Nitrogen in chondritic metal

We report new nitrogen isotopic data in metals of H-, L- and one LL -chondrites, with N abundances in the range of ∼0.3 to 3.3 ppm and half of these <1 ppm. Nitrogen isotopic signatures in metals with low indigenous N concentrations are modified by cosmic ray spallation components; corrections are required to determine the indigenous N signatures. The metals of type 4 and 5 show uniform indigenous nitrogen (δ¹⁵N = −6.8 ± 0.5 ‰) and confirm a reported possible genetic association of chondritic metal with metal in IIE and IVA iron meteorites. Distinct isotopic signatures are observed in two metal samples of the Portales Valley (H6) meteorite which both are inconsistent with signatures in H4 and H5 chondrites, but possibly reveal a record of impact-induced melting and metamorphism on the parent asteroid. Anomalous nitrogen signatures in metals of type 3 chondrites, on the other hand, may reflect residues of surviving presolar isotopic signatures.     

Nitrogen and argon isotopic signatures in graphite from the 3.8-Ga-old Isua Supracrustal Belt, Southern West Greenland

The problems involved with the interpretation of carbon isotopes as indicators for early life in highly metamorphosed early Archean rocks have prompted the search for additional chemical and isotopic biomarkers. Here we report an attempt to identify the origin of carbonaceous matter in the 3.8 Ga old Isua Supracrustal Belt in southern West Greenland by measuring the concentration and isotopic composition of a trapped nitrogen component. Stepped-combustion/pyrolysis-mass spectrometry of carbonaceous matter in several rock samples revealed three different reservoirs of trapped nitrogen: (1) nitrogen associated with a very small amount of reactive carbonaceous material, (2) nitrogen intercalated in graphite, correlated with intercalated radiogenic argon, (3) nitrogen strongly retained at defects or chemically bound in the graphite structure. The δ¹⁵N of nitrogen associated with reactive carbonaceous matter (ca. +6‰) overlaps with that of average Phanerozoic sedimentary organic matter, and is believed to be part of nonindigenous postmetamorphic biologic material. In situ Raman spectroscopy confirmed the high degree of crystallinity of the metamorphosed indigenous carbonaceous material, and this material is further referred to as graphite. Graphite interpreted as epigenetic (associated with Mg,Mn-siderite in metacarbonates) contains a very small strongly retained nitrogen component with a low δ¹⁵N ratio (−3 to −1‰). This range overlaps with values that are typically found in Archean kerogens, but also those of a metamorphically emplaced inorganic basaltic source. Geological constraints suggest that this graphite incorporated nitrogen from surrounding metabasaltic rocks. Graphite interpreted as syngenetic and biogenic found in a turbidite deposit is relatively similar to this Mg,Mn-siderite-derived graphite, based on degree of graphite crystallinity, amount of trapped radiogenic argon, low nitrogen concentration and δ¹⁵N signature. We conclude that nitrogen concentration and its isotope ratio in graphite cannot be used conclusively as a biomarker in these rocks from the highly metamorphosed Isua Supracrustal Belt.     

Groundwater overdraft vulnerability and environmental impact assessment in Arusha

A simple approach is proposed for identifying areas vulnerable to groundwater overdraft. The methodology utilizes GIS techniques to analyze and evaluate controlling factors in areas with little data. The proposed methodology was applied in Arusha. Water demand in Arusha Municipality and its environs has increased to about 5.3% annually since 1999. Groundwater levels have declined. The aquifer hydrogeological variables were evaluated for impact to potential groundwater overdraft by overlay and index techniques. The spatial distribution of overdraft vulnerability was discussed. The northwestern part of Arusha is the most vulnerable to overdraft and possible serious environmental impacts. The Loruvani area has the most potential for aquifer development due to its permeability, high recharge rate, massive aquifer thickness and low drawdown.     

Representative sampling of sandy fluvial gravels

Data obtained from two streams indicate that the surficial and underlying bed material in streams with sandy-gravel beds should be sampled independently, in order to facilitate the detection of segregated (armoured/paved) gravel surfaces, and obviate any bias in the particle-size distribution of the bed-material samples that might arise from the inclusion of a proportion of the surficial bed material in a volumetric sample.     

Northward migration under a changing climate: a case study of blackgum (Nyssa sylvatica)

Species are predicted to shift their distribution ranges in response to climate change. Region-wide, empirically-based studies, however, are still limited to support these predictions. We used a model tree species, blackgum (Nyssa sylvatica), to study climate-induced range shift. Data collected from two separate sampling periods (1980s and 2007) by the USDA’s Forestry and Inventory Analysis (FIA) Program were used to investigate changes in abundance and dominance, and shifts in distribution, of blackgum in four ecoregions of the eastern United States. Our results indicated new recruitment of blackgum in the northern portion of its range, along with increases in both density and annual rates of change in importance value (IV). Conversely, declines in recruitment were found in the southern portion of blackgum’s range, along with decreases in density and IV. The center portion of blackgum’s range had mixed patterns of change (i.e., both increases and decreases) throughout. A northward range expansion was also detected by comparing blackgum’s historic range to where it was detected during our two more-recent sampling periods. Our findings suggest that blackgum is migrating north in response to climate change. Our study also suggests two broader implications about tree migration patterns in response to climate change: (1) species can respond to changing climate in relatively short time periods, at least for generalist species such as blackgum, and (2) climate-induced vegetation dynamic patterns can be detected at the regional level, but are inherently complex.     

Prospect for UV observations from the Moon

Space astronomy in the last 40 years has largely been done from spacecraft in low Earth orbit (LEO) for which the technology is proven and delivery mechanisms are readily available. However, new opportunities are arising with the surge in commercial aerospace missions. We describe here one such possibility: deploying a small instrument on the Moon. This can be accomplished by flying onboard the Indian entry to the Google Lunar X PRIZE competition, Team Indus mission, which is expected to deliver a nearly 30 kgs of payloads to the Moon, with a rover as its primary payload. We propose to mount a wide-field far-UV (130–180 nm) imaging telescope as a payload on the Team Indus lander. Our baseline operation is a fixed zenith pointing but with the option of a mechanism to allow observations of different attitudes. Pointing towards intermediate ecliptic latitude (50^° or above) ensures that the Sun is at least 40^° off the line of sight at all times. In this position, the telescope can cover higher galactic latitudes as well as parts of Galactic plane. The scientific objectives of such a prospective are delineated and discussed.     

Spatio-temporal variation in radon concentration in groundwater with respect to rock types: A case study from Chitradurga district,Karnataka

An attempt was made in the present study to delineate how the radon concentrations vary with respect to different geological formations and to evaluate annual effective dose exposure due to ingestion of radon. A total of 60 groundwater samples were collected from layered sequential aquifers in Chitradurga district having major rock types such as Bababudan Group, Charnockite, Chitradurga Group, Closepet granite, migmatites and granodiorite — tonalitic gneisses and Sargur Schist complex during pre-monsoon and post-season of the year 2011. Radon measurement was made using Durridge RAD-7 radon-in-air monitor, connected to RAD H₂O accessory with closed loop aeration concept. In the present study, the radon activity ranged from 0 to 186.6 Bq/L and 0 to 150.6 Bq/L during pre- and post-monsoon seasons of the year 2011, with 56.67 % (17 samples) of samples during both the seasons exceeding the EPA’s MCL value of 11.1 Bq/L. The annual mean radon activity in the groundwater was higher in the area having Chitradurga rock group formations (78.1 Bq/L) followed by Sargur-Satyamangalam schist complex group (56.8 bq/L), migmatites and granodiorite — tonalitic Gneisses group (56.3 Bq/L), Closepet granite (42.7 Bq/L), Charnonkite (29.1 Bq/L) and Bababudan Group (22.2 Bq/L). It is inferred that radon concentration found to depend on the tectonic structure, geology of the area and on the presence of uranium minerals in these rocks. The annual effective dose resulting from radon in groundwater in the Chitradurga district were significantly lower than UNSCEAR and WHO recommended limit of 1 mSv/y.