Spurenelemente in der Aare (Schweiz)

Instrumental neutron activation analysis was used for the determination of more than 20 trace and minor elements in water and silt samples (suspended load) of the river Aare. The samples were collected at four different locations along the river between its source and the lake of Bienne. The principal results are: 1. The concentrations of all elements investigated are much lower than WHO-limits for drinking water. 2. Human activities are responsible for an increase of some elements along the river. 3. The concentrations of dissolved trace elements are generally anticorrelated with the water flow rate. 4. The concentrations of the trace elements in particulates (in μg/l) are correlated with the flow rate of water. Except for Ca?Sr there are no significant interelement correlations for all four sampling stations.     

An on Orbit Determination of Point Spread Functions for the <Emphasis Type="Italic">Interface Region Imaging Spectrograph</Emphasis>

Using the 2016 Mercury transit of the Sun, we characterize on orbit spatial point spread functions (PSFs) for the Near- (NUV) and Far- (FUV) Ultra-Violet spectrograph channels of NASA’s Interface Region Imaging Spectrograph (IRIS). A semi-blind Richardson–Lucy deconvolution method is used to estimate PSFs for each channel. Corresponding estimates of Modulation Transfer Functions (MTFs) indicate resolution of 2.47 cycles/arcsec in the NUV channel near 2796 Å and 2.55 cycles/arcsec near 2814 Å. In the short (\({\approx}\,1336~\mathring{\mathrm{A}}\)) and long (\({\approx}\,1394~\mathring{\mathrm{A}}\)) wavelength FUV channels, our MTFs show pixel-limited resolution (3.0 cycles/arcsec). The PSF estimates perform well under deconvolution, removing or significantly reducing instrument artifacts in the Mercury transit spectra. The usefulness of the PSFs is demonstrated in a case study of an isolated explosive event. PSF estimates and deconvolution routines are provided through a SolarSoft module.     

The Impact of New EUV Diagnostics on CME-Related Kinematics

We present the application of novel diagnostics to the spectroscopic observation of a Coronal Mass Ejection (CME) on disk by the Extreme Ultraviolet Imaging Spectrometer (EIS) on the Hinode spacecraft. We apply a recently developed line profile asymmetry analysis to the spectroscopic observation of NOAA AR 10930 on 14?–?15 December 2006 to three raster observations before and during the eruption of a 1000 km?s^?1 halo CME. We see the impact that the observer’s line-of-sight and magnetic field geometry have on the diagnostics used. Further, and more importantly, we identify the on-disk signature of a high-speed outflow behind the CME in the dimming region arising as a result of the eruption. Supported by recent coronal observations of the STEREO spacecraft, we speculate about the momentum flux resulting from this outflow as a secondary momentum source to the CME. The results presented highlight the importance of spectroscopic measurements in relation to CME kinematics, and the need for full-disk synoptic spectroscopic observations of the coronal and chromospheric plasmas to capture the signature of such explosive energy release as a way of providing better constraints of CME propagation times to L1, or any other point of interest in the heliosphere.     

Transverse Oscillations in Coronal Loops Observed with TRACE – II. Measurements of Geometric and Physical Parameters

Solar Physics - We measure geometric and physical parameters oftransverse oscillations in 26 coronal loops, out of the 17 events described in Paper I by Schrijver, Aschwanden, and Title (2002)....     

The High-Resolution Coronal Imager (Hi-C)

The High-Resolution Coronal Imager (Hi-C) was flown on a NASA sounding rocket on 11 July 2012. The goal of the Hi-C mission was to obtain high-resolution (≈?0.3?–?0.4′′), high-cadence (≈?5 seconds) images of a solar active region to investigate the dynamics of solar coronal structures at small spatial scales. The instrument consists of a normal-incidence telescope with the optics coated with multilayers to reflect a narrow wavelength range around 19.3 nm (including the Fe xii 19.5-nm spectral line) and a 4096×4096 camera with a plate scale of 0.1′′?pixel^?1. The target of the Hi-C rocket flight was Active Region 11520. Hi-C obtained 37 full-frame images and 86 partial-frame images during the rocket flight. Analysis of the Hi-C data indicates the corona is structured on scales smaller than currently resolved by existing satellite missions.     

Modeling uncertainty of moving objects on road networks via space–time prisms

Moving objects produce trajectories, which are typically observed in a finite sample of time‐stamped locations. Between sample points, we are uncertain about the moving objects's location. When we assume extra information about an object, for instance, a (possibly location‐dependent) speed limit, we can use space–time prisms to model the uncertainty of an object's location.

Until now, space–time prisms have been studied for unconstrained movement in the 2D plane. In this paper, we study space–time prisms for objects that are constrained to travel on a road network. Movement on a road network can be viewed as essentially one‐dimensional. We describe the geometry of a space–time prism on a road network and give an algorithm to compute and visualize space–time prisms. For experiments and illustration, we have implemented this algorithm in MATHEMATICA.

Furthermore, we study the alibi query, which asks whether two moving objects could have possibly met or not. This comes down to deciding if the chains of space–time prisms produced by these moving objects intersect. We give an efficient algorithm to answer the alibi query for moving objects on a road network. This algorithm also determines where and when two moving objects may have met.     

The geometry of space-time prisms with uncertain anchors

Space-time prisms envelop all spatio-temporal locations that moving objects may have visited between two of their known spatio-temporal locations, given a bound on their travel speed. In this context, the known locations are often the result of observations or measurements, and they are called ‘anchor points’. The classic space-time prism, in isotropic two-dimensional space, as well as in transportation networks, assumes that the measurements of these anchor points are exact. Whereas, in many applications, we can assume that time can be measured fairly precisely, this assumption is unrealistic for the spatial components of measured locations (we think of Global Positioning System (GPS) errors, for instance). In this paper, we extend the classical prism from anchor points to circular ‘anchor regions’ that capture the uncertainty or error on their measurement. We define the notion of a space-time prism with uncertain anchor points, called uncertain prism, for short. We study the geometry of uncertain prisms in an arbitrary metric space to make this concept as widely applicable as possible. We also focus on the rims of uncertain space-time prisms, which demarcate the area that a moving object can have visited between two anchor regions (given some local speed limitations).     

Stable isotopes and trace elements in modern ostracod shells: implications for reconstructing past environments on the Tibetan Plateau,China

Stable isotopes and trace elements in ostracod shells have been used widely in paleolimnological investigations of past lake hydrochemistry and climate because they provide insights into past water balance and solute evolution of lakes. Regional differences in lake characteristics and species-specific element fractionation, however, do not permit generalization of results from other regions or ostracod species to the southern Tibetan Plateau, in part because most common taxa from the southern Tibetan Plateau are endemic to the area. This study evaluated relations between present-day environmental conditions and the geochemical composition of modern ostracod shells from the southern Tibetan Plateau, to assess the suitability of using shell chemistry to infer hydrological conditions. We studied nine lakes and their catchments, located along a west–east transect in the south-central part of the Tibetan Plateau. Stable oxygen and carbon isotope values and trace element concentrations in recent shells from the four most abundant ostracod species (Leucocytherella sinensis, ?Leucocythere dorsotuberosa, Limnocythere inopinata, Tonnacypris gyirongensis) were measured, together with hydrochemical properties of host waters at the time of sampling. Results revealed significant between-species differences in stable isotope fractionation and trace element incorporation into shell calcite. Stable oxygen and carbon isotope values of ostracod shells were correlated significantly with the stable isotope composition of the respective water body \( \left( {\updelta^{18} {\text{O}}_{{{\text{H}}_{ 2} {\text{O}}}} \,{\text{and }}\updelta^{13} {\text{C}}_{{{\text{H}}_{ 2} {\text{O}}}} } \right) \), reflecting salinity and productivity, respectively. Offsets between δ¹⁸O_shell and δ¹³C_shell and inorganic calcite, the latter representing isotopic equilibrium, suggest shell formation of T. gyirongensis during spring melt. L. sinensis reproduces throughout the monsoon season until September and shows several consecutive generations, and L. inopinata molts to the adult stage after the monsoon season in August/September. The influence of pore water δ¹³C was displayed by L. inopinata, suggesting shell calcification within the sediment. Mg/Ca_shell is primarily influenced by water Mg/Ca ratios and salinity and confirms the use of this shell ratio as a proxy for precipitation-evaporation balance and lake level. In addition, Sr/Ca and Ba/Ca can be used to infer changes in salinity, at least in closed-basin lakes with calcite saturation. Observed effects of water Sr/Ca and salinity on Sr/Ca incorporation are biased by the presence of aragonite precipitation in the lakes, which removes bioavailable Sr from the host water, resulting in low Sr/Ca_shell values. Changes in carbonate mineralogy affect the bioavailability of trace elements, a process that should be considered in paleoclimate reconstructions. Oxygen isotopes and Mg/Ca_shell ratios were unaffected by water temperature. Positive correlations among Fe/Ca, Mn/Ca and U/Ca in ostracod shells, and their negative correlation with δ¹³C, which reflects organic matter decay, show the potential to infer changes in redox conditions that can be used to reconstruct past oxygen supply to bottom waters and thus past water-circulation changes within lakes. The intensity of microbial activity, associated with organic matter decomposition, can be inferred from U/Ca ratios in ostracod shells. These findings highlight the value of fossil ostracod records in lake deposits for inferring paleoenvironmental conditions on the southern Tibetan Plateau.     

Multi-scale aquifer characterization and groundwater flow model parameterization using direct push technologies

Direct push (DP) technologies are typically used for cost-effective geotechnical characterization of unconsolidated soils and sediments. In more recent developments, DP technologies have been used for efficient hydraulic conductivity (K) characterization along vertical profiles with sampling resolutions of up to a few centimetres. Until date, however, only a limited number of studies document high-resolution in situ DP data for three-dimensional conceptual hydrogeological model development and groundwater flow model parameterization. This study demonstrates how DP technologies improve building of a conceptual hydrogeological model. We further evaluate the degree to which the DP-derived hydrogeological parameter K, measured across different spatial scales, improves performance of a regional groundwater flow model. The study area covers an area of ~60 km² with two overlying, mainly unconsolidated sand aquifers separated by a 5–7 m thick highly heterogeneous clay layer (in north-eastern Belgium). The hydrostratigraphy was obtained from an analysis of cored boreholes and about 265 cone penetration tests (CPTs). The hydrogeological parameter K was derived from a combined analysis of core and CPT data and also from hydraulic direct push tests. A total of 50 three-dimensional realizations of K were generated using a non-stationary multivariate geostatistical approach. To preserve the measured K values in the stochastic realizations, the groundwater model K realizations were conditioned on the borehole and direct push data. Optimization was performed to select the best performing model parameterization out of the 50 realizations. This model outperformed a previously developed reference model with homogeneous K fields for all hydrogeological layers. Comparison of particle tracking simulations, based either on the optimal heterogeneous or reference homogeneous groundwater model flow fields, demonstrate the impact DP-derived subsurface heterogeneity in K can have on groundwater flow and solute transport. We demonstrated that DP technologies, especially when calibrated with site-specific data, provide high-resolution 3D subsurface data for building more reliable conceptual models and increasing groundwater flow model performance.