Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.     

Lithospheric mantle beneath NE part of Bohemian Massif and its relation to overlying crust: new insights from Pilchowice xenolith suite,Sudetes, SW Poland

International Journal of Earth Sciences - The Oligocene/Miocene basanite from Pilchowice (Sudetes Mts., SW Poland) carries numerous small xenoliths of mantle peridotite, mostly harzburgite. The...     

Contrasting sources of Late Paleozoic rhyolite magma in the Polish Lowlands: evidence from U–Pb ages and Hf and O isotope composition in zircon

International Journal of Earth Sciences - The Polish Lowlands, located southwest of the Teisseyre–Tornquist Zone, within Trans-European Suture Zone, were affected by bimodal, but dominantly...     

Impact of a Jet A-1/HEFA blend on the performance and emission characteristics of a miniature turbojet engine

It is forecast that in the future, alternative fuels derived from non-petroleum sources will become the basic propellant for turbine aircraft engines. Currently, five types of aviation turbine fuel containing synthesized hydrocarbons are certified and accepted, and allow adding a maximum of 50% of synthetic component to conventional fuel. The experimental performance and the emission characteristics of a turbojet engine were investigated in this paper. The studies were conducted with the use of a miniature turbojet engine, which is the main component of a laboratory test rig. The test rig is an interesting solution for engine research, due to the fact that studies concerning full-scale aircraft engines are very complex and expensive. The literature of the subject contains many papers using small-scale turbojet engines for testing alternative fuels. However, most of them concern components of fuels, e.g. biodiesel, butanol, which do not have direct application in aviation. Two different fuel samples, a conventional Jet A-1 fuel and a blend of 48% synthesized paraffinic kerosene from hydroprocessed esters and fatty acids process with Jet A-1 were tested. This process is one of the routes of producing alternative fuel for aviation, approved by ASTM standard. The test rig studies were performed according to a specific profile of engine test, which models different modes of a turbojet engine’s operation. The obtained results are compared in relation to the results for neat Jet A-1 fuel and then discussed.