Evaluation of cold-water carbonates as a possible paleoclimatic indicator

The common belief currently shared by many geoscientists concerning the climatic interpretation of limestones is that a warm-water environment is essential. This concept is not necessarily true because the rate and extent of terrigenous sediment dilution, rather than water temperature, is the primary factor determining whether or not a limestone forms at nearshore or continental shelf depths. Because carbonate productivity is lowest in cold climates, however, CaCO₃ abundance and the thickness of carbonate accumulations tend to be least at high latitudes. In this regard present-day continental shelves and beaches offer a poor model for comparing cold-water and warm-water carbonates because of the generally emergent continental tectonic framework, recent eustatic sea-level changes, and the presence of ice caps at the modern poles.Typically, the influence of climate on non-reef continental shelf and beach environments cannot be clearly distinguished by the presence or absence of major taxonomic groups. Faunal diversity and equitability are more sensitive in this regard. The absence of shelf-depth inorganic carbonate precipitates, micrite envelopes, and peloids may also point to the cold-water origin of a rock. Skeletal mineralogy and oxygen isotopes of certain unrecrystallized carbonates may be good paleoclimatic indicators; however, trace elements and physical-textural attributes of the carbonate fraction are probably temperature insensitive.Previous studies of high-latitude continental shelves have concentrated merely on the abundance of calcareous material and there is seemingly a disproportionate amount of information with respect to low-latitude carbonate studies. Further research on cold-water carbonates may open up new avenues for alternative paleoenvironmental and paleoclimatic interpretations.     

Glacial meltwater cooling of the Gulf of Mexico: GCM implications for Holocene and present-day climates

An atmospheric general circulation model, the NCAR CCM, has been used to investigate the possible effects that reduced Gulf of Mexico sea surface temperatures (SST) could have on regional and hemispheric climates. ¹⁸O records and terrestrial evidence indicate at least two major glacial meltwater discharges into the Gulf of Mexico subsequent to the last glacial maximum. It is probable that these discharges reduced Gulf of Mexico SST. We have conducted three numerical experiments, with imposed gulf-wide SST coolings of 3°C, 6°C, and 12°C, and find in all three experiments significant reductions in the North Atlantic storm-track intensity, along with a strong decrease in transient eddy water vapor transport out of the Gulf of Mexico. Surface pressures are higher over the North Atlantic, indicating a reduction of the climatological Icelandic low. The region is generally cooler and drier, with a reduction in precipitation that agrees well with evidence from Greenland ice cores. Other statistically significant changes occur across the Northern Hemisphere, but vary between the three experiments. In particular, warmer, wetter conditions are found over Europe for both the 6°C and 12°C SST reductions, but cooler conditions are found for the 3°C reduction. This indicates a dependence, in both the sign and magnitude of the model response, on the magnitude of the imposed SST anomaly. The results suggest that the present-day North Atlantic storm track is dependent on warm Gulf of Mexico SST for much of its intensity. They also suggest that meltwater-induced coolings may help account, in part, for some of the climatic oscillations that occurred during the last glacial/interglacial transition.     

Analyses of organic and inorganic contaminants in Salton Sea fish

Chemical contamination of fish from the Salton Sea, a quasi-marine lake in Southern California, could adversely impact millions of birds using the Pacific Flyway and thousands of humans using the lake for recreation. Bairdiella icistia (bairdiella), Cynoscion xanthulus (orangemouth corvina), and Oreochromis spp. (tilapia) were sampled from two river mouths and two nearshore areas of the Salton Sea. Muscle tissues were analyzed for a complete suite of 14 trace metals and 53 pesticides. Fish muscle tissues had concentrations of selenium ranging between 1.89 and 2.73 microg/g wet weight. 4,4'-DDE accounted for 94% of the total DDT metabolites. Total DDTs ranged between 17.1 and 239.0 and total PCBs between 2.5 and 18.6 ng/g wet weight. PCB congeners 132, 138, 153, 168, and 180 comprised over 50% of the total PCBs. Given the potential implementation of a commercial fishing at the Salton Sea in the future, the presence of persistent organic pollutants and selenium warrants further research into the effects of these mixtures on fish populations, and on wildlife and humans consuming fish.     

Propagation of Love waves in surface layers of varying thickness

Summary A study is made of the scattered field which results when a Love wave is incident on a layer having an irregular surface. To obtain this solution a perturbation method is used. It is shown that the scattered field may be described by a superposition of Love waves and non-propagating disturbances. As an illustrative example, the result is applied to obtain the scattering by a triangular trough.     

Petrophysics and mineral exploration: a workflow for data analysis and a new interpretation framework

As mineral exploration seeks deeper targets, there will be a greater reliance on geophysical data and a better understanding of the geological meaning of the responses will be required, and this must be achieved with less geological control from drilling. Also, exploring based on the mineral system concept requires particular understanding of geophysical responses associated with altered rocks. Where petrophysical datasets of adequate sample size and measurement quality are available, physical properties show complex variations, reflecting the combined effects of various geological processes. Large datasets, analysed as populations, are required to understand the variations. We recommend the display of petrophysical data as frequency histograms because the nature of the data distribution is easily seen with this form of display. A petrophysical dataset commonly contains a combination of overlapping sub-populations, influenced by different geological factors. To understand the geological controls on physical properties in hard rock environments, it is necessary to analyse the petrophysical data not only in terms of the properties of different rock types. It is also necessary to consider the effects of processes such as alteration, weathering, metamorphism and strain, and variables such as porosity and stratigraphy. To address this complexity requires that much more supporting geological information be acquired than in current practice. The widespread availability of field portable instruments means quantitative geochemical and mineralogical data can now be readily acquired, making it unnecessary to rely primarily on categorical rock classification schemes. The petrophysical data can be combined with geochemical, petrological and mineralogical data to derive explanations for observed physical property variations based not only on rigorous rock classification methods, but also in combination with quantitative estimates of alteration and weathering. To understand how geological processes will affect different physical properties, it is useful to define three end-member forms of behaviour. Bulk behaviour depends on the physical properties of the dominant mineral components. Density and, to a lesser extent, seismic velocity show such behaviour. Grain and texture behaviour occur when minor components of the rock are the dominate controls on its physical properties. Grain size and shape control grain properties, and for texture properties the relative positions of these grains are also important. Magnetic and electrical properties behave in this fashion. Thinking in terms of how geological processes change the key characteristics of the major and minor mineralogical components allows the resulting changes in physical properties to be understood and anticipated.     

High‐temporal resolution fluvial sediment source fingerprinting with uncertainty: a Bayesian approach

This contribution addresses two developing areas of sediment fingerprinting research. Specifically, how to improve the temporal resolution of source apportionment estimates whilst minimizing analytical costs and, secondly, how to consistently quantify all perceived uncertainties associated with the sediment mixing model procedure. This first matter is tackled by using direct X‐ray fluorescence spectroscopy (XRFS) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analyses of suspended particulate matter (SPM) covered filter papers in conjunction with automatic water samplers. This method enables SPM geochemistry to be quickly, accurately, inexpensively and non‐destructively monitored at high‐temporal resolution throughout the progression of numerous precipitation events. We then employed a Bayesian mixing model procedure to provide full characterization of spatial geochemical variability, instrument precision and residual error to yield a realistic and coherent assessment of the uncertainties associated with source apportionment estimates. Applying these methods to SPM data from the River Wensum catchment, UK, we have been able to apportion, with uncertainty, sediment contributions from eroding arable topsoils, damaged road verges and combined subsurface channel bank and agricultural field drain sources at 60‐ and 120‐minute resolution for the duration of five precipitation events. The results presented here demonstrate how combining Bayesian mixing models with the direct spectroscopic analysis of SPM‐covered filter papers can produce high‐temporal resolution source apportionment estimates that can assist with the appropriate targeting of sediment pollution mitigation measures at a catchment level. © 2015 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Adaptations for scavenging by three diverse bathyla species, Eptatretus stouti, Neptunea amianta and Orchomene obtusus

Many deep-sea animals derive part of their nutrition from rare and unpredictable food falls. However, traits that allow organisms inhabiting the sea floor to exploit carrion are poorly understood. We found in laboratory experiments that hagfish (Eptatretus stouti), gastropods (Neptunea amianta) and amphipods (Orchomene obtusus) survived extended periods of starvation, in some cases for more than a year. When exposed to odors emitted from carrion, most individuals of E. stouti and O. obtusus began searching for food within seconds, whereas none responded to the scent of the live prey. In contrast, the slow crawling N. amianta readily consumed carrion but showed no apparent response to any odor solutions tested. Because more motile animals exhibited lower thresholds for response to signal molecules, sensitivity to chemical cues appears related to species mobility. Hagfish were also found to defend carrion from some competitors by releasing slime when feeding. Though varying dramatically in size, morphology, locomotive ability, and phylogeny, these three species all possess traits well suited for a scavenging lifestyle.     

Small-scale, high-precision and high-accuracy determination of Poisson’s ratios in cohesive marine sediments

Poisson’s ratio (static) appears as a parameter in models of soft-sediment geomechanical processes such as gas bubble formation and bioturbation, and in a number of practical applications, including acoustic imaging, but is rarely measured in soft near-surface (upper 20 cm) marine sediments. A new uniaxial apparatus was developed to assess Poisson’s ratios of cylindrical samples of soft cohesive sediments under finite-strain, unconfined, undrained conditions. No constraining membrane around the sample is necessary in the instrument. By monitoring the fluid level in a capillary, changes in sample volume can be determined to high precision (reproducibility). Measurements on reference materials, i.e., gelatine and polyurethane, also indicate high accuracy (veracity). For natural sediments from Nova Scotia, Canada, Poisson’s ratios range from 0.4951 to 0.5 with no indication of anisotropy; therefore, such sediments act as incompressible solids to short-term/small-magnitude stresses, as occur during bubble formation and infaunal movement.     

Caught in the act: the 20 December 2001 gravity flow event in Monterey Canyon

A sediment gravity flow descended through the axis of Monterey Canyon on 20 December 2001 at 13:35 Pacific standard time. The timing of this event is documented by a current-meter package which recorded an 11.9-dbar pressure increase in less than 10 min and was found 550 m down-canyon from its deployment site, buried completely within a >70-cm-thick gravity flow deposit. This event is believed to have started in less than 290 m of water because an instrument at this location was also lost at the same time. A 178-cm core collected after the event from the axis of the canyon at 1,297-m water depth contained fresh, greenish, chlorophyll-rich organic material at 32-cm sub-bottom depth, suggesting the event extended to this water depth. The only trigger identified for this mass movement event appears to be moderate sea and surf conditions. Thus, gravity flow events of this magnitude do not require an exceptional triggering event.     

Sensitivity of crop yields and land resource potential to climatic change in Ontario,Canada

Increasing concentrations of atmospheric CO₂ and other greenhouse gases are expected to contribute to a global warming. This paper examines the potential implications of a climatic change corresponding to a doubling of atmospheric concentrations of CO₂ on crop production opportunities throughout Ontario, a major food producing region in Canada. The climate is projected to become warmer and drier, but the extent of these shifts are expected to vary from region to region within Ontario. The effect of this altered climate on crop yields and the area of land capable of supporting specific crops varies according to region, soil quality and crop type. Most notable are the enhanced opportunities for grains and oilseeds in the northern regions, and the diminished production prospects for most crops in the most southerly parts of Ontario.