Dynamic partial melting: its application to the petrogeneses of basalts erupted in Iceland,the Faeroe Islands,the Isle of Skye (Scotland) and the Troodos Massif (Cyprus)

The lava piles erupted in Iceland, the Faeroes, Skye, and Troodos are vertically compositionally zoned with the most Mg-rich and hygromagmatophile element (HE) depleted basalts concentrated towards the top of the lava pile in each case. The observed variations in the REE in the Mg-rich basalts from each lava pile cannot be explained in terms of batch partial melting of a homogeneous upper mantle source. Dynamic partial melting (Langmuiret al., 1977, Earth Planet. Sci. Lett.36, 133–156), in conjunction with, or in some cases as a possible alternative to postulating local inhomogeneities in the upper mantle source region, can explain the vertical chemical variations. In this model the presence and amount of liquid remaining in the residue has an important effect on the HE composition of subsequent melts, i.e. it introduces an additional variable to the incremental partial melting equation. The REE variation observed can be accurately reproduced by numerical models of dynamic partial melting using appropriate source compositions.The small but significant, radiogenic isotope variations in Icelandic basalts, whilst suggesting inhomogeneities in the source regions also lend some support to the dynamic melting process. In at least some of the HE-depleted basalts the Sm/Nd ratios are too high to explain the measured ¹⁴³Nd/¹⁴⁴Nd ratios for a single stage mantle evolution. It is necessary to infer a recent enrichment of the Sm/Nd ratios in their sources—an event predicted by the continuous melting process.The chemical inhomogeneities required in the mantle beneath Iceland are consistent with an HE depleted source region-veined to varying degrees by fluids or magmas related to previous events of melt transfer. Dynamic partial melting of such a mantle source would result in the vertical chemical zonation of a lava pile if the source was not continuously replenished at depth.     

Activity-composition relationships for pyrope-grossular garnet

Activity coefficients () for grossular in pyrope-grossular garnet have been determined experimentally using the divariant assemblage garnet-anorthite-sillimanite (kyanite)-quartz. Values of for garnets with 10–12 mole % grossular have been obtained at 1000 °, 1100 °, 1200 ° and 1300 ° C at pressures between 15 and 21 Kb. The data are consistent with a symmetrical regular solid model for grossular-pyrope solid solutions. The interaction parameter (W) increases linearly with decreasing temperature and is given by W = 7460-4.3 T cals (T in °K). A solvus in the pyrope-grossular solid solution is predicted with a temperature of critical mixing of 629°C±90 ° C.     

The influence of pressure,temperature and bulk composition on the appearance of garnet in orthogneisses — an example from South Harris,Scotland

Granulite facies metamorphism of the igneous complex of South Harris has produced garnet-clinopyroxene-plagioclase assemblages from olivine-normative rocks and 2 pyroxene-plagioclase-quartz assemblages from quartz-normative rocks. The appearance of garnet can be considered in terms of two complex reactions:Olivine + plagioclase₁ → (Ca, Mg, Fe) garnet + plagioclase₂(olivine-normative) (A)Orthopyroxene + plagioclase₁ → (Ca, Mg, Fe) garnet + plagioclase₂ + quartz (quartz-normative) (B)For bulk compositions of the South Harris rocks the equilibrium pressure for reaction (A) has been exceeded whereas that for reaction (B) was not reached. Estimated physical conditions of metamorphism bracketed by these and other reactions are: 800–860°C and 10–13 kbar. These estimates, based on experimental data on simple systems combined with thermodynamic models of the solid solutions involved are in good agreement with extrapolated pressures for the experimentally determined appearance of garnet in basaltic compositions (Green and Ringwood, 1967). The latter give 9–12 kbar in the temperature range of interest. The calculations are also consistent with the occurrence of kyanite in associated metapelites and with the stability of spinel-lherzolite during the granulite metamorphism.     

Aluminum coordination in metaaluminous and peralkaline silicate melts

Incremental amounts of Na₂O and K₂O added to immiscible melts in the MgO-CaO-TiO₂-Al₂O₃ SiO₂ system cause a decrease in critical temperature, phase separation and change in the pattern of Al₂O₃ partitioning. Al₂O₃, which is concentrated in the low SiO₂ immiscible melts in the alkali-free system, is increasingly partitioned into the high-SiO₂ immiscible melt as the alkali/aluminium ratio is increased. However, K₂O is more effective than Na₂O in stabilizing Al₂O₂ in the SiO₂-rich melt. The coordination changes occurring in the aluminosilicate melts upon the addition of the alkali oxides are described by CaAl₂O₄+2SiOK=2KAlO₂+SiOCaOSi where K (or Na) displaces Ca as the charge-balancing cation for the networkforming AlO₄ tetrahedra. The increased stability of the AlO₄ species in the highly polymerized SiO₂-rich melt and the consequent shrinkage of the miscibility gap is ascribed to positive configurational entropy and negative enthalpy changes associated with the formation of K, Na-AlO₄ species. Element partition systematics indicate that (Na, K)AlO₂ species favor the more polymerized, CaAl₂O₄ and TiO₂ species, the less polymerized silicate structure in the melt.     

Origin of Archean anorthosites: Evidence from the Bad Vermilion Lake anorthosite complex,Ontario

The Bad Vermilion Lake anorthosite complex (2,700 m.y.) is exposed over an area of about 100 km² near Rainy Lake, Ontario. As is typical of other Archean anorthosites, it is composed of coarse (1–30 cm across), equidimensional, euhedral to subhedral, calcic (An₈₀) plagioclase, in a finer grained mafic matrix. The amount of mafic matrix in individual samples ranges from none to about 70% by volume. The complex has been variably metamorphosed to greenschist facies. Zoisite, chlorite, and hornblende are abundant, but primary plagioclase is preserved in many places. The anorthosite complex is associated with gabbro and with mafic to felsic metavolcanic rocks, and is cut by tonalite plutons and by mafic dikes. Some gabbros contain local concentrations of Fe-Ti oxides and/or apatite, but no chromite. The mafic groundmass of the anorthositic rocks is similar in major and trace element chemistry, including rare earth elements, to the associated basaltic metavolcanics, suggesting that the anorthositic complex may have accumulated from a subvolcanic magma chamber which fed mafic lavas to the surface during its crystallization. Mafic flows and dikes chemically similar to the mafic metavolcanics contain plagioclase megacrysts akin to those of the anorthositic rocks, and thus may represent a link between the anorthosite complex and associated mafic lavas. Elongate pretectonic tonalite intrusions were comagmatic with the felsic metavolcanics, but not with the anorthosites or metabasalts. These silicic rocks may represent low-pressure partial melts of the mafic rocks. There is no direct or indirect evidence for significant volumes of ultramafic material at the present exposure level of the complex. An estimate of the bulk composition of all rocks presumed to be comagmatic with the anorthosites, including gabbros and mafic metavolcanics, is an aluminous basalt with about 20 wt.% Al₂O₃. This composition has REE abundances unlike those of typical Archean high-Al basalts and probably does not represent that of a primary or evolved melt. The possibility must be considered, therefore, that a substantial fraction of material comagmatic with the anorthosites has been separated from the complex, either by magmatic or tectonic processes.     

Potential Implications of PCM Climate Change Scenarios for Sacramento–San Joaquin River Basin Hydrology and Water Resources

The potential effects of climate change on the hydrology and water resources of the Sacramento–San Joaquin River Basin were evaluated using ensemble climate simulations generated by the U.S. Department of Energy and National Center for Atmospheric Research Parallel Climate Model (DOE/NCAR PCM). Five PCM scenarios were employed. The first three were ensemble runs from 1995–2099 with a `business as usual' global emissions scenario, eachwith different atmospheric initializations. The fourth was a `control climate'scenario with greenhouse gas emissions set at 1995 levels and run through 2099. The fifth was a historical climate simulation forced with evolving greenhouse gas concentrations from 1870–2000, from which a 50-yearportion is taken for use in bias-correction of the other runs. From these global simulations, transient monthly temperature and precipitation sequences were statistically downscaled to produce continuous daily hydrologic model forcings, which drove a macro-scale hydrology model of theSacramento–San Joaquin River Basins at a 1/8-degree spatial resolution, and produceddaily streamflow sequences for each climate scenario. Each streamflow scenario was used in a water resources system model that simulated current and predicted future performance of the system. The progressive warming of the PCM scenarios (approximately 1.2 °C at midcentury, and 2.2 °C by the 2090s), coupled with reductions in winter and spring precipitation (from 10 to 25%), markedly reduced late spring snowpack (by as much as half on average by the end of the century). Progressive reductions in winter, spring, and summer streamflow were less severe in the northern part of the study domain than in the south, where a seasonality shift was apparent. Results from the water resources system model indicate that achieving and maintaining status quo (control scenario climate) system performance in the future would be nearly impossible, given the altered climate scenario hydrologies. The most comprehensive of the mitigation alternatives examined satisfied only 87–96% of environmental targets in the Sacramento system, and less than 80% in the San Joaquin system. It is evident that demand modification and system infrastructure improvements will be required to account for the volumetric and temporal shifts in flows predicted to occur with future climates in the Sacramento–San JoaquinRiver basins.