (ELAs) are within the range of values determined previously for LLS glaciers in the Lake District and do not necessitate revision of established palaeoclimatic parameters. Individual ELAs were probably influenced by local factors; all three former glaciers had accumulation-area aspects between north and east, limiting the impact of direct solar radiation during the ablation season, and were adjacent to extensive areas of high ground to the west and/or south that would have facilitated transfer of snow to their surfaces by winds from those directions. In Fordingdale, three essentially contemporaneous depositional landforms occur upslope of the moraines and are considered to represent hillslope adjustments following wastage of glacier ice from the site. © 1998 John Wiley & Sons, Ltd.     

A New Specimen of Liaoceratops yanzigouensis (Dinosauria:Neoceratopsia) from the Early Cretaceous of Liaoning Province, China

A new specimen of basal neoceratopsian dinosaur Liaoceratops yanzigouensis is described. The specimen comes from the Lujiatun Bed of the Lower Cretaceous Yixian Formation in Beipiao City of western Liaoning Province, and is represented by a very well preserved three-dimensional partial skull and mandible. It is also the smallest among the three specimens of L. yanzigouensis, and several features in the new specimen, such as the short preorbital length and the round rostroventral orbital rim, can be ontogenetically-related. The superb exposure of the palatal complex may be caused by the removing of its brain by a small predator in the contemporary Jehol Biota.     

Groundwater-level response to land-use change and the implications for salinity management in the West Moorabool River catchment, Victoria, Australia

The connection between the removal of native vegetation, rising water tables and increasing stream salinity has been established for many catchments across Australia. However, the West Moorabool River in south west Victoria is an example of a catchment where there has been little discernable effect on groundwater levels following land clearing. Over the past 150 years, a significant portion of the catchment has been cleared of dense forest for agricultural development. Historic standing water-level records from 1870–1871 and 1881 are compared with contemporary measurements (1970s to 2007) recorded in the government bore databases. The data show that the earliest recorded groundwater levels are well within the seasonal range of values observed today. By integrating geology and hydrogeology with historical observations of groundwater levels, climate data and land use, the contemporary field observations of stream salinity are linked to the changed water use and shift in rainfall. In contrast to the normally accepted axiom, reafforestation as a management strategy to mitigate the rising salinity in the West Moorabool River catchment would seem inappropriate.     

Polycyclic aromatic hydrocarbon concentrations in urban soils representing different land use categories in Shanghai

An extensive soil survey was carried out in Shanghai to investigate the spatial distribution and possible sources of polycyclic aromatic hydrocarbons (PAHs) in urban soils. Soil samples were collected from highways, iron-smelting plants, steel-smelting plants, shipbuilding yards, coking plants, power plants, chemical plants, urban parks, university campuses and residential areas and were analyzed for 16 PAHs by gas chromatography with mass detection. High PAH concentrations were found in all locations investigated, with mean values of soil total PAH concentrations in the range 3,279–38,868 μg/kg DM, and the PAH concentrations were significantly influenced by soil organic matter content. Soil PAH profiles in all districts were dominated by PAHs with 4–6 rings. Principal components analysis and diagnostic ratios of PAHs indicate that they were mainly derived from coal combustion and petroleum but in soils from highways the PAHs were derived largely from vehicle exhaust emissions. The high concentrations of PAHs found indicate that many urban soils in Shanghai represent a potential hazard to public health.     

A kinetic approach to describe trace-element distribution between particles and solution in natural aquatic systems

The partitioning of radioactive trace elements between seawater and particulate matter from surface sediments and sediment traps was investigated in laboratory experiments. For the elements Na, Zn, Se, Sr, Cd, Sn, Sb, Cs, Ba, Hg, Th and Pa (group I) constant distribution coefficients (K_d) were found after a few days of equilibration, whereas the elements Be, Mn, Co and Fe (group II) showed an increasing K_d over the whole time of observation of 108 days. The time dependence of K_d is described by an adsorption-desorption equilibrium (group I elements), followed by a lattice transport reaction step (group II elements). The reaction rate constants are compared to Mn oxidation rates and to adsorption rate constants derived from in situ measurements of the $\text{U}\text{Th}$ disequilibrium as available from literature.     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

Large-scale laboratory experiment on erosion of sand beds by moving circular vertical jets

This study investigates the topographic deformation due to the erosion of a sand bed impinged by a moving submerged turbulent round jet in a large-scale laboratory. The test conditions represent the case of discharges beneath a vessel while operating in water with a limited clearance such as a shallow navigation channel. The jet moves horizontally and discharges water vertically downward towards the bed. The distance between the jet nozzle and the bed equals six times the jet diameter so the jet flow is in the potential core region. The speed of the jet horizontal motion was varied to examine its effect on the scour profile. The characteristic lengths of the scour profile in the asymptotic state were determined by modifying the empirical formulas in Aderibigbe and Rajaratnam [1996. Erosion of loose beds by submerged circular impinging vertical turbulent jets. Journal of Hydraulic Research 34(1), 19–33]. The maximum scour depth, the scour hole radius, and the ridge height were found to be a function of the ratio of the jet exit to jet translation velocities and were modeled using a hyperbolic function. Empirical equations describing the scour profile were developed and the scour profile was found to be self-similar when normalized by appropriate length scales.     

Thermodynamic characterization of boltwoodite and uranophane: Enthalpy of formation and aqueous solubility

Boltwoodite and uranophane are uranyl silicates common in oxidized zones of uranium ore deposits. An understanding of processes that impact uranium transport in the environment, especially pertaining to the distribution of uranium between solid phases and aqueous solutions, ultimately requires determination of thermodynamic parameters for such crystalline materials. We measured formation enthalpies of synthetic boltwoodites, K(UO₂)(HSiO₄)·H₂O and Na(UO₂)(HSiO₄)·H₂O, and uranophane, Ca(UO₂)₂(HSiO₄)₂·5H₂O, by high temperature oxide melt solution calorimetry. We also studied the aqueous solubility of these phases from both saturated and undersaturated conditions at a variety of pH. The combined data permit the determination of standard enthalpies, entropies and Gibbs free energies of formation for each phase and analysis of its potential geological impact from a thermodynamic point of view.